Structure

    redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
178.95 136.6
201.98 98.4

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-GlcNAc,p$MONO,Und,-H,0,redEnd
263.0 124.9

Annotations:

Y^{2,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#xcleavage_2_4$MONO,Und,-2H,0,redEnd
272.02 102.6
290.03 11025.0

Annotations:

B a2D-NeuAc,p/#bcleavage--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
291.03 1376.4
292.01 157.2
308.04 282.9

Annotations:

C a2D-NeuAc,p/#ccleavage--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
364.06 155.4

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
380.09 161.7

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
382.06 99.5

Annotations:

CY ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
389.11 775.0

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
390.07 132.7
392.05 164.3
407.14 294.6

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
424.16 231.1

Annotations:

^{0,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
425.16 122.9

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
431.11 115.4
493.15 1148.9
494.11 234.7
509.14 115.9
511.17 100.9
519.13 185.6
521.13 184.7
527.15 258.5
533.17 110.7
537.17 289.3
538.17 71.8
540.11 119.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd
545.14 72.7
550.19 72.8
551.19 157.0

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
563.09 292.0
564.11 79.5
566.16 298.1
566.64 130.3
567.15 75.7
569.19 10366.4

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
570.18 2780.5
571.16 511.7
574.17 293.9
574.66 221.8
575.17 1467.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
575.66 777.1
576.16 221.4
579.15 172.7
580.16 74.0
581.16 21569.1

Annotations:

B ?1D-Gal,p/#bcleavage--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
582.13 5169.2
583.11 1035.7
584.16 613.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
584.65 387.4
585.19 158.9
585.62 75.9
587.2 1074.2

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
588.2 270.4
608.23 93.5
610.2 370.2

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
611.18 129.9
628.23 335.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
629.25 89.4
646.67 121.9
647.19 99.1
655.22 137.2

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
655.68 187.8
730.26 563.7

Annotations:

^{2,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
731.26 178.1
743.18 84.5

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
745.18 88.7
748.24 95.5
790.26 14962.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
791.24 4990.9
792.22 1200.0
793.34 75.6
842.2 73.3

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
845.26 183.9
846.21 80.0
860.25 725.2

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
861.22 254.1
862.24 80.6
878.31 78.5

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
946.27 314.0

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
947.31 79.1
1003.33 80.8
1018.28 249.0
1019.25 113.8
1063.34 427.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1064.34 190.2
1081.33 11954.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1082.31 5643.5
1083.3 1949.4
1084.3 175.8
1107.35 249.4
1108.32 127.7
1133.34 2147.9
1134.33 1133.0
1135.31 365.8
1150.36 181.7
1151.34 329.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1152.34 122.4

There are 1 similar spectra:

Id Structure Score

8058

0.90

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1371.51
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

Report errors in this entry

UniCarb-DR Creative Commons License

Supported by SIB ExPASy  |  JST / NBDCDICP