Structure

    redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p@270)--4b1D-GalNAc,p--3b1D-Gal,p(--3a2D-NeuAc,p@270)--4b1D-GalNAc,p$MONO,Und,-H,0,redEnd

A-series gangliosides inhibit TGF-β-induced epithelial-mesenchymal transition via TRI degradation

GlyTouCan Accession Number: Loading...

Peak Intensity
290.07 6352.0

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuAc,p@270$MONO,Und,-H,0,redEnd
343.25 564.0

Annotations:

YY redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#ycleavage@270)--4b1D-GalNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
549.28 478.0

Annotations:

BZ b1D-Gal,p/#bcleavage--4b1D-GalNAc,p--3b1D-Gal,p(--3a2D-NeuAc,p/#zcleavage@270)--??1D-GalNAc,p$MONO,Und,-H,0,redEnd
567.22 346.0

Annotations:

BY b1D-Gal,p/#bcleavage--4b1D-GalNAc,p--3b1D-Gal,p(--3a2D-NeuAc,p/#ycleavage@270)--??1D-GalNAc,p$MONO,Und,-H,0,redEnd CZ b1D-Gal,p/#ccleavage--4b1D-GalNAc,p--3b1D-Gal,p(--3a2D-NeuAc,p/#zcleavage@270)--??1D-GalNAc,p$MONO,Und,-H,0,redEnd
673.16 325.0

Annotations:

CY ?1D-Glc,p/#ccleavage--4b1D-Gal,p(--3a2D-NeuAc,p@270)--4b1D-GalNAc,p--3b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd CY b1D-Gal,p/#ccleavage--4b1D-GalNAc,p--3b1D-Gal,p(--3a2D-NeuAc,p@270)--??1D-GalNAc,p/#ycleavage$MONO,Und,-H,0,redEnd C b1D-GalNAc,p/#ccleavage--3b1D-Gal,p(--3a2D-NeuAc,p@270)--??1D-GalNAc,p$MONO,Und,-H,0,redEnd
858.35 828.0

Annotations:

B b1D-Gal,p/#bcleavage--4b1D-GalNAc,p--3b1D-Gal,p(--3a2D-NeuAc,p@270)--??1D-GalNAc,p$MONO,Und,-H,0,redEnd
876.25 804.0

Annotations:

C b1D-Gal,p/#ccleavage--4b1D-GalNAc,p--3b1D-Gal,p(--3a2D-NeuAc,p@270)--??1D-GalNAc,p$MONO,Und,-H,0,redEnd
893.5 1243.0

Annotations:

YZ redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#ycleavage@270)--4b1D-GalNAc,p--3b1D-Gal,p(--3a2D-NeuAc,p/#zcleavage@270)--??1D-GalNAc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#zcleavage@270)--4b1D-GalNAc,p--3b1D-Gal,p(--3a2D-NeuAc,p/#ycleavage@270)--??1D-GalNAc,p$MONO,Und,-H,0,redEnd
911.36 4044.0

Annotations:

YY redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#ycleavage@270)--4b1D-GalNAc,p--3b1D-Gal,p(--3a2D-NeuAc,p/#ycleavage@270)--??1D-GalNAc,p$MONO,Und,-H,0,redEnd
999.38 908.0

Annotations:

YY redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#ycleavage@270)--4b1D-GalNAc,p--3b1D-Gal,p(--3a2D-NeuAc,p@270)--??1D-GalNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p@270)--4b1D-GalNAc,p--3b1D-Gal,p(--3a2D-NeuAc,p/#ycleavage@270)--??1D-GalNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1184.36 2929.0

Annotations:

Z redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p@270)--4b1D-GalNAc,p--3b1D-Gal,p(--3a2D-NeuAc,p/#zcleavage@270)--??1D-GalNAc,p$MONO,Und,-H,0,redEnd
1202.5 20437.0

Annotations:

Y redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p/#ycleavage@270)--4b1D-GalNAc,p--3b1D-Gal,p(--3a2D-NeuAc,p@270)--??1D-GalNAc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-Glc,p--4b1D-Gal,p(--3a2D-NeuAc,p@270)--4b1D-GalNAc,p--3b1D-Gal,p(--3a2D-NeuAc,p/#ycleavage@270)--??1D-GalNAc,p$MONO,Und,-H,0,redEnd

There are 8 similar spectra:

Id Structure Score

6840

1.00

6860

1.00

6878

1.00

6896

1.00

6914

1.00

6932

1.00

6950

1.00

7643

0.82

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1492.53
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

N/A

HPLC

Column Hypercarb

Method

  • 73min gradient with 0,6ul/min run rate
  • 10mM ammonium bicarbonate
  • 60% ACN, 10mM ammonium bicarbonate

Mass Spec

Bruker Daltonik amaZon Speed ETD ETD

MIRAGE Structural data

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