Structure

    redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

400.0600.0800.01000m/z0.02.0e+24.0e+26.0e+2Abundance
Peak Intensity
347.07 7.6
347.38 2.0
359.08 4.3
364.03 5.4

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
365.12 9.3

Annotations:

^{0,4}X_{GalNAc} redEnd--??1D-GalNAc,p/#xcleavage_0_4--3b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
371.12 2.8
389.07 18.4

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
407.12 588.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
408.1 108.0
408.76 2.7
409.25 1.9
416.05 3.4
425.12 129.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
425.63 2.1
426.11 14.4
426.74 2.4
434.04 4.5
468.13 4.2
470.13 2.7

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
479.14 22.0
494.06 6.1
509.24 1.9
510.18 4.1
512.17 1.9
536.1 11.7
550.11 5.3
551.34 2.2

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
568.15 10.3
569.17 13.5

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
570.15 2.4
587.23 4.1

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
592.21 5.7
610.19 151.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
611.16 34.5
628.22 135.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
629.22 28.0
629.79 2.3
630.16 3.3
653.11 3.7
654.15 5.9
655.24 7.2

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
670.17 3.6
674.15 5.5
684.22 2.6
689.32 1.9
696.16 8.7
697.2 2.3
724.24 4.3
726.23 2.8
730.25 25.3
731.25 3.3
738.25 12.7
739.2 4.1
740.2 3.2
748.24 6.1
749.23 2.5
752.3 2.7
768.24 6.5
772.27 18.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
773.34 3.3
782.26 1.8
786.23 50.6
787.19 8.9
789.2 3.1
790.26 503.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
791.25 119.9
791.79 4.1
794.61 1.8
817.3 2.8
820.79 2.3
835.17 4.0
842.26 2.5
843.26 2.1
860.26 34.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
861.24 11.3
878.19 4.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
878.48 3.2
879.2 11.5
880.43 3.1
883.23 4.7
884.37 2.7
919.32 2.8
931.29 2.0
973.25 9.3
974.24 2.5
977.25 2.9
997.29 4.6
999.8 1.9
1003.31 69.0
1004.28 27.3
1019.28 2.5
1021.32 99.9
1022.27 26.5
1027.26 4.4
1033.32 2.1
1037.34 28.1
1038.33 10.5
1045.32 22.2
1046.33 4.1
1050.32 2.9

There are 11 similar spectra:

Id Structure Score

5244

0.68

4252

0.68

6756

0.68

5401

0.68

0.68

5213

0.67

0.65

0.65

4882

0.60

0.60

5598

0.58

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1080.41
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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