Structure

    redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p)--??1L-Fuc,p)--6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd

Effects of size and geographical origin on Atlantic salmon, Salmo salar, mucin O-glycan repertoire

PubMed Entry

GlyTouCan Accession Number: Loading...

200.0400.0600.0800.01000120014001600m/z0.0501.0e+2Abundance
Peak Intensity
287.9 0.6
290.14 15.9

Annotations:

B ?1D-GalNAc,p/#bcleavage--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
291.27 2.0
492.95 0.4
493.47 0.6

Annotations:

B ?1D-Gal,p/#bcleavage--??1HexNAc,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
494.13 0.9
510.11 0.5

Annotations:

B a1D-GalNAc,p/#bcleavage--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p$MONO,Und,-H,0,redEnd
532.52 0.6

Annotations:

YY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p/#ycleavage)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
540.1 0.7

Annotations:

YZ redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p/#ycleavage)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p/#zcleavage)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd YY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p/#ycleavage)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd YY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p/#ycleavage)--6?1HexNAc,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd YY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p/#ycleavage)--6?1HexNAc,p(--??1L-Fuc,p/#ycleavage)--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
570.43 0.7

Annotations:

^{0,4}A_{GalNAc} a1D-GalNAc,p/#acleavage_0_4--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p$MONO,Und,-H,0,redEnd
632.07 0.4

Annotations:

^{2,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_2_4--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p/#zcleavage)--??1D-Gal,p$MONO,Und,-2H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p/#zcleavage)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd
656.06 1.2

Annotations:

^{0,4}X_{GalNAc} redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p/#xcleavage_0_4--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
673.08 0.7

Annotations:

C a1D-GalNAc,p/#ccleavage--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
676.01 1.6

Annotations:

^{0,4}X_{GalNAc}Z redEnd--??1D-GalNAc,p/#xcleavage_0_4--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd Z^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p/#zcleavage)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p)--6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-2H,0,redEnd
696.41 0.8
696.97 0.9

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p/#zcleavage)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p/#zcleavage)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p/#zcleavage)--6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
716.16 0.6

Annotations:

YY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p/#ycleavage)--6?1HexNAc,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
739.2 0.4
742.14 1.6
758.11 1.4

Annotations:

Y^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p/#ycleavage)--??1D-Gal,p)--6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-2H,0,redEnd
759.35 0.7
778.2 0.6

Annotations:

ZY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p/#zcleavage)--??1D-Gal,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p/#ycleavage)--??1D-Gal,p/#zcleavage)--6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
781.22 0.7
790.35 1.6
815.54 0.5
830.71 1.2

Annotations:

^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p)--6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-2H,0,redEnd
831.43 1.9
850.06 0.9
852.54 1.2
858.39 1.2

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ^{2,4}X_{GalNAc}Z redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p/#xcleavage_2_4--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ^{0,4}X_{GalNAc}Z redEnd--??1D-GalNAc,p/#xcleavage_0_4--3a1D-GalNAc,p(--3?1D-Gal,p/#zcleavage)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p$MONO,Und,-H,0,redEnd
859.25 1.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p/#zcleavage)--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
860.37 4.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
860.85 2.1
861.46 1.2
881.22 0.8
883.25 0.7
900.07 1.0

Annotations:

^{2,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_2_4--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p/#zcleavage)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
902.5 3.8
902.92 1.9
910.47 1.3
910.82 3.5
911.39 7.5
911.95 2.6
1039.18 0.7
1040.34 0.4
1046.57 0.8
1074.32 0.5
1091.02 0.5
1139.61 1.2
1141.88 0.7
1230.66 0.4
1248.65 1.5
1249.45 0.8

Annotations:

^{2,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_2_4--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
1266.78 0.5
1301.37 1.3
1301.67 2.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p/#ycleavage)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1302.44 1.0
1303.02 0.4
1311.47 0.5
1328.55 0.8
1353.25 0.4

Annotations:

Z^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p/#zcleavage)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p)--6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
1371.6 1.6

Annotations:

Y^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p/#ycleavage)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p)--6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p/#zcleavage)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1372.45 0.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1387.46 0.5
1387.69 0.7

Annotations:

C ?1D-GalNAc,p/#ccleavage--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p$MONO,Und,-H,0,redEnd
1389.55 3.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p/#ycleavage)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1390.55 2.6
1391.7 1.3
1428.73 0.9

Annotations:

YZ redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p/#ycleavage)--??1D-Gal,p)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p/#zcleavage)--??1D-Gal,p)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p/#ycleavage)--6?1HexNAc,p(--??1L-Fuc,p/#zcleavage)--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p/#zcleavage)--6?1HexNAc,p(--??1L-Fuc,p/#ycleavage)--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1429.42 0.6

Annotations:

^{2,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_4--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p$MONO,Und,-H,0,redEnd
1430.8 0.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p/#ycleavage)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p/#ycleavage)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1431.6 1.4
1432.8 0.6
1446.78 0.5

Annotations:

YY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p/#ycleavage)--??1D-Gal,p)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p/#ycleavage)--6?1HexNAc,p(--??1L-Fuc,p/#ycleavage)--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1461.62 0.6
1479.44 0.8
1508.75 0.4
1515.62 0.5
1532.5 0.9

Annotations:

^{0,4}X_{GalNAc} redEnd--??1D-GalNAc,p/#xcleavage_0_4--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p$MONO,Und,-H,0,redEnd
1532.91 1.0
1533.33 0.8
1533.71 0.6
1534.6 1.1
1550.63 0.8
1556.9 2.0
1557.44 0.7

Annotations:

ZY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p/#zcleavage)--??1D-Gal,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p/#ycleavage)--??1D-Gal,p/#zcleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1573.65 0.7
1574.01 0.5
1574.43 6.2

Annotations:

Z redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p/#zcleavage)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1574.74 5.6
1575.32 1.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p/#ycleavage)--??1D-Gal,p/#ycleavage)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1575.72 1.4
1576.63 1.5
1590.46 2.0
1590.71 1.1
1591.63 1.0
1592.64 126.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3a1D-GalNAc,p(--3?1D-Gal,p--??1HexNAc,p--??2D-NeuAc,p/#ycleavage)--6?1HexNAc,p(--??1L-Fuc,p)--??1D-Gal,p)--6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1593.62 75.7
1594.71 17.3
1595.08 1.6

There are 3 similar spectra:

Id Structure Score

1.00

4948

0.93

0.93

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1882.70
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Salmo Salar
Tissue - Mucus

HPLC

Column

Method

  • 40 min gradient with 10 ul/min run rate
  • 10 mM (NH4)HCO3 in water
  • 10 mM (NH4)HCO3 in 80% acetontirile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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