Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1HexNAc,p)--6b1HexNAc,p)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
291.98 1.0
311.91 1.9
324.05 1.8
328.03 0.9
330.04 0.7
346.04 24.7

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd BZ ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
346.42 1.2
346.93 0.9
364.08 22.9

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd BY ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
365.02 0.6

Annotations:

^{2,4}X_{GalNAc} redEnd--??1D-GalNAc,p/#xcleavage_2_4--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
385.0 1.0
389.14 3.2
401.18 0.8
407.08 15.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
408.02 0.7
409.21 1.1
425.19 28.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
426.04 5.4
429.91 0.9
437.18 2.3
464.06 0.5
478.96 2.8
479.2 2.6
495.81 0.9
527.42 1.3

Annotations:

^{0,4}X_{Gal}Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_0_4--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{2,4}X_{Gal}Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_2_4--6b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{0,4}X_{GalNAc}Y redEnd--??1D-GalNAc,p/#xcleavage_0_4--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{0,4}X_{GalNAc}Y redEnd--??1D-GalNAc,p/#xcleavage_0_4--3b1D-Gal,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
532.96 1.3
550.65 1.4
551.19 1.0

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
567.18 3.8

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
568.14 2.8
569.16 3.7

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
570.24 1.2
587.05 2.1

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
587.3 0.9
622.12 0.9
640.21 4.3
649.26 0.9
653.05 1.5
663.1 0.9
673.84 2.2
674.37 0.7
679.01 0.7
680.7 0.6
682.22 23.8
683.48 1.7
685.17 0.5
704.03 0.7
707.08 1.2
712.26 1.5
713.53 0.8
716.79 0.7
724.16 5.7
730.22 15.8

Annotations:

^{0,4}X_{GalNAc} redEnd--??1D-GalNAc,p/#xcleavage_0_4--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd ^{0,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_0_4--3b1D-GlcNAc,p)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd ^{2,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_2_4--6b1D-GlcNAc,p)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
731.19 3.8
752.6 0.6
772.22 15.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
773.27 2.9
790.23 57.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
791.18 22.8
799.77 2.4
811.25 1.6
817.09 0.6
823.5 0.9
831.0 1.6
836.94 4.3
847.75 0.7
852.1 0.7
860.29 2.9
863.11 1.8
885.94 1.4
886.25 1.6
886.74 1.2
892.33 2.0
894.27 0.5
894.57 0.6
895.08 6.8
896.9 1.5
921.17 2.3
927.34 1.7
930.96 1.1
931.77 1.0
933.3 23.7
934.36 7.1
934.76 2.0
937.96 0.7
940.19 3.2
942.89 0.7
945.69 0.7
949.28 1.5
951.24 7.9
952.32 0.9
952.55 1.1
954.56 1.8
957.0 0.5
958.03 2.5
959.06 2.0
966.03 3.1
992.94 1.5
994.19 1.0
995.08 0.6

There are 2 similar spectra:

Id Structure Score

5444

0.73

3978

0.53

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 992.40
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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