Structure

    redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p)--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p$MONO,Und,-H,0,redEnd

Protein N-glycosylation in the airways of long-term smokers with or without COPD differs from never-smokers

GlyTouCan Accession Number: Loading...

Peak Intensity
279.96 0.3
281.04 0.8

Annotations:

^{0,2}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_0_2--4b1D-Man,p--?a1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd
287.13 0.4
290.32 0.2
302.24 0.2
305.07 0.3
308.11 0.9
316.94 0.2
326.21 0.2
329.03 0.2
340.94 5.3

Annotations:

C b1D-GlcNAc,p/#ccleavage--4b1D-Man,p--?a1D-Man,p$MONO,Und,-H,0,redEnd
346.14 0.3

Annotations:

BZ b1D-GlcNAc,p/#bcleavage--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p/#zcleavage$MONO,Und,-H,0,redEnd
350.13 26.7

Annotations:

Z redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p)--4b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
351.09 2.0

Annotations:

Z redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p)--4b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
364.94 0.2

Annotations:

BY b1D-GlcNAc,p/#bcleavage--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-GlcNAc,p/#ccleavage--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p/#zcleavage$MONO,Und,-H,0,redEnd
365.24 0.2
365.9 0.6
368.2 6.5

Annotations:

Y redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p)--4b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
369.07 0.2

Annotations:

Y redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p)--4b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
371.07 0.2
377.11 0.2
383.11 15.7

Annotations:

CY b1D-GlcNAc,p/#ccleavage--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd ^{2,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_4--4b1D-Man,p--?a1D-Man,p$MONO,Und,-H,0,redEnd
384.06 0.9

Annotations:

^{2,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_4--4b1D-Man,p--?a1D-Man,p$MONO,Und,-H,0,redEnd
389.14 2.8

Annotations:

ZZ redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p/#zcleavage)--4b1D-GlcNAc,p--4b1D-Man,p/#zcleavage$MONO,Und,-H,0,redEnd
407.02 0.4

Annotations:

^{2,4}A_{GlcNAc}Z b1D-GlcNAc,p/#acleavage_2_4--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p/#zcleavage)--4b1D-GlcNAc,p--4b1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p/#ycleavage)--4b1D-GlcNAc,p--4b1D-Man,p/#zcleavage$MONO,Und,-H,0,redEnd
407.32 0.5

Annotations:

ZY redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p/#zcleavage)--4b1D-GlcNAc,p--4b1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p/#ycleavage)--4b1D-GlcNAc,p--4b1D-Man,p/#zcleavage$MONO,Und,-H,0,redEnd
408.11 3.7

Annotations:

ZY redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p/#zcleavage)--4b1D-GlcNAc,p--4b1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p/#ycleavage)--4b1D-GlcNAc,p--4b1D-Man,p/#zcleavage$MONO,Und,-H,0,redEnd
414.9 0.2
421.28 0.3

Annotations:

^{3,5}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_3_5(--6a1L-Fuc,p)--4b1D-GlcNAc,p--4b1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd
425.09 1.1

Annotations:

^{2,4}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_2_4--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p/#ycleavage)--4b1D-GlcNAc,p--4b1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd
426.25 0.6

Annotations:

^{2,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_5--4b1D-Man,p--?a1D-Man,p$MONO,Und,-H,0,redEnd
437.79 0.4

Annotations:

^{0,3}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_0_3(--6a1L-Fuc,p)--4b1D-GlcNAc,p--4b1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd
442.8 0.3

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2--4b1D-Man,p--?a1D-Man,p$MONO,Und,-H,0,redEnd
448.15 0.3
448.34 0.3
449.11 0.3
463.11 0.3
464.13 0.3
466.0 0.4
466.5 0.2
487.76 0.2
490.79 0.3
493.42 0.3
508.29 0.2
509.23 0.2
511.26 0.7
526.16 7.0

Annotations:

B b1D-GlcNAc,p/#bcleavage--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p$MONO,Und,-H,0,redEnd
527.12 0.9

Annotations:

B b1D-GlcNAc,p/#bcleavage--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p$MONO,Und,-H,0,redEnd
528.14 0.9
551.27 0.2

Annotations:

ZZ redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p/#zcleavage)--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p/#zcleavage$MONO,Und,-H,0,redEnd
553.16 17.7

Annotations:

Z redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p)--4b1D-GlcNAc,p--4b1D-Man,p/#zcleavage$MONO,Und,-H,0,redEnd
554.57 0.3
558.24 0.3
569.11 0.6

Annotations:

ZY redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p/#zcleavage)--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p/#ycleavage)--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p/#zcleavage$MONO,Und,-H,0,redEnd
570.24 3.2

Annotations:

Y redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p)--4b1D-GlcNAc,p--4b1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd
571.99 0.2

Annotations:

Y redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p)--4b1D-GlcNAc,p--4b1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd
600.05 1.2

Annotations:

^{0,3}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_0_3(--6a1L-Fuc,p)--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd
600.28 1.2

Annotations:

^{0,3}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_0_3(--6a1L-Fuc,p)--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd
601.07 0.3

Annotations:

^{0,3}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_0_3(--6a1L-Fuc,p)--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd
611.17 0.7
629.26 0.4

Annotations:

^{0,2}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_0_2(--6a1L-Fuc,p)--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd
642.39 0.2
647.18 1.0
671.27 3.2
672.17 0.3
673.34 0.2
689.26 23.2
690.28 2.2
691.07 0.3
691.52 0.2
700.16 0.3
703.69 0.4
707.28 0.2
713.71 0.2
721.69 0.2
731.22 45.3

Annotations:

Z redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p/#zcleavage)--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p$MONO,Und,-H,0,redEnd
732.15 3.6

Annotations:

Z redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p/#zcleavage)--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p$MONO,Und,-H,0,redEnd
732.5 1.0

Annotations:

Y redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p)--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd
733.35 1.3

Annotations:

Y redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p)--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p/#ycleavage$MONO,Und,-H,0,redEnd
734.47 0.2
735.36 0.2
750.16 0.6

Annotations:

Y redEnd--?b1D-GlcNAc,p(--6a1L-Fuc,p/#ycleavage)--4b1D-GlcNAc,p--4b1D-Man,p--?a1D-Man,p$MONO,Und,-H,0,redEnd
751.31 0.3
788.48 0.2
793.32 0.2
794.65 0.3
797.59 0.3
801.3 0.2
834.89 0.8
835.21 4.5
835.46 3.4
836.27 2.0
837.35 0.2
846.08 0.2
851.87 0.3
853.29 25.7
854.42 2.7
854.66 0.9
863.82 0.5
865.13 0.2

There are 9 similar spectra:

Id Structure Score

7770

1.00

7800

1.00

3535

0.98

7543

0.98

7704

0.96

4090

0.94

0.93

4002

0.86

5017

0.73

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 894.35
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Homo Sapiens
Tissue - Bronchoalveolar Lavage Fluid

HPLC

Column

Method

  • 78 min gradient with approx 3-5 ul/min (static split from 250 ul/min) run rate
  • 10 mM (NH4)HCO3
  • 10 mM (NH4)HCO3 in 80% acetonitrile

Mass Spec

N/A

MIRAGE Structural data

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