Structure

    freeEnd--??1D-GlcN,p(((--4a14uHexA,p--2?1S)--N?1S)--6?1S)--3?1S$MONO,Und,-2H,0,freeEnd

Shotgun Ion-Mobility Mass Spectrometry Sequencing (SIMMS2) for glycosaminoglycan oligosaccharides

GlyTouCan Accession Number: Loading...

Peak Intensity
57.0703 1360.0
79.977 15500.0
80.0645 28.4
80.9839 5750.0
85.0465 13800.0
96.9726 410000.0
98.9674 15500.0
101.0414 18.7
111.0147 8760.0
112.0188 894.0
112.991 4130.0
113.029 2950.0
115.0077 5450.0
132.9681 2380.0
134.9657 813.0
137.9866 28000.0

Annotations:

^{1,3}A_{GlcN} ?1D-GlcN,p/#acleavage_1_3(--N?1S/#lcleavage)--3?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
139.9825 2090.0
142.0497 895.0
152.9864 620.0
154.9768 295.0

Annotations:

^{3,5}A_{GlcN} ?1D-GlcN,p/#acleavage_3_5(--4a14uHexA,p--2?1S/#lcleavage)--6?1S/#lcleavage}--??1S$MONO,Und,-2H,0,freeEnd
157.0112 21500.0

Annotations:

B ?1D-GlcN,p/#bcleavage--4a14uHexA,p--2?1S/#lcleavage$MONO,Und,-H,0,freeEnd
164.9814 2300.0
168.4864 4180.0

Annotations:

Y freeEnd--??1D-GlcN,p(((--4a14uHexA,p/#ycleavage)--N?1S/#lcleavage)--6?1S/#lcleavage)--3?1S/#lcleavage}(--??1S)--??1S$MONO,Und,-2H,0,freeEnd
169.4829 383.0
174.9992 180.0

Annotations:

C ?1D-GlcN,p/#ccleavage--4a14uHexA,p--2?1S/#lcleavage$MONO,Und,-H,0,freeEnd
182.9923 2060.0
188.9846 94.5
189.4903 32700.0
189.6083 27.2
189.9922 3940.0
198.5124 10900.0
198.9898 5670.0
202.498 7430.0

Annotations:

^{1,4}A_{GlcN} ?1D-GlcN,p/#acleavage_1_4((--4a14uHexA,p--2?1S/#lcleavage)--N?1S/#lcleavage)--3?1S/#lcleavage}(--??1S)--??1S$MONO,Und,-2H,0,freeEnd
203.4954 1780.0
207.5174 11400.0

Annotations:

freeEnd--??1D-GlcN,p(((--4a14uHexA,p--2?1S/#lcleavage)--N?1S/#lcleavage)--6?1S/#lcleavage)--3?1S/#lcleavage}--??1S$MONO,Und,-2H,0,freeEnd
208.0193 1910.0
208.9731 1530.0

Annotations:

^{1,5}A_{4uHexA} a14uHexA,p/#acleavage_1_5--2?1S$MONO,Und,-H,0,freeEnd
216.4958 6270.0
217.9792 22800.0

Annotations:

^{1,3}A_{GlcN} ?1D-GlcN,p/#acleavage_1_3(--N?1S)--3?1S$MONO,Und,-H,0,freeEnd ^{0,2}A_{GlcN} ?1D-GlcN,p/#acleavage_0_2((--4a14uHexA,p--2?1S/#lcleavage)--6?1S/#lcleavage)--3?1S/#lcleavage}(--??1S)--??1S$MONO,Und,-2H,0,freeEnd
222.0052 19100.0
223.0104 1610.0
225.501 2770.0
235.0259 2320.0
236.9696 14500.0

Annotations:

B ?1D-GlcN,p/#bcleavage--4a14uHexA,p--2?1S$MONO,Und,-H,0,freeEnd
238.4945 57400.0
238.5936 87.3
238.9956 11000.0
239.4931 7580.0
239.5584 237.0
240.016 9050.0

Annotations:

Z freeEnd--??1D-GlcN,p(((--4a14uHexA,p/#zcleavage)--N?1S/#lcleavage)--6?1S/#lcleavage)--3?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
241.0028 4010.0
244.9381 408.0
246.4919 5000.0
247.5114 3300000.0

Annotations:

freeEnd--??1D-GlcN,p(((--4a14uHexA,p--2?1S/#lcleavage)--N?1S/#lcleavage)--6?1S/#lcleavage)--3?1S/#lcleavage}(--??1S)--??1S$MONO,Und,-2H,0,freeEnd
248.2009 642.0
249.0011 38400.0
249.4993 15100.0
250.5183 385.0
251.6116 29.2
252.9632 64.4
254.9195 248.0

Annotations:

C ?1D-GlcN,p/#ccleavage--4a14uHexA,p--2?1S$MONO,Und,-H,0,freeEnd
254.9824 46500.0

Annotations:

C ?1D-GlcN,p/#ccleavage--4a14uHexA,p--2?1S$MONO,Und,-H,0,freeEnd
255.9839 3990.0
256.1557 167.0
256.9789 2910.0
258.0297 36300.0

Annotations:

^{0,2}A_{GlcN} ?1D-GlcN,p/#acleavage_0_2((--4a14uHexA,p--2?1S)--6?1S)--3?1S$MONO,Und,-2H,0,freeEnd Y freeEnd--??1D-GlcN,p(((--4a14uHexA,p/#ycleavage)--N?1S/#lcleavage)--6?1S/#lcleavage)--3?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
258.997 415.0
260.9423 821.0

Annotations:

^{2,5}A_{GlcN} ?1D-GlcN,p/#acleavage_2_5((--4a14uHexA,p--2?1S/#lcleavage)--6?1S/#lcleavage)--3?1S/#lcleavage$MONO,Und,-H,0,freeEnd
262.9741 2360.0
268.0156 6050.0
269.4696 1040.0
278.4765 41000.0
278.9776 7900.0
279.4753 7210.0
279.5359 291.0
279.9757 988.0
282.0312 3780.0
282.3152 287.0
283.0133 365.0
283.2666 5760.0
283.3701 100.0
284.2671 765.0
286.4742 4720.0
287.4961 6480000.0

Annotations:

freeEnd--??1D-GlcN,p(((--4a14uHexA,p--2?1S/#lcleavage)--N?1S/#lcleavage)--6?1S/#lcleavage)--3?1S/#lcleavage}((--??1S)--??1S)--??1S$MONO,Und,-2H,0,freeEnd
287.624 140000.0

Annotations:

freeEnd--??1D-GlcN,p(((--4a14uHexA,p--2?1S/#lcleavage)--N?1S/#lcleavage)--6?1S/#lcleavage)--3?1S/#lcleavage}((--??1S)--??1S)--??1S$MONO,Und,-2H,0,freeEnd
287.9082 1440.0
287.9972 893000.0
288.4195 1170.0
288.4951 850000.0
290.4861 13000.0
290.9876 2420.0
295.0177 1230.0
297.0516 11700.0

Annotations:

^{2,4}A_{GlcN} ?1D-GlcN,p/#acleavage_2_4(--4a14uHexA,p--2?1S/#lcleavage)--3?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
300.0444 30300.0
300.4472 333.0
301.0456 3830.0
302.0111 71.3
308.9439 863.0
309.0523 7350.0
310.9273 649.0

Annotations:

^{3,5}A_{GlcN} ?1D-GlcN,p/#acleavage_3_5(--4a14uHexA,p--2?1S/#lcleavage)--6?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
311.0578 1420.0

Annotations:

^{3,5}A_{GlcN} ?1D-GlcN,p/#acleavage_3_5(--4a14uHexA,p--2?1S/#lcleavage)--6?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
311.2278 1550.0

Annotations:

^{3,5}A_{GlcN} ?1D-GlcN,p/#acleavage_3_5(--4a14uHexA,p--2?1S/#lcleavage)--6?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
312.0453 1040.0
313.2454 906.0
318.0712 653.0
318.1725 65.9
326.194 29700.0

Annotations:

^{1,4}A_{GlcN} ?1D-GlcN,p/#acleavage_1_4((--4a14uHexA,p--2?1S/#lcleavage)--N?1S/#lcleavage)--3?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
326.8545 1310.0

Annotations:

^{0,3}A_{GlcN} ?1D-GlcN,p/#acleavage_0_3(--4a14uHexA,p--2?1S/#lcleavage)--6?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
326.9381 6550.0

Annotations:

^{0,3}A_{GlcN} ?1D-GlcN,p/#acleavage_0_3(--4a14uHexA,p--2?1S/#lcleavage)--6?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
327.1857 54800.0

Annotations:

^{0,3}A_{GlcN} ?1D-GlcN,p/#acleavage_0_3(--4a14uHexA,p--2?1S/#lcleavage)--6?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd freeEnd--??1D-GlcN,p(((--4a14uHexA,p--2?1S)--N?1S)--6?1S)--3?1S$MONO,Und,-2H,0,freeEnd
327.4804 1870000.0

Annotations:

freeEnd--??1D-GlcN,p(((--4a14uHexA,p--2?1S)--N?1S)--6?1S)--3?1S$MONO,Und,-2H,0,freeEnd
327.971 316000.0
328.0423 29100.0
328.1833 12800.0
328.4693 357000.0
328.9671 53800.0
329.0386 5180.0
329.1909 9820.0
329.3682 114.0
329.4645 33000.0
329.9656 7900.0
330.1375 2830.0
330.4679 9480.0
330.7699 788.0
331.0261 2360.0
336.0475 11600.0

Annotations:

freeEnd--??1D-GlcN,p(((--4a14uHexA,p--2?1S/#lcleavage)--N?1S/#lcleavage)--6?1S/#lcleavage)--3?1S/#lcleavage$MONO,Und,-H,0,freeEnd
336.9285 77.0
337.9937 6310.0

Annotations:

Y freeEnd--??1D-GlcN,p(((--4a14uHexA,p/#ycleavage)--N?1S/#lcleavage)--6?1S/#lcleavage)--3?1S/#lcleavage}(--??1S)--??1S$MONO,Und,-H,0,freeEnd
339.0098 2990.0
353.872 85.0
354.0591 13900.0
355.0624 2190.0
357.0238 59200.0

Annotations:

^{0,2}A_{GlcN} ?1D-GlcN,p/#acleavage_0_2((--4a14uHexA,p--2?1S/#lcleavage)--6?1S/#lcleavage)--3?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
358.0261 8500.0
359.0219 3950.0
370.0528 339.0

Annotations:

^{1,5}A_{GlcN} ?1D-GlcN,p/#acleavage_1_5(((--4a14uHexA,p--2?1S/#lcleavage)--N?1S/#lcleavage)--6?1S/#lcleavage)--3?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
380.0409 30100.0
380.8165 90.0
381.0421 4460.0
382.0374 2050.0
383.0443 380.0
396.0339 851.0
397.9758 546.0
398.0621 372000.0
398.1414 1100.0
399.0565 55000.0
399.3352 189.0
400.0528 22900.0

Annotations:

Z freeEnd--??1D-GlcN,p(((--4a14uHexA,p/#zcleavage)--N?1S)--6?1S)--3?1S$MONO,Und,-H,0,freeEnd
400.699 130.0
401.0549 2920.0
404.4586 173.0
414.0502 443.0
415.0538 1480.0
415.8692 91.0

Annotations:

freeEnd--??1D-GlcN,p(((--4a14uHexA,p--2?1S/#lcleavage)--N?1S/#lcleavage)--6?1S/#lcleavage)--3?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
417.9559 1740.0

Annotations:

Y freeEnd--??1D-GlcN,p(((--4a14uHexA,p/#ycleavage)--N?1S)--6?1S)--3?1S$MONO,Und,-H,0,freeEnd
434.0161 472.0
460.0016 2240.0
478.0159 164000.0
478.0962 713.0
479.0145 25800.0
480.0105 19000.0
480.8798 124.0
481.0121 2200.0
481.7512 146.0
482.0109 1410.0
483.021 126.0
484.0219 767.0
557.97 76500.0
558.0546 296.0
558.971 12100.0
559.1306 51.9
559.5306 126.0
559.9672 12200.0
560.9686 1590.0
561.9626 945.0

There are not related spectra

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 654.93
(Calculated Monoisotopic)

Reducing End: Free reducing end

Persubstitution: Underivatised

Biological Context

N/A

HPLC

Column

Method

  • gradient with 0.1 ml/min run rate
  • water
  • water

Mass Spec

Waters Synapt G2-S HDMS

MIRAGE Structural data

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