Structure

    redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
244.0 4.9
246.74 2.5
262.03 2.8

Annotations:

^{2,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_4--3b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
262.96 48.4
263.99 3.1
281.01 15.2

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2--4b1D-Gal,p$MONO,Und,-H,0,redEnd
304.01 8.4
305.0 10.5
310.99 2.7
317.01 5.9
329.09 5.0
341.07 5.5
345.94 3.4
347.1 31.3
348.08 3.1
353.1 9.6
364.07 117.7

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
365.05 22.3
366.12 2.8
371.09 8.2
382.07 27.8

Annotations:

C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
382.99 7.4
384.08 8.2
389.08 561.4

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
390.08 127.1
392.34 2.7
396.07 16.3
405.11 8.7
406.03 4.6
407.12 177.7

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
408.08 28.0
424.09 123.3

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
424.57 5.9
425.1 44.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
426.09 4.3
438.1 10.0
449.11 3.5
456.03 11.4
467.07 5.4
474.12 38.4
474.52 5.0
475.1 6.7
486.15 2.5
491.09 25.2
492.22 4.3
509.13 94.0
521.13 121.2
521.71 3.1
522.14 27.1
527.16 276.6

Annotations:

^{2,4}X_{GalNAc} redEnd--??1D-GalNAc,p/#xcleavage_2_4--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
528.15 68.5
533.13 92.1
533.66 5.3
534.11 27.0
541.13 16.0
542.18 2.7
545.19 11.5
550.16 71.0
551.15 142.7
552.14 22.5
567.18 3.9
568.17 6.9
569.18 8061.7

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
570.17 1775.5
571.24 17.0
571.75 4.6
587.17 735.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd
588.18 166.9
589.08 3.2
592.17 17.7
593.06 3.2
610.19 227.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
610.65 9.8
611.19 48.2
628.19 54.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
629.19 17.7
640.16 2.7
670.27 3.9
671.31 3.4
681.14 2.5
687.03 2.4
688.09 2.4
689.25 3.6
691.06 2.4
725.06 3.9
729.14 2.6
730.21 552.3
731.21 162.2
731.86 5.1
747.67 2.6
748.24 65.5
749.2 24.7
754.17 7.3
755.24 6.6
755.62 2.5
760.22 6.2
761.22 2.6
761.99 3.2
791.17 3.1

There are 7 similar spectra:

Id Structure Score

3757

0.99

5564

0.98

5779

0.97

6723

0.97

7998

0.70

5684

0.58

5202

0.54

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 789.32
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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