Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p$MONO,Und,-2H,0,redEnd

Ion Mobility-Tandem Mass Spectrometry of Mucin-type O-Glycans: from Healthy Sputum

The MS/MS data was generated after TIMS separation and retention time refers to CCS values in Ų

GlyTouCan Accession Number: Loading...

Peak Intensity
294.1328 2.2

Annotations:

^{1,4}X_{Gal}Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_1_4)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
404.088 2.4
426.0662 3.1

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ^{0,2}X_{Fuc}Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#xcleavage_0_2)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z^{0,2}X_{Fuc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#zcleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#xcleavage_0_2$MONO,Und,-2H,0,redEnd ^{0,2}X_{Fuc}Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#xcleavage_0_2)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
426.0922 3.1

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ^{0,2}X_{Fuc}Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#xcleavage_0_2)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z^{0,2}X_{Fuc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#zcleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#xcleavage_0_2$MONO,Und,-2H,0,redEnd ^{0,2}X_{Fuc}Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#xcleavage_0_2)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
432.4858 2.0
444.0862 8.4

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
444.3062 2.5
445.0844 2.1
462.0841 1.9

Annotations:

CY ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
462.0985 3.4

Annotations:

CY ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
504.1473 2.2

Annotations:

^{0,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd C^{0,2}X_{Fuc} ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
523.0445 2.1
534.1141 2.3

Annotations:

^{0,3}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_3--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd C^{0,3}X_{Fuc} ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#xcleavage_0_3$MONO,Und,-H,0,redEnd
534.1577 3.6

Annotations:

^{0,3}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_3--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd C^{0,3}X_{Fuc} ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#xcleavage_0_3$MONO,Und,-H,0,redEnd
554.1179 2.2
562.1576 1.7
571.1443 2.7
575.2462 2.0
590.1321 11.6

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
591.1361 3.5
608.1516 30.4

Annotations:

C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
609.1504 5.0
609.2952 2.4
610.1633 2.6
624.1427 5.6
631.1569 4.7

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
631.1743 4.1

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
631.212 3.8

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
649.1706 29.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
650.1694 11.9

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
650.1879 12.3

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
651.1497 4.5
651.1668 5.1
651.203 4.8
651.2298 2.1
652.161 3.7
667.1815 12.5

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{1,5}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_5(--3b1D-Gal,p--2a1L-Fuc,p)--6b1D-GlcNAc,p--3/4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
680.1622 12.1

Annotations:

^{0,3}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_3--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
680.2048 4.5

Annotations:

^{0,3}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_3--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
681.1674 3.8
715.2102 1.7

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p)--6b1D-GlcNAc,p--3/4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S/#lcleavage)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
734.1917 2.5
736.1916 4.3
756.2002 2.0
759.2238 3.9

Annotations:

^{1,5}X_{Fuc}Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#xcleavage_1_5)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S/#lcleavage)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd Z^{1,5}X_{Fuc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#zcleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S/#lcleavage)--2a1L-Fuc,p/#xcleavage_1_5$MONO,Und,-H,0,redEnd
759.2651 1.9

Annotations:

^{1,5}X_{Fuc}Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#xcleavage_1_5)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S/#lcleavage)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd Z^{1,5}X_{Fuc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#zcleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S/#lcleavage)--2a1L-Fuc,p/#xcleavage_1_5$MONO,Und,-H,0,redEnd
765.2108 3.8
770.21 31.9
770.2488 3.6
770.8584 1.9
771.2114 4.7
771.338 1.8
777.2158 14.6

Annotations:

^{1,5}X_{Fuc}Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#xcleavage_1_5)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S/#lcleavage)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd Y^{1,5}X_{Fuc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#ycleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S/#lcleavage)--2a1L-Fuc,p/#xcleavage_1_5$MONO,Und,-H,0,redEnd
777.2355 8.7

Annotations:

^{1,5}X_{Fuc}Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#xcleavage_1_5)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S/#lcleavage)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd Y^{1,5}X_{Fuc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#ycleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S/#lcleavage)--2a1L-Fuc,p/#xcleavage_1_5$MONO,Und,-H,0,redEnd
777.4956 2.4
778.2242 7.8
778.2518 4.3
779.247 2.4
779.3139 2.6
795.0345 2.8
795.2356 100.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
795.3184 5.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
795.4152 2.2
795.4596 2.2
795.5622 2.3
795.8753 2.1
796.1329 2.2
796.2374 38.0
796.2972 2.3
796.41 3.0
796.4575 1.9
797.2261 16.0
797.2506 6.3
798.3954 2.1
811.2315 8.2

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#ycleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#zcleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
812.2256 5.4
813.2395 11.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
813.263 6.9

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
814.2307 3.8
814.254 3.3
815.2618 2.1
856.239 2.1

Annotations:

^{2,5}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_2_5(--3b1D-Gal,p--2a1L-Fuc,p)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{2,5}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_2_5(--3b1D-Gal,p--2a1L-Fuc,p/#ycleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
916.2576 12.7
916.2874 2.5
918.2465 2.8
918.3036 1.8
957.2903 20.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#zcleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
957.347 2.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#zcleavage)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
958.2962 10.8
958.3307 4.3
959.2779 1.7
959.3057 4.6
1061.3428 2.3

Annotations:

^{1,3}X_{Fuc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#xcleavage_1_3$MONO,Und,-H,0,redEnd ^{2,4}X_{Fuc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd ^{1,3}X_{Fuc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#xcleavage_1_3)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd ^{2,4}X_{Fuc} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--2a1L-Fuc,p/#xcleavage_2_4)--6b1D-GlcNAc,p--3/4b1D-Gal,p(--3/6?1S)--2a1L-Fuc,p$MONO,Und,-H,0,redEnd
1179.3767 1.7

There are not related spectra

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1120.36
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Homo Sapiens
Tissue - Sputum

Mass Spec

N/A

MIRAGE Structural data

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