Structure

    a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p)--4b1D-Gal,p$MONO,perMe,Na,0,PA

Occurrence of a D-arabinose-containing complex-type free-N-glycan in the urine of cancer patients

GlyTouCan Accession Number: Loading...

200.0300.0400.0500.0600.0m/z0.0204060801.0e+2Abundance
Peak Intensity
194.09 0.3
197.01 0.4

Annotations:

B b1D-GlcNAc,p/#bcleavage--3b1D-Ara,p$MONO,perMe,Na,0,PA
203.99 0.7
213.02 0.2
215.02 6.5

Annotations:

C b1D-GlcNAc,p/#ccleavage--3b1D-Ara,p$MONO,perMe,Na,0,PA
216.04 0.3

Annotations:

C b1D-GlcNAc,p/#ccleavage--3b1D-Ara,p$MONO,perMe,Na,0,PA
218.0 0.9

Annotations:

BZZ a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#zcleavage)--4b1D-Gal,p/#zcleavage$MONO,perMe,Na,0,PA
220.06 1.1
227.02 0.5
236.05 4.3

Annotations:

BYZ a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#ycleavage)--4b1D-Gal,p/#zcleavage$MONO,perMe,Na,0,PA BZY a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#zcleavage)--4b1D-Gal,p/#ycleavage$MONO,perMe,Na,0,PA
237.08 0.1

Annotations:

BYZ a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#ycleavage)--4b1D-Gal,p/#zcleavage$MONO,perMe,Na,0,PA BZY a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#zcleavage)--4b1D-Gal,p/#ycleavage$MONO,perMe,Na,0,PA
241.07 4.6

Annotations:

B b1D-GlcNAc,p/#bcleavage--4b1D-Gal,p$MONO,perMe,Na,0,PA
242.12 0.2
243.14 0.2
257.12 3.3

Annotations:

^{2,4}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_2_4(--3b1D-Ara,p)--4b1D-Gal,p/#ycleavage$MONO,perMe,Na,0,PA
259.09 77.1

Annotations:

C b1D-GlcNAc,p/#ccleavage--4b1D-Gal,p$MONO,perMe,Na,0,PA
260.11 6.2

Annotations:

C b1D-GlcNAc,p/#ccleavage--4b1D-Gal,p$MONO,perMe,Na,0,PA
261.05 0.2
272.98 0.1
297.17 0.1

Annotations:

^{2,5}A_{GlcNAc}Z b1D-GlcNAc,p/#acleavage_2_5(--3b1D-Ara,p)--4b1D-Gal,p/#zcleavage$MONO,perMe,Na,0,PA
301.12 3.9

Annotations:

^{2,4}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_2_4(--3b1D-Ara,p/#ycleavage)--4b1D-Gal,p$MONO,perMe,Na,0,PA
329.18 5.0

Annotations:

^{3,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_3_5--4b1D-Gal,p$MONO,perMe,Na,0,PA
330.13 0.4

Annotations:

^{3,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_3_5--4b1D-Gal,p$MONO,perMe,Na,0,PA
336.12 0.1

Annotations:

BZ^{0,3}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#zcleavage)--4b1D-Gal,p/#xcleavage_0_3$MONO,perMe,Na,0,PA B^{0,4}X_{GlcNAc}Z a1D-Man,p/#bcleavage--4b1D-GlcNAc,p/#xcleavage_0_4(--3b1D-Ara,p)--4b1D-Gal,p/#zcleavage$MONO,perMe,Na,0,PA
338.29 0.3
340.16 0.6

Annotations:

BY^{1,4}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#ycleavage)--4b1D-Gal,p/#xcleavage_1_4$MONO,perMe,Na,0,PA B^{3,5}X_{GlcNAc} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p/#xcleavage_3_5--3b1D-Ara,p$MONO,perMe,Na,0,PA ^{2,5}A_{GlcNAc}Z b1D-GlcNAc,p/#acleavage_2_5(--3b1D-Ara,p/#zcleavage)--4b1D-Gal,p$MONO,perMe,Na,0,PA
350.27 0.1
353.05 0.3

Annotations:

BZ^{3,5}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#zcleavage)--4b1D-Gal,p/#xcleavage_3_5$MONO,perMe,Na,0,PA
354.19 0.6

Annotations:

BY^{0,3}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#ycleavage)--4b1D-Gal,p/#xcleavage_0_3$MONO,perMe,Na,0,PA B^{0,4}X_{GlcNAc}Y a1D-Man,p/#bcleavage--4b1D-GlcNAc,p/#xcleavage_0_4(--3b1D-Ara,p)--4b1D-Gal,p/#ycleavage$MONO,perMe,Na,0,PA
355.2 1.4
362.1 0.1
366.09 0.2

Annotations:

BZ^{1,3}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#zcleavage)--4b1D-Gal,p/#xcleavage_1_3$MONO,perMe,Na,0,PA BZ^{2,4}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#zcleavage)--4b1D-Gal,p/#xcleavage_2_4$MONO,perMe,Na,0,PA
367.19 0.1

Annotations:

^{1,4}A_{GlcNAc}Z b1D-GlcNAc,p/#acleavage_1_4(--3b1D-Ara,p/#zcleavage)--4b1D-Gal,p$MONO,perMe,Na,0,PA
368.22 16.1

Annotations:

^{1,4}A_{GlcNAc}Z b1D-GlcNAc,p/#acleavage_1_4(--3b1D-Ara,p/#zcleavage)--4b1D-Gal,p$MONO,perMe,Na,0,PA
369.24 1.6

Annotations:

BY^{3,5}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#ycleavage)--4b1D-Gal,p/#xcleavage_3_5$MONO,perMe,Na,0,PA
380.21 2.0

Annotations:

B^{0,4}X_{GlcNAc}Z a1D-Man,p/#bcleavage--4b1D-GlcNAc,p/#xcleavage_0_4(--3b1D-Ara,p/#zcleavage)--4b1D-Gal,p$MONO,perMe,Na,0,PA BZ^{0,4}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#zcleavage)--4b1D-Gal,p/#xcleavage_0_4$MONO,perMe,Na,0,PA
381.15 0.5

Annotations:

B^{0,4}X_{GlcNAc}Z a1D-Man,p/#bcleavage--4b1D-GlcNAc,p/#xcleavage_0_4(--3b1D-Ara,p/#zcleavage)--4b1D-Gal,p$MONO,perMe,Na,0,PA BZ^{0,4}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#zcleavage)--4b1D-Gal,p/#xcleavage_0_4$MONO,perMe,Na,0,PA
382.3 0.3

Annotations:

^{1,5}A_{GlcNAc}Z b1D-GlcNAc,p/#acleavage_1_5(--3b1D-Ara,p)--4b1D-Gal,p/#zcleavage$MONO,perMe,Na,0,PA
383.15 0.2

Annotations:

^{1,5}A_{GlcNAc}Z b1D-GlcNAc,p/#acleavage_1_5(--3b1D-Ara,p)--4b1D-Gal,p/#zcleavage$MONO,perMe,Na,0,PA
383.34 0.2

Annotations:

BY^{1,3}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#ycleavage)--4b1D-Gal,p/#xcleavage_1_3$MONO,perMe,Na,0,PA BY^{2,4}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#ycleavage)--4b1D-Gal,p/#xcleavage_2_4$MONO,perMe,Na,0,PA
384.26 1.3

Annotations:

BY^{1,3}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#ycleavage)--4b1D-Gal,p/#xcleavage_1_3$MONO,perMe,Na,0,PA BY^{2,4}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#ycleavage)--4b1D-Gal,p/#xcleavage_2_4$MONO,perMe,Na,0,PA
385.21 0.5

Annotations:

^{1,4}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_1_4(--3b1D-Ara,p/#ycleavage)--4b1D-Gal,p$MONO,perMe,Na,0,PA
385.62 0.1

Annotations:

^{1,4}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_1_4(--3b1D-Ara,p/#ycleavage)--4b1D-Gal,p$MONO,perMe,Na,0,PA
394.25 8.4
395.15 0.9
396.09 0.2
398.22 1.2

Annotations:

B^{0,4}X_{GlcNAc}Y a1D-Man,p/#bcleavage--4b1D-GlcNAc,p/#xcleavage_0_4(--3b1D-Ara,p/#ycleavage)--4b1D-Gal,p$MONO,perMe,Na,0,PA BY^{0,4}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#ycleavage)--4b1D-Gal,p/#xcleavage_0_4$MONO,perMe,Na,0,PA
399.21 1.0

Annotations:

^{1,5}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_1_5(--3b1D-Ara,p)--4b1D-Gal,p/#ycleavage$MONO,perMe,Na,0,PA
400.25 0.3

Annotations:

^{1,5}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_1_5(--3b1D-Ara,p)--4b1D-Gal,p/#ycleavage$MONO,perMe,Na,0,PA
410.24 18.2

Annotations:

BZ a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p)--4b1D-Gal,p/#zcleavage$MONO,perMe,Na,0,PA
411.27 2.2
412.26 3.7
413.27 0.5
422.24 0.6
426.23 0.2

Annotations:

^{1,5}A_{GlcNAc}Z b1D-GlcNAc,p/#acleavage_1_5(--3b1D-Ara,p/#zcleavage)--4b1D-Gal,p$MONO,perMe,Na,0,PA
428.29 2.3

Annotations:

BY a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p)--4b1D-Gal,p/#ycleavage$MONO,perMe,Na,0,PA
429.26 0.2
430.35 0.5
431.28 1.2
432.28 0.2
433.38 0.2
442.21 2.1
443.32 0.2

Annotations:

^{1,5}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_1_5(--3b1D-Ara,p/#ycleavage)--4b1D-Gal,p$MONO,perMe,Na,0,PA
449.28 0.7
454.27 23.4

Annotations:

BZ a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#zcleavage)--4b1D-Gal,p$MONO,perMe,Na,0,PA
455.29 4.9

Annotations:

B^{1,5}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p)--4b1D-Gal,p/#xcleavage_1_5$MONO,perMe,Na,0,PA
456.28 33.9

Annotations:

B^{1,5}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p)--4b1D-Gal,p/#xcleavage_1_5$MONO,perMe,Na,0,PA
457.3 5.8
470.42 0.5
471.19 0.4
472.29 32.9

Annotations:

BY a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p/#ycleavage)--4b1D-Gal,p$MONO,perMe,Na,0,PA
473.31 6.6
473.98 0.1
474.39 0.4

Annotations:

^{2,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_4(--3b1D-Ara,p)--4b1D-Gal,p$MONO,perMe,Na,0,PA
489.41 0.2
496.12 0.2
496.51 0.1
499.92 0.1

Annotations:

B^{2,5}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p)--4b1D-Gal,p/#xcleavage_2_5$MONO,perMe,Na,0,PA
500.38 0.3

Annotations:

B^{2,5}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p)--4b1D-Gal,p/#xcleavage_2_5$MONO,perMe,Na,0,PA
501.33 0.7
540.33 0.3
542.35 1.2
543.46 0.6

Annotations:

B^{3,5}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p)--4b1D-Gal,p/#xcleavage_3_5$MONO,perMe,Na,0,PA
548.31 0.3

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2(--3b1D-Ara,p)--4b1D-Gal,p$MONO,perMe,Na,0,PA
570.37 5.5
571.39 2.4

Annotations:

B^{0,4}X_{GlcNAc} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p/#xcleavage_0_4(--3b1D-Ara,p)--4b1D-Gal,p$MONO,perMe,Na,0,PA B^{0,4}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p)--4b1D-Gal,p/#xcleavage_0_4$MONO,perMe,Na,0,PA
572.36 106.9

Annotations:

B^{0,4}X_{GlcNAc} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p/#xcleavage_0_4(--3b1D-Ara,p)--4b1D-Gal,p$MONO,perMe,Na,0,PA B^{0,4}X_{Gal} a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p)--4b1D-Gal,p/#xcleavage_0_4$MONO,perMe,Na,0,PA
573.37 24.7
574.45 0.7
575.36 8.7
576.36 1.5
586.51 0.1
591.51 0.1
600.34 1.7
601.28 0.4
604.42 39.1
605.4 10.5
606.55 0.6
616.42 1.2
646.44 8.6

Annotations:

B a1D-Man,p/#bcleavage--4b1D-GlcNAc,p(--3b1D-Ara,p)--4b1D-Gal,p$MONO,perMe,Na,0,PA

There are not related spectra

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 621.32
(Calculated Monoisotopic)

Reducing End: 2-Aminopyridine

Persubstitution: Per-methylation

Biological Context

Taxonomy - Homo Sapiens
Tissue - Urine

HPLC

Column

Method

  • 14min gradient with 0.05ml/min run rate
  • 5mM Acetic acid/Triethylamine (pH6.0)
  • 50% acetonitrile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

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