Structure

    redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
347.07 8.8
364.06 24.7

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd BY b1D-GlcNAc,p/#bcleavage--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-GlcNAc,p/#ccleavage--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
365.12 10.0
382.06 8.2

Annotations:

CY ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CY b1D-GlcNAc,p/#ccleavage--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
389.08 147.4

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
389.61 10.7

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
390.07 17.5
405.1 142.2

Annotations:

B b1D-Gal,p/#bcleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
406.03 20.8

Annotations:

^{0,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
407.12 68.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
408.07 7.2
423.04 11.5

Annotations:

C b1D-Gal,p/#ccleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
424.08 27.9

Annotations:

^{0,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
425.11 28.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
448.09 5.4
474.12 6.2
491.16 7.1
509.15 25.6
510.17 6.1
521.12 30.0
521.48 4.2
522.09 7.7
527.18 111.7
528.15 17.4
533.14 18.4
545.18 15.8
546.18 4.4
550.18 82.7
551.15 49.6

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
567.17 20.7

Annotations:

B b1D-GlcNAc,p/#bcleavage--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
568.18 14.3

Annotations:

^{2,4}X_{GlcNAc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
569.19 2278.6

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
570.17 380.3
585.16 9.8

Annotations:

C b1D-GlcNAc,p/#ccleavage--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
586.23 4.7
587.19 274.5

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
588.18 42.6
592.17 4.9
610.19 62.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
611.11 12.1
627.17 62.6

Annotations:

^{2,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_4--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
628.18 67.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
629.2 7.3
646.16 5.7
664.21 37.4
665.11 12.3
665.33 5.6
669.19 77.7
670.13 12.6
682.1 5.0
687.19 12.0

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
688.2 10.8
694.28 5.0
706.24 44.7
707.22 7.9
712.21 6.6
724.26 19.3
725.26 7.0
730.26 388.4
731.24 94.2
731.75 4.6
736.14 7.0
736.38 6.1
748.25 74.3
748.74 8.0
749.24 21.9
754.23 50.9

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
755.27 13.8
772.26 44.7

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
773.34 10.3
789.39 4.1
790.25 2110.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
791.24 414.9
792.19 7.6
825.18 5.6
830.26 44.7

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
867.28 42.4
868.25 15.7
872.24 6.1
885.32 39.1
886.3 7.0
897.21 10.2
898.31 11.0
915.34 35.3
916.27 9.6
927.3 149.7
928.28 32.4
933.29 21.5
934.31 9.7
939.35 6.9
957.29 35.6
958.25 8.5
975.33 552.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
976.31 128.5
993.33 150.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
994.27 39.6
1136.4 180.0
1137.4 85.5
1154.4 82.4
1155.4 43.6

There are not related spectra

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1195.48
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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