Structure

    redEnd--??1D-GalNAc,p--3?1HexNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
316.02 1.4
322.14 1.2
330.06 2.2
346.03 4.3

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--3?1HexNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
346.35 0.0
358.04 3.7
361.88 1.2
363.7 0.9
364.06 18.1

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3?1HexNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3?1HexNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
364.43 1.4
375.27 2.2
376.01 2.6
376.64 1.5
377.12 1.3
382.0 1.2

Annotations:

CY ?1D-GalNAc,p/#ccleavage--3?1HexNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
405.08 76.7

Annotations:

B ?1HexNAc,p/#bcleavage--6b1D-GlcNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
405.7 0.1
406.18 10.0
407.05 21.9

Annotations:

YZ redEnd--??1D-GalNAc,p--3?1HexNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p--3?1HexNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
407.37 0.2
408.06 3.1
423.06 2.9

Annotations:

C ?1HexNAc,p/#ccleavage--6b1D-GlcNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
425.15 11.1

Annotations:

YY redEnd--??1D-GalNAc,p--3?1HexNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
440.98 1.8
464.97 2.1

Annotations:

^{0,4}A_{HexNAc} ?1HexNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
465.26 0.0
479.08 13.6
479.71 2.6
480.05 0.8
481.64 0.4
485.27 1.4
521.21 0.7
527.14 13.6

Annotations:

^{0,4}X_{HexNAc} redEnd--??1D-GalNAc,p--3?1HexNAc,p/#xcleavage_0_4--3b1D-Gal,p$MONO,Und,-H,0,redEnd
545.25 0.5
549.05 4.5

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--3?1HexNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
550.01 2.7
567.06 7.3

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3?1HexNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3?1HexNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
567.44 1.6
569.07 13.8

Annotations:

Z redEnd--??1D-GalNAc,p--3?1HexNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
569.53 0.0
581.08 0.5
587.17 624.0

Annotations:

Y redEnd--??1D-GalNAc,p--3?1HexNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
588.15 91.8
588.9 0.9
589.08 0.5
608.34 4.7

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3?1HexNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3?1HexNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
608.72 0.1
627.06 3.1
627.39 1.7
627.68 0.0
628.22 2.2

Annotations:

YY redEnd--??1D-GalNAc,p--3?1HexNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
638.03 0.9
664.22 4.5
666.54 1.3
669.21 17.8
669.57 0.5
670.19 2.2
676.27 0.8
682.2 15.3
683.32 1.0
688.17 2.3
703.21 3.2
713.14 2.3
713.43 0.0
723.2 2.0
724.2 40.6
724.84 0.1
725.2 1.4
725.52 0.0
736.5 0.8
754.16 1.3
770.27 7.5

Annotations:

B ?1D-GalNAc,p/#bcleavage--3?1HexNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
770.67 0.1
771.27 2.7

Annotations:

^{2,4}X_{HexNAc} redEnd--??1D-GalNAc,p--3?1HexNAc,p/#xcleavage_2_4--6b1D-GlcNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
772.28 25.4

Annotations:

Z redEnd--??1D-GalNAc,p--3?1HexNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
772.81 8.2
773.25 6.2
778.06 0.9
790.35 8.6

Annotations:

Y redEnd--??1D-GalNAc,p--3?1HexNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
792.26 4.7
812.13 1.8
813.31 1.7

Annotations:

Z redEnd--??1D-GalNAc,p--3?1HexNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
832.18 2.2
839.21 0.8
843.44 4.8
843.66 1.1
859.05 1.0
861.67 1.8
878.23 1.4
885.2 2.5
895.02 1.4
917.27 1.3
933.42 2.8
950.4 1.5
951.16 2.8
951.41 4.9
957.23 0.9
958.09 3.0
958.43 0.0
962.47 0.9

There are 2 similar spectra:

Id Structure Score

0.95

0.95

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 992.40
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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