Structure

    redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
347.08 71.6
364.07 178.2

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
365.09 86.0

Annotations:

^{2,4}X_{GalNAc} redEnd--??1D-GalNAc,p/#xcleavage_2_4--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
371.1 31.0
382.04 40.4

Annotations:

CY ?1D-GalNAc,p/#ccleavage--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
389.12 1351.5

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
390.07 193.9
404.07 28.0
406.07 28.0
407.13 1466.8

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
408.1 292.5
416.04 44.1
424.11 234.7

Annotations:

^{2,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_2_4--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
425.14 271.4

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
426.1 45.3
434.07 28.9
474.09 45.7
491.12 34.2
494.1 59.4
509.14 158.8
510.17 50.8
521.16 160.8
522.14 30.8
527.16 649.6

Annotations:

^{0,4}X_{GalNAc}Y redEnd--??1D-GalNAc,p/#xcleavage_0_4--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
528.13 135.5
533.17 127.0
536.11 97.9
545.21 40.4
550.2 161.1
551.16 314.7

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
552.13 58.0
565.16 47.5
568.22 80.2
569.19 11199.8

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
570.15 2409.3
587.2 1246.8

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
588.19 288.1
592.21 85.5
593.2 29.0
610.22 838.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
611.17 173.7
628.22 1359.9

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
629.18 297.7
654.22 28.0
668.19 45.6
671.2 52.4
696.19 215.5
697.18 73.9
730.25 557.4

Annotations:

^{2,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p/#xcleavage_2_4)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
731.24 129.8
738.23 123.0
739.23 40.7
748.24 80.1
749.24 30.0
752.27 62.1
756.27 43.1
768.21 79.4
772.26 652.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
773.24 177.7
774.29 70.5
782.23 107.6
783.24 35.1
786.22 537.0
787.18 119.1
790.26 6764.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
791.23 1743.0
791.82 39.9
800.24 110.6
801.26 37.7
816.29 411.3
817.3 93.2
832.26 31.5
834.28 75.6
842.25 483.6
843.25 130.8
859.25 92.6
860.25 573.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
861.27 192.7
878.27 149.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
879.26 154.1
880.24 42.6
883.28 112.2
884.27 48.7
961.32 42.1
962.29 29.4
973.29 80.2
974.28 42.8
977.35 52.8
985.36 55.8
986.25 31.0
997.31 65.1
1003.32 2301.8
1004.31 806.7
1020.26 39.3
1021.34 2170.3
1022.33 879.1
1037.35 160.3
1038.35 55.9
1045.3 266.8
1046.31 96.5

There are 8 similar spectra:

Id Structure Score

3770

0.97

5810

0.93

5213

0.52

0.52

0.52

5244

0.52

4252

0.52

6756

0.50

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1080.41
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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