Structure

    redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1S$MONO,Und,-2H,0,redEnd

Sulfation of O-glycans on mucin-type proteins from serous ovarian epithelial tumors

GlyTouCan Accession Number: Loading...

Peak Intensity
204.05 1.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
219.95 0.4

Annotations:

CY ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
222.1 0.4

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
222.99 0.2
240.95 7.1

Annotations:

B ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p--??1S$MONO,Und,-H,0,redEnd
241.96 0.5
242.94 0.3

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-2H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-2H,0,redEnd
258.91 0.5

Annotations:

C ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p--??1S$MONO,Und,-H,0,redEnd
261.49 12.9

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1S$MONO,Und,-2H,0,redEnd
261.99 2.4

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1S$MONO,Und,-2H,0,redEnd
262.49 1.8
281.98 0.1

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
290.05 0.2
301.2 0.1
315.09 0.2
323.98 0.3

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-2H,0,redEnd
333.05 1.5

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-2H,0,redEnd
333.47 0.2

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-2H,0,redEnd
334.13 0.4
342.99 0.5
343.52 0.3
352.42 0.2
360.86 0.9
361.13 0.8
362.05 0.4
362.99 0.1
363.49 0.6
364.05 2.5

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1S$MONO,Und,-2H,0,redEnd B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
364.54 0.8

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1S$MONO,Und,-2H,0,redEnd B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
365.04 0.3
367.14 0.1
373.04 96.8

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1S$MONO,Und,-2H,0,redEnd
373.54 29.5

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1S$MONO,Und,-2H,0,redEnd
374.04 15.2

Annotations:

redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1S/#lcleavage$MONO,Und,-2H,0,redEnd
381.93 0.2

Annotations:

C ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
384.05 0.2

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
393.19 0.1
393.53 0.2
394.07 0.5
394.56 0.2
395.12 0.1
407.19 0.2

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
409.0 0.4
409.37 0.2
410.02 1.8
410.66 0.3
411.11 0.6
414.05 0.5

Annotations:

redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-2H,0,redEnd
414.56 0.2

Annotations:

redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-2H,0,redEnd
417.98 0.1
424.08 2.9
424.57 0.7
425.15 0.5

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
426.41 0.2
426.92 0.4
431.39 0.1
433.02 1.2
433.82 0.3
435.25 0.3
436.23 0.6
437.03 0.3
439.19 0.2
439.63 0.2
440.21 0.3
444.04 14.5

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-H,0,redEnd
445.03 4.0
445.52 1.2
446.02 1.1
462.03 7.0

Annotations:

C ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-H,0,redEnd
463.08 1.1
464.08 2.5
465.06 0.4
504.04 0.9
505.17 0.3

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
506.19 0.2
534.06 4.7
535.06 0.9
536.2 0.3
546.9 0.1
547.25 0.2
589.25 0.2
589.97 0.1
607.18 0.6
608.11 0.2
624.09 0.2
631.07 1.3
631.99 0.3
632.36 0.1
649.12 46.7

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-H,0,redEnd
650.11 10.8
651.13 4.0
667.12 25.1

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1S/#lcleavage}--??1S$MONO,Und,-H,0,redEnd
668.13 6.2
669.12 2.2
751.18 0.2
793.29 0.2
811.15 4.2
812.15 1.3
813.06 0.4
813.33 0.1

There are 4 similar spectra:

Id Structure Score

1.00

6667

0.80

0.80

0.70

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 908.20
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Homo Sapiens
Tissue - Cyst Fluid

HPLC

Column

Method

  • 100 min gradient with approx 3-5 ul/min (static split from 250 ul/min) run rate
  • 10 mM (NH4)HCO3
  • 10 mM (NH4)HCO3 in 80% acetonitrile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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