Structure

    redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-2H,0,redEnd

Ion Mobility-Tandem Mass Spectrometry of Mucin-type O-Glycans: from Cystic Fibrosis Sputum

The MS/MS data was generated after TIMS separation and retention time refers to CCS values in Ų

GlyTouCan Accession Number: Loading...

Peak Intensity
254.2418 11.0
290.0828 14.8

Annotations:

B b1D-Gal,p/#bcleavage--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd ^{1,5}X_{Gal}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_1_5)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd
291.2046 7.6
291.3413 12.9

Annotations:

^{3,5}A_{GalNAc}Y a1D-GalNAc,p/#acleavage_3_5--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd
345.6012 25.5
470.089 7.9

Annotations:

C b1D-GlcNAc,p/#ccleavage--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
470.1366 22.1

Annotations:

C b1D-GlcNAc,p/#ccleavage--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
470.4602 8.5
502.1505 7.6
522.1907 21.8
554.1298 12.9
655.2131 89.7

Annotations:

BY a1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#ycleavage)--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd CZ a1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#zcleavage)--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd ^{1,3}X_{Fuc}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#xcleavage_1_3)--3/4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ^{2,4}X_{Fuc}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#xcleavage_2_4)--3/4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ^{0,4}X_{Gal}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_0_4)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ^{1,3}X_{Gal}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_1_3)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ^{2,4}X_{Gal}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_2_4)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
655.237 13.2

Annotations:

BY a1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#ycleavage)--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd CZ a1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#zcleavage)--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd ^{1,3}X_{Fuc}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#xcleavage_1_3)--3/4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ^{2,4}X_{Fuc}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#xcleavage_2_4)--3/4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ^{0,4}X_{Gal}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_0_4)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ^{1,3}X_{Gal}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_1_3)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ^{2,4}X_{Gal}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_2_4)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
659.138 15.8

Annotations:

^{0,3}X_{Fuc}Y redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#xcleavage_0_3)--3/4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd ^{3,5}X_{Gal}Y redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_3_5)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
667.1939 23.7

Annotations:

^{1,5}A_{GalNAc}Z a1D-GalNAc,p/#acleavage_1_5(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
699.238 31.9

Annotations:

C^{0,4}X_{NeuAc} a1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd
801.2876 44.8

Annotations:

Z^{0,2}X_{NeuAc} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#zcleavage)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd B a1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd Z^{2,5}X_{NeuAc} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#xcleavage_2_5$MONO,Und,-H,0,redEnd
814.4825 8.5
817.3085 15.8

Annotations:

Z^{2,5}X_{NeuAc} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#zcleavage)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#xcleavage_2_5$MONO,Und,-H,0,redEnd ^{1,3}X_{Fuc}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#xcleavage_1_3)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ^{2,4}X_{Fuc}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#xcleavage_2_4)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ^{0,4}X_{Gal}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_0_4)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ^{1,3}X_{Gal}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_1_3)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ^{2,4}X_{Gal}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_2_4)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
819.2853 100.0

Annotations:

C a1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd ^{3,5}X_{Fuc}Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#xcleavage_3_5)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd Y^{0,2}X_{NeuAc} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#ycleavage)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd Y^{2,5}X_{NeuAc} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#xcleavage_2_5$MONO,Und,-H,0,redEnd
819.8336 13.2
820.2814 33.8
825.3917 11.7
831.3716 17.4

Annotations:

Z^{0,3}X_{NeuAc} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#zcleavage)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#xcleavage_0_3$MONO,Und,-H,0,redEnd Z^{3,5}X_{NeuAc} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#xcleavage_3_5$MONO,Und,-H,0,redEnd
832.3544 13.9
842.3017 11.0

Annotations:

ZZ redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#zcleavage)--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
911.3292 21.5
981.3372 63.8

Annotations:

^{2,5}X_{NeuAc} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#xcleavage_2_5$MONO,Und,-H,0,redEnd
981.3621 14.8

Annotations:

^{2,5}X_{NeuAc} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p/#xcleavage_2_5$MONO,Und,-H,0,redEnd
982.361 12.6
983.3555 19.2
987.7284 8.9
1006.3536 14.5

Annotations:

Z redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1024.3676 13.9

Annotations:

Y redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1025.0412 14.2
1126.4458 23.6

Annotations:

^{1,3}X_{Fuc} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#xcleavage_1_3)--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd ^{2,4}X_{Fuc} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p/#xcleavage_2_4)--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd ^{0,4}X_{Gal} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_0_4)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd ^{1,3}X_{Gal} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_1_3)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd ^{2,4}X_{Gal} redEnd--?a1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_2_4)--6b1D-GlcNAc,p(--3/4a1L-Fuc,p)--3/4b1D-Gal,p--3/6a2D-NeuAc,p$MONO,Und,-H,0,redEnd

There are 1 similar spectra:

Id Structure Score

7963

0.63

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1185.44
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Homo Sapiens
Tissue - Sputum

Mass Spec

N/A

MIRAGE Structural data

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