Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
219.71 5.5
220.02 9.2

Annotations:

C ?1HexNAc,p/#ccleavage--??1HexNAc,p$MONO,Und,-H,0,redEnd
292.03 5.7
321.96 4.6
323.05 9.2
364.03 16.1

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
364.52 3.7
365.96 3.7

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
382.03 9.0

Annotations:

CY ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
385.91 3.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-2H,0,redEnd
405.11 61.7

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
405.56 9.0
406.06 19.2

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
406.47 4.1
414.59 30.8
415.04 8.9

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
415.55 4.4
417.96 4.0
439.14 3.7
452.1 6.8
463.6 5.1
475.1 3.6
496.14 14.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
503.13 5.7
516.11 9.6
525.11 4.1
527.2 7.7
537.19 3.5
545.18 5.0
555.08 3.7
564.64 16.5
567.18 6.2

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
568.19 7.0
579.67 6.5
584.15 6.8
588.68 42.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
589.17 27.7
589.68 13.0
597.23 5.0
597.67 42.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
598.16 38.9
598.73 11.2
600.01 6.2
601.17 5.5
602.27 8.9
604.82 7.3
608.11 3.5

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
617.19 43.6
617.71 17.8
618.15 9.1
619.1 6.0
620.42 4.5
627.18 4.8

Annotations:

^{2,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
629.1 6.0
636.1 4.7
637.11 7.3
638.19 6.5
639.22 7.1
646.44 5.5
647.1 3.6
654.16 4.2
655.07 12.3
655.56 7.4
656.28 4.9
662.64 6.2
663.09 4.9
665.13 4.0
666.26 3.6
668.22 15.9

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
669.17 24.2
669.67 7.1
670.26 12.5
759.14 3.8
772.24 64.6

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
773.25 11.4
790.26 3.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
791.42 5.0
830.28 11.2
831.21 5.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
869.29 3.4
872.15 3.4
935.37 4.8
939.21 5.8
975.43 6.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
993.33 164.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
994.32 71.7
995.31 11.1
1032.26 3.6
1033.28 20.6
1034.28 5.4
1130.37 9.6
1136.41 4.5
1160.31 4.4
1161.55 3.4
1175.3 3.9
1178.4 85.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1179.39 36.0
1180.38 14.5
1196.34 10.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1197.46 4.2

There are 2 similar spectra:

Id Structure Score

8062

0.54

0.54

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1398.56
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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