Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd

Stress impairs skin barrier function and induces α2-3 linked N-acetylneuraminic acid and core 1 O-glycans on skin mucins in Atlantic salmon, Salmo salar

GlyTouCan Accession Number: Loading...

Peak Intensity
392.47 0.1
417.19 0.0
476.83 0.1

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
477.12 0.0
478.36 0.1
502.8 0.1
507.23 0.1
511.09 0.0
511.37 0.0
519.1 0.3
519.69 0.0
537.1 2.3
537.79 0.0
555.32 0.1
562.87 0.1
563.32 0.1
567.13 0.1
567.36 0.1
581.13 19.3

Annotations:

B ?1D-GalNAc,p/#bcleavage--6a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
582.16 0.1
596.92 0.1
597.25 0.1

Annotations:

^{2,4}X_{Gal}Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_2_4)--6a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
615.24 0.3

Annotations:

^{2,4}X_{Gal}Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_2_4)--6a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{0,4}X_{GalNAc} redEnd--??1D-GalNAc,p/#xcleavage_0_4--3b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
615.49 0.1
615.84 0.0
631.27 0.1
637.17 0.0
639.28 0.1

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
652.91 0.0
656.85 0.3
657.27 2.6

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
657.96 0.0
673.27 0.2
674.14 0.0
675.24 95.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
676.08 0.2
677.27 0.3
677.84 0.0
717.33 0.1
727.05 0.1

Annotations:

Z^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
744.83 0.0

Annotations:

^{0,2}X_{NeuAc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
792.24 0.1
810.48 0.0
816.4 0.1
828.26 0.1
840.43 0.1
842.5 0.1
851.12 0.0
862.05 0.1
872.29 0.3
872.84 0.0
888.34 0.1
891.05 0.0
903.79 0.1
904.05 0.2
904.43 0.2
904.66 0.0
906.04 0.2
906.34 0.3

Annotations:

^{2,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_2_4)--6a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
906.61 0.2
912.21 0.1
922.32 7.1
923.17 0.0
930.26 0.3
931.05 0.5
931.6 0.0
948.28 11.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
949.21 0.1
952.04 0.1
964.23 0.1
966.25 94.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
967.46 0.0
967.74 0.1
968.3 0.0
968.59 0.1
992.99 0.0
1034.24 0.1
1036.34 0.0
1041.44 0.1
1057.31 0.1
1063.41 0.1
1096.28 0.1
1109.33 0.0
1112.89 0.1
1136.0 0.0
1140.3 0.0
1169.45 0.0
1179.12 0.2
1179.68 0.0
1185.34 0.1
1195.42 0.8
1197.05 0.0
1197.53 0.1
1213.18 0.9
1213.45 0.6
1213.88 0.3
1214.43 0.0
1221.08 0.1
1221.48 0.1
1301.51 0.1

There are 2 similar spectra:

Id Structure Score

7217

1.00

7636

0.79

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1256.44
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Salmo Salar
Tissue - Mucus

HPLC

Column Hypercarb

Method

  • 40 min gradient with 10 ul/min run rate
  • 10 mM (NH4)HCO3 in water
  • 10 mM (NH4)HCO3 in 80% acetontirile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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