Structure

    redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd

Effects of size and geographical origin on Atlantic salmon, Salmo salar, mucin O-glycan repertoire

PubMed Entry

GlyTouCan Accession Number: Loading...

200.0400.0600.0800.0100012001400m/z0.01.0e+22.0e+23.0e+2Abundance
Peak Intensity
290.11 52.0

Annotations:

B ?1D-GalNAc,p/#bcleavage--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
291.16 3.8
292.21 1.0
424.23 5.9

Annotations:

^{0,4}A_{GalNAc} a1D-GalNAc,p/#acleavage_0_4--6?1HexNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
449.32 0.6

Annotations:

^{2,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_2_4--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p)--6?1HexNAc,p/#zcleavage$MONO,Und,-2H,0,redEnd
494.89 0.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p/#zcleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
567.34 0.9

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3a1D-GalNAc,p(--3?1D-Gal,p/#ycleavage)--6?1HexNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3a1D-GalNAc,p(--3?1D-Gal,p/#zcleavage)--6?1HexNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
569.04 0.7
626.93 0.6
627.48 0.7

Annotations:

^{2,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_2_4--3a1D-GalNAc,p(--3?1D-Gal,p/#ycleavage)--6?1HexNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
628.4 0.6
676.16 0.9
686.25 1.0
722.84 0.9

Annotations:

Y redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p)--6?1HexNAc,p--??1D-Gal,p)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p/#ycleavage)--6?1HexNAc,p--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
723.91 0.5
739.61 0.6
748.33 0.5
756.89 1.0
757.18 1.8
757.67 3.3

Annotations:

^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p)--6?1HexNAc,p--??1D-Gal,p)--6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-2H,0,redEnd
758.32 4.2
765.85 0.5
769.6 1.5
769.94 1.2
775.56 0.5
777.64 1.2
777.95 0.6
778.36 0.7

Annotations:

Z redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p)--6?1HexNAc,p--??1D-Gal,p/#zcleavage)--6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
779.2 0.7
784.96 1.1
787.3 5.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p)--6?1HexNAc,p--??1D-Gal,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
787.82 5.7
788.44 1.1
801.52 0.5
805.96 0.7
807.24 0.7
815.49 0.9
823.35 0.5
824.31 0.7
829.56 1.1
829.75 0.8
830.14 1.0
830.43 0.8
835.86 0.8
837.3 0.7
837.74 2.3
838.34 5.6
838.82 2.2
839.31 0.5
839.72 0.6
841.26 0.6

Annotations:

^{2,4}X_{GalNAc}Z redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p/#xcleavage_2_4--6?1HexNAc,p--??1D-Gal,p/#zcleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
892.32 0.7

Annotations:

^{0,4}X_{GalNAc}Y redEnd--??1D-GalNAc,p/#xcleavage_0_4--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p/#ycleavage)--6?1HexNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
932.36 0.6

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p/#ycleavage)--6?1HexNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p/#zcleavage)--6?1HexNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
933.52 0.8
952.23 1.8

Annotations:

YY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p/#ycleavage)--6?1HexNAc,p--??1D-Gal,p)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
980.71 1.5
1064.28 0.6
1064.55 0.6
1081.44 1.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p/#ycleavage)--6?1HexNAc,p--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1081.66 0.8
1082.4 0.6
1137.18 1.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p/#ycleavage)--6?1HexNAc,p--??1D-Gal,p)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p/#zcleavage)--6?1HexNAc,p--??1D-Gal,p)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1155.43 12.0

Annotations:

YY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p/#ycleavage)--6?1HexNAc,p--??1D-Gal,p)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1156.32 5.7
1156.7 1.8
1156.91 0.8
1210.4 0.6
1225.25 1.0

Annotations:

Y^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p/#ycleavage)--6?1HexNAc,p--??1D-Gal,p)--6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p/#zcleavage)--6?1HexNAc,p--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1225.55 0.8
1226.62 2.1
1227.26 0.8
1241.55 0.7

Annotations:

C ?1D-GalNAc,p/#ccleavage--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p)--6?1HexNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
1243.55 12.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p/#ycleavage)--6?1HexNAc,p--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1244.44 6.8
1244.81 0.9
1245.53 1.4
1245.75 0.7
1266.26 1.3

Annotations:

YZ redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p)--6?1HexNAc,p--??1D-Gal,p/#ycleavage)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p)--6?1HexNAc,p--??1D-Gal,p/#zcleavage)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p/#ycleavage)--6?1HexNAc,p--??1D-Gal,p/#zcleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p/#zcleavage)--6?1HexNAc,p--??1D-Gal,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1266.71 1.0
1326.45 0.6
1368.66 1.2
1386.59 1.4

Annotations:

^{2,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p/#xcleavage_2_4)--6?1HexNAc,p--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd ^{0,4}X_{GalNAc} redEnd--??1D-GalNAc,p/#xcleavage_0_4--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p)--6?1HexNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
1387.34 1.3
1388.16 0.6
1388.54 1.6
1410.4 4.1
1410.68 1.8
1411.4 0.8
1411.75 0.9
1428.56 37.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p)--6?1HexNAc,p--??1D-Gal,p)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p/#zcleavage)--6?1HexNAc,p--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1429.53 21.5
1430.79 2.7
1431.43 0.8
1444.6 0.9
1446.59 280.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p)--6?1HexNAc,p--??1D-Gal,p)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--3a2D-NeuAc,p/#ycleavage)--6?1HexNAc,p--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1447.57 161.1
1448.53 62.4
1449.34 7.5
1449.75 3.8
1488.81 1.6

N/A

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1736.64
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Salmo Salar
Tissue - Mucus

HPLC

Column

Method

  • 40 min gradient with 10 ul/min run rate
  • 10 mM (NH4)HCO3 in water
  • 10 mM (NH4)HCO3 in 80% acetontirile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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