Structure

    redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p)--??1S)--??1S$MONO,Und,-2H,0,redEnd

Sulfation of O-glycans on mucin-type proteins from serous ovarian epithelial tumors

GlyTouCan Accession Number: Loading...

Peak Intensity
196.84 0.2
241.07 0.9

Annotations:

BY ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
261.53 6.1

Annotations:

CZ ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S)--??1S$MONO,Und,-2H,0,redEnd BY ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S)--??1S$MONO,Und,-2H,0,redEnd
281.97 0.2

Annotations:

BY ?1D-Gal,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-Gal,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
315.3 0.1

Annotations:

ZZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-2H,0,redEnd
328.5 0.2
332.55 0.2

Annotations:

CY ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-2H,0,redEnd
342.48 2.1

Annotations:

B ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p)--??1S)--??1S$MONO,Und,-2H,0,redEnd
343.05 0.3
343.42 0.2
351.51 0.3

Annotations:

C ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p)--??1S)--??1S$MONO,Und,-2H,0,redEnd
352.81 0.2
372.98 0.1

Annotations:

C ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p)--??1S/#lcleavage)--??1S/#lcleavage$MONO,Und,-2H,0,redEnd
374.04 0.1

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S/#lcleavage$MONO,Und,-2H,0,redEnd
379.53 0.4
393.7 0.3
415.14 0.1
431.11 0.2
443.57 0.3
444.07 11.8

Annotations:

B ?1D-Gal,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd BY ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-H,0,redEnd B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p)--??1S)--??1S$MONO,Und,-2H,0,redEnd
445.08 2.2
446.06 0.3
454.29 0.3
462.13 1.1

Annotations:

C ?1D-Gal,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd CY ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CY ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-H,0,redEnd
463.38 0.2
464.27 0.3
465.13 0.1

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S)--??1S$MONO,Und,-2H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S)--??1S$MONO,Und,-2H,0,redEnd
465.7 0.2

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S)--??1S$MONO,Und,-2H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S)--??1S$MONO,Und,-2H,0,redEnd
466.13 0.2
474.02 0.2
474.67 0.4

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S)--??1S$MONO,Und,-2H,0,redEnd
475.06 0.2

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S)--??1S$MONO,Und,-2H,0,redEnd
489.28 0.4
496.69 0.4
505.21 0.3
516.32 0.3
525.04 0.3
525.55 0.3
526.22 0.3

Annotations:

B ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p)--??1S/#lcleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
534.03 0.3
535.6 0.2
538.95 0.1
545.57 0.2
545.75 0.2
546.63 0.3

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S)--??1S$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p)--??1S)--??1S$MONO,Und,-2H,0,redEnd
548.08 0.2
555.63 18.0

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S)--??1S$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p)--??1S)--??1S$MONO,Und,-2H,0,redEnd
556.14 7.2
556.61 4.3

Annotations:

redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p)--??1S/#lcleavage)--??1S/#lcleavage$MONO,Und,-2H,0,redEnd
557.2 0.4

Annotations:

redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p)--??1S/#lcleavage)--??1S/#lcleavage$MONO,Und,-2H,0,redEnd
564.7 0.2
574.73 0.2
575.33 0.2
576.11 0.1
576.51 0.2
576.8 0.2
577.63 0.2
584.23 0.2
588.62 0.2
592.04 0.1
592.98 0.2
597.71 0.3
606.17 0.5

Annotations:

B ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p)--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-H,0,redEnd
607.01 0.4
643.71 0.2
649.48 0.2

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
666.12 0.2
667.16 1.1

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
667.9 0.2
668.18 0.4
708.1 0.2
725.95 0.8
726.22 1.0
791.29 0.1
809.24 0.6

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p)--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-H,0,redEnd
809.49 0.3

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p)--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-H,0,redEnd
810.25 0.6
811.72 0.2

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
827.3 0.8

Annotations:

C ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p)--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-H,0,redEnd
827.99 0.3
828.31 0.3
829.23 1.5

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
830.42 0.3
869.4 0.2
870.31 1.1

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-H,0,redEnd
871.04 0.2
871.34 0.2
899.45 0.3
955.85 0.1
1014.27 6.8

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p)--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-H,0,redEnd
1015.37 1.4
1016.08 0.9
1016.4 1.0
1032.41 2.3

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p(--??1D-Gal,p)--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-H,0,redEnd
1033.45 0.8
1034.29 0.9
1034.81 0.2
1175.26 0.2
1176.26 0.6
1177.38 0.5

There are 3 similar spectra:

Id Structure Score

6664

0.86

3520

0.84

6663

0.82

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1273.34
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Homo Sapiens
Tissue - Cyst Fluid

HPLC

Column

Method

  • 100 min gradient with approx 3-5 ul/min (static split from 250 ul/min) run rate
  • 10 mM (NH4)HCO3
  • 10 mM (NH4)HCO3 in 80% acetonitrile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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