Structure

    freeEnd--?b1D-GlcNAc,p(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd

Shotgun Ion-Mobility Mass Spectrometry Sequencing (SIMMS2) for glycosaminoglycan oligosaccharides

GlyTouCan Accession Number: Loading...

Peak Intensity
51.038 101.0
52.4616 13.9
55.0243 216.0
57.0426 859.0
57.749 32.0

Annotations:

C b1D-GlcNAc,p/#ccleavage--4a14uHexA,p$MONO,Und,-3H,0,freeEnd
59.022 257.0
59.6398 29.1
62.3246 29.5
62.8704 46.6
69.0448 1580.0

Annotations:

^{0,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_4--6?1S$MONO,Und,-2H,0,freeEnd
70.3467 61.0
73.04 3920.0
74.033 184.0
78.0371 39.8

Annotations:

B b1D-GlcNAc,p/#bcleavage--4a14uHexA,p$MONO,Und,-2H,0,freeEnd
79.0253 130.0
79.9693 27800.0
80.9772 28900.0
81.9666 509.0

Annotations:

^{0,3}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_3(--4a14uHexA,p)--6?1S/#lcleavage$MONO,Und,-3H,0,freeEnd
82.041 741.0
82.9735 630.0
83.0292 1130.0
84.0576 7520.0
87.0219 61100.0

Annotations:

C b1D-GlcNAc,p/#ccleavage--4a14uHexA,p$MONO,Und,-2H,0,freeEnd
88.0266 884.0
88.7229 32.1
89.0369 795.0
92.0641 1560.0
93.048 1540.0

Annotations:

Z freeEnd--?b1D-GlcNAc,p(--4a14uHexA,p/#zcleavage)--6?1S$MONO,Und,-3H,0,freeEnd
93.8676 46.8
94.0438 1490.0
94.9938 494.0
95.0276 6650.0
96.0572 1060.0
96.2817 22.7
96.9787 416000.0
97.9741 910.0
98.0732 2180.0
98.7148 74.2
98.9711 8360.0
99.0234 1780.0
99.0621 498.0

Annotations:

Y freeEnd--?b1D-GlcNAc,p(--4a14uHexA,p/#ycleavage)--6?1S$MONO,Und,-3H,0,freeEnd
100.055 3920.0
101.0391 2990.0
103.0537 343.0

Annotations:

^{3,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_3_5(--4a14uHexA,p)--6?1S$MONO,Und,-3H,0,freeEnd
104.0507 1150.0
106.9954 193.0
108.0585 1490.0

Annotations:

^{2,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_4--4a14uHexA,p$MONO,Und,-2H,0,freeEnd ^{0,3}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_3(--4a14uHexA,p)--6?1S$MONO,Und,-3H,0,freeEnd
109.045 1690.0
109.0821 355.0
109.5424 29.3

Annotations:

Y freeEnd--?b1D-GlcNAc,p(--4a14uHexA,p/#ycleavage)--6?1S/#lcleavage$MONO,Und,-2H,0,freeEnd
109.9335 59.0

Annotations:

^{1,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_1_5(--4a14uHexA,p)--6?1S/#lcleavage$MONO,Und,-3H,0,freeEnd
111.0302 1050.0
112.0568 2080.0
113.041 27200.0

Annotations:

^{2,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_5(--4a14uHexA,p)--6?1S$MONO,Und,-3H,0,freeEnd
113.0864 79.4

Annotations:

^{2,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_5(--4a14uHexA,p)--6?1S$MONO,Und,-3H,0,freeEnd
115.0205 5720.0

Annotations:

^{3,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_3_5(--4a14uHexA,p)--6?1S/#lcleavage$MONO,Und,-2H,0,freeEnd
118.9751 11.7
121.0483 652.0
121.2113 37.2
123.0136 39.8

Annotations:

^{0,3}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_3(--4a14uHexA,p)--6?1S/#lcleavage$MONO,Und,-2H,0,freeEnd
125.0426 9900.0
126.0753 64500.0
127.0924 158.0
129.0383 2790.0
132.0504 551.0
133.0445 50.2
135.0634 417.0
136.0617 971.0
138.0759 2280.0

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2(--4a14uHexA,p)--6?1S/#lcleavage$MONO,Und,-2H,0,freeEnd
138.9975 839000.0

Annotations:

^{0,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_4--6?1S$MONO,Und,-H,0,freeEnd
140.9888 20000.0
141.0783 139.0
143.0565 1080.0
143.1298 349.0
146.0711 137.0
148.0155 23.3
148.0738 1530.0
149.0411 288.0
151.0479 221.0
152.0632 267.0

Annotations:

freeEnd--?b1D-GlcNAc,p(--4a14uHexA,p)--6?1S$MONO,Und,-3H,0,freeEnd
154.0757 1700.0
154.9701 1990.0

Annotations:

^{3,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_3_5(--4a14uHexA,p)--6?1S$MONO,Und,-2H,0,freeEnd
165.0119 63900.0
167.0325 117.0
171.1122 69.8
175.0515 29400.0

Annotations:

C b1D-GlcNAc,p/#ccleavage--4a14uHexA,p$MONO,Und,-H,0,freeEnd
176.0547 819.0
177.0402 99.2
178.011 75.6

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2(--4a14uHexA,p)--6?1S$MONO,Und,-2H,0,freeEnd
178.0776 1720.0

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2(--4a14uHexA,p)--6?1S$MONO,Und,-2H,0,freeEnd
181.0085 14700.0
182.0275 52.5
183.0372 34600.0
184.0855 20700.0
185.0591 133.0
191.084 181.0
193.1187 352.0
196.9328 1360.0
197.0633 938.0
197.9523 17.8
198.0691 303.0
199.0273 170000.0
203.0815 100.0
205.1441 1470.0
208.9665 1640.0
214.9474 16400.0
216.9448 2030.0

Annotations:

^{2,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_4--4a14uHexA,p$MONO,Und,-H,0,freeEnd
217.0117 299.0

Annotations:

^{2,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_4--4a14uHexA,p$MONO,Und,-H,0,freeEnd
217.0688 21700.0

Annotations:

^{2,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_4--4a14uHexA,p$MONO,Und,-H,0,freeEnd
217.1548 245.0

Annotations:

^{2,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_4--4a14uHexA,p$MONO,Und,-H,0,freeEnd
218.0762 820.0
220.1794 1390.0

Annotations:

Y freeEnd--?b1D-GlcNAc,p(--4a14uHexA,p/#ycleavage)--6?1S/#lcleavage$MONO,Und,-H,0,freeEnd
222.9632 58.8
223.0261 21900.0
223.2313 179.0
224.0316 666.0
225.0993 292.0
227.0883 64.8
231.21 1180.0

Annotations:

^{3,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_3_5(--4a14uHexA,p)--6?1S/#lcleavage$MONO,Und,-H,0,freeEnd
232.9597 5510.0
233.1913 1410.0
234.9574 564.0
235.0821 1210.0
238.942 298.0
239.1239 233.0
241.0437 120000.0
242.042 3620.0
244.082 32.4
245.0135 736.0
248.0605 1670.0
253.2556 2250.0
255.2724 19000.0
256.0975 600.0
256.1841 88.6
256.2762 1890.0
259.0862 25900.0
260.0891 1300.0
263.1281 109.0
264.0587 17300.0
264.1967 265.0
265.0663 4060.0
265.1846 4450.0
265.2942 492.0
265.9309 94.0
266.0752 16200.0
266.1833 387.0
267.1339 252.0
268.1126 125.0
268.9958 59.0
269.1439 322.0
269.2759 722.0
271.1858 134.0
273.0828 42.9
274.9245 35800.0
275.9231 3710.0
276.1609 134.0
277.0241 185.0

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2(--4a14uHexA,p)--6?1S/#lcleavage$MONO,Und,-H,0,freeEnd
277.9236 409.0
278.0451 190.0
278.1057 478.0
282.0798 130000.0

Annotations:

Z freeEnd--?b1D-GlcNAc,p(--4a14uHexA,p/#zcleavage)--6?1S$MONO,Und,-H,0,freeEnd
283.0875 1980.0
283.309 36200.0
284.0712 2510.0
284.3109 4100.0
285.2436 775.0
285.3105 284.0
286.084 68.0
286.9864 10.8
288.1028 70.5

Annotations:

^{1,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_1_4--4a14uHexA,p$MONO,Und,-H,0,freeEnd
288.948 551.0
292.9376 982.0
293.2236 3100.0
294.1588 131.0
294.9377 439.0
295.0585 12900.0
296.0606 830.0
297.2155 817.0
299.2655 260.0
300.0988 428000.0

Annotations:

Y freeEnd--?b1D-GlcNAc,p(--4a14uHexA,p/#ycleavage)--6?1S$MONO,Und,-H,0,freeEnd
301.0898 18700.0
302.0851 9110.0
302.9648 187.0
303.1498 146.0
305.2182 217.0
307.2369 209.0
308.1783 85.8
309.1613 139.0
309.2216 17800.0
309.923 60.5
309.9904 18.1
310.226 1410.0
310.4989 20.2
310.9379 392.0

Annotations:

^{3,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_3_5(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
311.1521 177.0

Annotations:

^{3,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_3_5(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
311.2188 29000.0

Annotations:

^{3,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_3_5(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
312.2195 2820.0
312.9328 83.4
313.0703 1970.0
313.2502 109.0
316.9312 593.0
317.2156 130.0
318.1625 114.0
318.93 132.0
319.1828 70.9
319.2718 177.0
323.2122 556.0
325.2367 46300.0
326.2336 4070.0
327.2307 1350.0

Annotations:

^{0,3}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_3(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
328.0853 1560.0
335.2068 75.4
335.9878 26.8
336.3803 130.0
336.9269 195.0
337.1874 205.0
337.257 5060.0
337.3593 269.0
339.086 847.0
340.1289 60.4
340.9771 64.2

Annotations:

^{2,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_5(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
341.1593 6810.0

Annotations:

^{2,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_5(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
341.2439 1080.0

Annotations:

^{2,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_5(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
342.119 567000.0
342.2574 12400.0
343.1085 44600.0
344.1041 18200.0
345.1083 940.0
348.2665 446.0
350.9096 213.0
353.2564 27200.0
354.9123 480.0
355.1589 41.9
355.2439 1050.0
357.0853 426000.0

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
357.2266 6650.0

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
357.2873 146.0

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
357.9214 124.0
358.0732 22800.0
358.899 213.0
359.0691 12600.0
360.0708 650.0
360.15 4440.0
361.042 2350.0
363.2485 68.0
364.9426 282.0
365.0107 873.0
365.3176 82.6
365.9835 19.3
366.2169 87.5
367.3358 41.5
367.9319 43.5
370.9423 1090.0
371.923 456.0
372.9175 386.0
377.1455 16000.0
378.1444 2760.0

Annotations:

freeEnd--?b1D-GlcNAc,p(--4a14uHexA,p)--6?1S/#lcleavage$MONO,Und,-H,0,freeEnd
379.0556 27600.0
379.1423 3710.0
379.2817 124.0
381.2913 5690.0
382.2927 859.0
385.2371 782.0
390.9101 134.0
395.0209 533.0
395.3032 48.7
395.8947 21.8
396.0121 31.5
396.1239 8760.0
397.2896 22400.0
397.8958 5.7
398.2912 2100.0
400.9368 70.0
401.0418 876.0
401.2123 119.0
406.9454 110.0
409.2558 146.0
412.8893 1980.0
413.8852 471.0
418.9071 196.0
422.1082 467.0
425.3246 4080.0
426.327 557.0
430.8985 190.0
433.2647 54.3
434.9004 153.0
437.2267 1450.0
440.1271 108000.0
441.247 82.9
442.1703 47.2
442.9225 195.0
443.1131 332.0
443.323 447.0
444.2231 34.0
445.2523 113.0
446.13 593.0
446.221 371.0
447.2058 15300.0
448.2075 1500.0
449.2193 1800.0
449.3177 41.0
449.9195 64.1
451.2632 1440.0
452.2697 501.0
453.2992 58.4
457.176 29.9
458.0221 103.0

Annotations:

freeEnd--?b1D-GlcNAc,p(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
458.1533 703000.0

Annotations:

freeEnd--?b1D-GlcNAc,p(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
458.312 10700.0

Annotations:

freeEnd--?b1D-GlcNAc,p(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
459.1431 75900.0
459.8975 42.2
460.1357 29200.0
460.2635 55.8
461.1345 1890.0
461.3139 51.8
462.132 450.0
462.8982 57.0
463.2216 165.0
465.3768 1800.0
467.3425 118.0
469.3579 2180.0
474.2502 71.5
474.364 337.0
475.0605 8.96
476.1448 444.0
479.2557 193.0
480.1198 16600.0
481.1234 1340.0
481.3753 207.0
482.1177 540.0
485.356 4940.0
485.4438 48.0
486.2338 54.7
486.3565 721.0
491.89 97.9
496.2373 367.0

There are 1 similar spectra:

Id Structure Score

5316

0.54

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 457.07
(Calculated Monoisotopic)

Reducing End: Free reducing end

Persubstitution: Underivatised

Biological Context

N/A

HPLC

Column

Method

  • gradient with 0.1 ml/min run rate
  • water
  • water

Mass Spec

Waters Synapt G2-S HDMS

MIRAGE Structural data

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