Structure

    redEnd--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p(--??2D-NeuGc,p)--??1HexNAc,p$MONO,Und,-H,0,redEnd

An E-workflow for implementing guidelines in glycomics mass spectrometry

Degradation product

GlyTouCan Accession Number: Loading...

Peak Intensity
305.23 1.8
306.09 4.3

Annotations:

B ?1D-Gal,p/#bcleavage--??2D-NeuGc,p$MONO,Und,-H,0,redEnd
307.02 4.3
307.23 1.3
312.04 2.0
364.24 0.9

Annotations:

BY ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p(--??2D-NeuGc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd CZ ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??2D-NeuGc,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
364.92 1.0
365.21 0.8
382.06 0.8

Annotations:

CY ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??2D-NeuGc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
384.5 1.2

Annotations:

Y redEnd--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
423.55 0.8
424.24 2.3
425.09 3.3
465.62 1.8
466.02 12.7
466.24 4.9
467.18 3.3
486.0 1.4

Annotations:

CY ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??2D-NeuGc,p)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
490.06 0.9
525.17 3.0
543.86 4.0
546.11 3.9

Annotations:

YY redEnd--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p(--??2D-NeuGc,p/#ycleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
546.48 2.9

Annotations:

YY redEnd--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p(--??2D-NeuGc,p/#ycleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
547.37 2.0
567.22 13.3

Annotations:

BY ?1D-Gal,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??2D-NeuGc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd CZ ?1D-Gal,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??2D-NeuGc,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
568.29 2.6
670.66 2.3
672.12 1.3
689.21 3.3

Annotations:

C ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??2D-NeuGc,p)--??1HexNAc,p$MONO,Und,-H,0,redEnd
689.81 1.1
707.33 5.2
708.25 2.4
733.29 3.7

Annotations:

^{0,4}X_{NeuGc}Y redEnd--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p(--??2D-NeuGc,p/#xcleavage_0_4)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
749.26 80.5

Annotations:

Y redEnd--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p(--??2D-NeuGc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
750.27 16.5
777.0 1.8
820.13 1.8
835.27 1.6

Annotations:

Z redEnd--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p(--??2D-NeuGc,p)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
842.38 3.6
842.89 0.9
843.26 4.7
853.36 2.7

Annotations:

Y redEnd--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p(--??2D-NeuGc,p)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
861.71 0.8
872.08 1.3
876.08 4.3
876.97 2.5
877.54 1.3
895.35 4.6
916.21 0.8
959.42 1.1
962.25 0.7
978.05 1.5
993.23 13.9
997.46 2.5
1010.71 1.3
1012.15 8.5

Annotations:

^{1,3}X_{NeuGc} redEnd--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p(--??2D-NeuGc,p/#xcleavage_1_3)--??1HexNAc,p$MONO,Und,-H,0,redEnd
1015.56 0.6

There are 7 similar spectra:

Id Structure Score

0.94

4216

0.84

4214

0.73

4271

0.61

3768

0.59

4215

0.57

3512

0.53

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1055.38
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Bos Taurus
Tissue - Cervix Mucus

HPLC

Column NA

Method

  • 78 min gradient with Approx 3-5 ul/min (static split from 250 ul/min) run rate
  • 10 mM (NH4)HCO3
  • 10 mM (NH4)HCO3 in 80% acetonitrile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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