Structure

    redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p@270)--4b1D-GalNAc,p--3b1D-Gal,p$MONO,Und,-H,0,redEnd

A-series gangliosides inhibit TGF-β-induced epithelial-mesenchymal transition via TRI degradation

GlyTouCan Accession Number: Loading...

Peak Intensity
290.04 63524.0

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuAc,p@270$MONO,Und,-H,0,redEnd
325.17 4013.0

Annotations:

YZ redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#ycleavage@270)--4b1D-GalNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#zcleavage@270)--4b1D-GalNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
343.05 37463.0

Annotations:

YY redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#ycleavage@270)--4b1D-GalNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
364.11 6573.0

Annotations:

B b1D-Gal,p/#bcleavage--4b1D-GalNAc,p--3b1D-Gal,p$MONO,Und,-H,0,redEnd
364.31 7573.0

Annotations:

B b1D-Gal,p/#bcleavage--4b1D-GalNAc,p--3b1D-Gal,p$MONO,Und,-H,0,redEnd
395.14 1572.0

Annotations:

^{0,2}X_{NeuAc}Z redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#xcleavage_0_2@270)--4b1D-GalNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
452.09 1462.0

Annotations:

BY ?1D-Glc,p/#bcleavage--4b1D-Gal,p(--3a2D-NeuAc,p@270)--4b1D-GalNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-Glc,p/#ccleavage--4b1D-Gal,p(--3a2D-NeuAc,p@270)--4b1D-GalNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
510.15 7509.0

Annotations:

ZZ redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#zcleavage@270)--4b1D-GalNAc,p--3b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
510.3 10395.0

Annotations:

ZZ redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#zcleavage@270)--4b1D-GalNAc,p--3b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
528.02 2895.0

Annotations:

YZ redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#ycleavage@270)--4b1D-GalNAc,p--3b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#zcleavage@270)--4b1D-GalNAc,p--3b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
528.18 9156.0

Annotations:

YZ redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#ycleavage@270)--4b1D-GalNAc,p--3b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#zcleavage@270)--4b1D-GalNAc,p--3b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
616.07 6315.0

Annotations:

Z redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p@270)--4b1D-GalNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
634.25 6337.0

Annotations:

Y redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p@270)--4b1D-GalNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
690.25 2279.0

Annotations:

Z redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#zcleavage@270)--4b1D-GalNAc,p--3b1D-Gal,p$MONO,Und,-H,0,redEnd
708.21 98417.0

Annotations:

Y redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#ycleavage@270)--4b1D-GalNAc,p--3b1D-Gal,p$MONO,Und,-H,0,redEnd
778.34 3071.0

Annotations:

^{0,2}X_{NeuAc} redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#xcleavage_0_2@270)--4b1D-GalNAc,p--3b1D-Gal,p$MONO,Und,-H,0,redEnd
819.44 4442.0

Annotations:

Z redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p@270)--4b1D-GalNAc,p--3b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd

There are 20 similar spectra:

Id Structure Score

6829

1.00

6849

1.00

6867

1.00

6885

1.00

6903

1.00

6921

1.00

6939

1.00

6975

1.00

6993

1.00

6838

0.93

6858

0.93

6876

0.93

6894

0.93

6912

0.93

6930

0.93

6948

0.93

6966

0.93

6984

0.93

7002

0.93

6843

0.81

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 998.36
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

N/A

HPLC

Column Hypercarb

Method

  • 73min gradient with 0,6ul/min run rate
  • 10mM ammonium bicarbonate
  • 60% ACN, 10mM ammonium bicarbonate

Mass Spec

Bruker Daltonik amaZon Speed ETD ETD

MIRAGE Structural data

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