Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
219.94 37.9

Annotations:

C ?1HexNAc,p/#ccleavage--??1HexNAc,p$MONO,Und,-H,0,redEnd
290.0 379.0

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
290.36 30.3
290.97 49.0
308.02 26.3
382.01 16.2

Annotations:

CY ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CY b1D-GlcNAc,p/#ccleavage--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
398.08 16.4
405.12 1277.1

Annotations:

B ?1D-Gal,p/#bcleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
406.11 230.1
406.48 16.0
407.12 434.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
408.08 77.1
425.13 74.5

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
438.66 21.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd
470.12 200.0

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
471.09 51.2
508.12 28.1
510.66 17.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-2H,0,redEnd
519.65 531.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd
520.17 257.7
520.62 71.3
536.11 42.2
567.18 67.8

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
567.68 35.5
568.14 36.2

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
569.17 65.8

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
570.19 15.6
587.16 28.1

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
588.16 140.2
588.66 81.6
589.07 23.6
591.2 29.2
600.3 17.6
612.16 124.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-2H,0,redEnd
612.71 85.9
613.18 30.5
621.19 491.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd
621.68 337.0
622.18 113.6
655.23 15.8
669.29 15.3
673.19 78.8
674.21 20.5
675.22 48.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
678.14 29.1
679.17 25.7
679.99 15.4
687.09 17.9
692.71 127.5
693.2 66.6
693.68 27.9
745.23 42.7
749.21 163.8

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
750.22 50.9
751.37 16.3
771.0 17.8
799.2 75.3
817.25 268.5
818.23 88.5
835.22 222.6
836.24 81.6
837.2 25.7
860.26 77.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
861.18 32.2
878.27 59.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
879.18 30.4
934.27 16.5

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
952.29 43.2

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
975.32 144.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
976.26 57.0
978.26 18.6
993.32 64.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
994.42 24.9
996.3 25.7
1004.31 37.1
1020.3 55.3
1021.24 47.3
1022.31 180.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1023.31 72.7
1024.29 15.1
1038.3 1063.3
1039.31 438.6
1040.33 3768.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1041.28 1720.0
1042.27 461.3
1042.89 35.8
1093.29 15.7
1095.39 21.0
1113.42 15.4
1135.33 45.8
1136.41 21.2
1155.38 605.9

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1156.38 251.9
1157.39 95.0
1207.37 22.3
1208.33 16.9
1225.37 402.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1226.36 271.7
1227.42 78.6
1243.36 33.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd

There are 1 similar spectra:

Id Structure Score

8070

0.89

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1445.54
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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