Structure

    redEnd--??1D-GalNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
321.01 2.5
326.96 2.6
339.34 1.4
348.06 14.2

Annotations:

B ?1HexNAc,p/#bcleavage--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd
348.73 1.2
349.38 1.2
364.0 2.2
366.08 13.3

Annotations:

C ?1HexNAc,p/#ccleavage--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p--??1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
371.14 2.8
384.07 128.5

Annotations:

Y redEnd--??1D-GalNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
384.57 2.2
385.01 5.0
387.09 7.9
388.6 1.8
405.11 38.0
406.07 5.8
419.11 2.0
424.11 1.5
434.03 1.4
443.05 1.7
461.15 5.3
462.05 1.7
463.2 1.1
474.1 2.8
479.11 25.2
479.69 1.2
480.09 2.8
515.13 2.3
521.16 91.3
522.04 6.8
522.25 3.0
551.14 419.2

Annotations:

B ?1HexNAc,p/#bcleavage--??1HexNAc,p--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd
551.62 10.7
552.13 30.6
552.78 1.1
553.3 1.2
569.17 111.9

Annotations:

C ?1HexNAc,p/#ccleavage--??1HexNAc,p--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
569.76 1.7
570.26 6.5
570.55 1.6
587.17 56.8

Annotations:

Y redEnd--??1D-GalNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
587.63 1.9
588.04 4.8
588.36 1.9
590.14 11.9
608.18 7.8
616.04 4.0
623.18 1.1
628.11 1.5
646.27 3.4
655.07 1.1
664.19 1.2
666.26 4.1
670.2 1.7
676.14 6.0
706.27 4.6
707.19 1.2
718.14 5.9
724.32 1.6
736.25 12.4
736.68 5.5
754.24 2024.6

Annotations:

B ?1D-Gal,p/#bcleavage--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd
755.21 264.4
755.98 12.2
756.26 4.8
772.26 1.2

Annotations:

C ?1D-Gal,p/#ccleavage--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
790.28 9.3

Annotations:

Y redEnd--??1D-GalNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
796.14 2.0
828.08 1.3
829.29 1.4
830.14 2.7
832.19 2.5
835.24 1.1
860.3 1.0
895.03 2.4
916.3 5.8

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd
918.25 2.8
919.34 1.5
974.18 1.2
977.42 3.6
989.36 1.6
994.21 1.1
994.8 1.9
995.34 1.1
1007.18 2.2
1019.69 1.6
1031.31 2.3
1032.48 3.6
1038.37 1.5
1044.25 1.8
1051.63 1.1
1060.62 1.1
1064.2 3.0
1076.46 1.5
1079.36 9.5
1080.32 4.1
1092.41 1.3
1094.3 1.2
1097.35 2.6
1098.49 1.5

There are 2 similar spectra:

Id Structure Score

8033

1.00

8035

0.92

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1138.45
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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