Structure

    redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p)--??1HexNAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
281.02 29.4
290.0 1042.6

Annotations:

B ?1D-Gal,p/#bcleavage--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
291.0 125.6

Annotations:

B ?1D-Gal,p/#bcleavage--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
347.11 44.1

Annotations:

BZ ?1D-Gal,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd BZ ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd BZ b1D-GlcNAc,p/#bcleavage--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
365.11 41.1

Annotations:

BY ?1D-Gal,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-Gal,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd BY b1D-GlcNAc,p/#bcleavage--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-GlcNAc,p/#ccleavage--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
382.05 66.2

Annotations:

CY ?1D-Gal,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd CY ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CY b1D-GlcNAc,p/#ccleavage--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
389.08 39.9

Annotations:

ZZ redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
399.05 29.4
405.08 111.6
407.11 1553.3

Annotations:

YZ redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
408.1 343.4

Annotations:

YZ redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd B b1D-GlcNAc,p/#bcleavage--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-2H,0,redEnd
425.13 335.9

Annotations:

YY redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
426.08 29.9

Annotations:

YY redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
445.9 57.0
452.07 28.0

Annotations:

B ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
461.9 35.0
470.1 31.4

Annotations:

C ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
479.98 33.7
508.13 119.8

Annotations:

BZ b1D-GlcNAc,p/#bcleavage--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
510.58 33.5

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-2H,0,redEnd
519.59 52.5

Annotations:

C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-2H,0,redEnd
520.09 29.5
526.12 68.5

Annotations:

BY b1D-GlcNAc,p/#bcleavage--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-GlcNAc,p/#ccleavage--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
536.12 167.8
537.05 44.1
554.07 70.2
567.15 94.6

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
567.65 82.2

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#zcleavage)--??1HexNAc,p$MONO,Und,-2H,0,redEnd
568.13 40.8

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#zcleavage)--??1HexNAc,p$MONO,Und,-2H,0,redEnd
577.11 39.8

Annotations:

Y redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-2H,0,redEnd
591.16 114.2
591.64 120.8
600.14 38.0
612.17 262.4

Annotations:

Z redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p)--??1HexNAc,p/#zcleavage$MONO,Und,-2H,0,redEnd
612.67 181.3

Annotations:

Z redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p)--??1HexNAc,p/#zcleavage$MONO,Und,-2H,0,redEnd
613.14 55.8

Annotations:

Z redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p)--??1HexNAc,p/#zcleavage$MONO,Und,-2H,0,redEnd
621.16 1383.2

Annotations:

Y redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p)--??1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd
621.67 721.9

Annotations:

Y redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p)--??1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd
622.17 339.9

Annotations:

Y redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p)--??1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd
622.7 32.6
655.07 39.8

Annotations:

B ?1D-Gal,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
655.62 45.0

Annotations:

B ?1D-Gal,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
656.15 35.6

Annotations:

B ?1D-Gal,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
657.14 35.8
672.15 28.2
673.18 236.6

Annotations:

C ?1D-Gal,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
674.18 75.2

Annotations:

C ?1D-Gal,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
679.15 42.6
691.81 29.4
692.18 42.2
692.7 556.0
693.16 279.7
693.68 161.0
694.13 33.7
745.23 134.8
775.19 35.7
781.18 28.9
790.22 30.4

Annotations:

YY redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
799.22 283.6
800.19 91.9
817.19 1078.2

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
818.19 385.3

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
819.15 115.3
835.21 861.0

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
836.2 338.2

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
837.2 117.4
844.25 30.5
952.29 105.2

Annotations:

YY redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#ycleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
953.23 33.8

Annotations:

YY redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#ycleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
975.26 54.3

Annotations:

Z redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
993.31 127.0

Annotations:

Y redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
994.3 69.8

Annotations:

Y redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
996.22 44.9
1004.29 61.1
1005.35 42.5
1020.28 282.5

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
1021.3 138.6

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
1022.3 89.7
1023.29 35.9
1038.29 4324.1

Annotations:

C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
1039.27 1979.9

Annotations:

C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
1040.25 833.6
1041.28 149.7
1042.3 53.8
1093.36 58.7
1095.36 65.2
1096.39 34.6
1103.35 29.2
1125.31 48.5
1135.36 167.1
1136.38 85.9
1137.36 46.7

Annotations:

Z redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
1155.36 1575.2

Annotations:

Y redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
1156.35 742.4

Annotations:

Y redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
1157.35 231.4
1225.37 191.4

Annotations:

Z redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1226.35 78.2

Annotations:

Z redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1227.36 30.3
1243.33 56.7

Annotations:

Y redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1244.37 59.7

Annotations:

Y redEnd--??1D-GalNAc,p(--6b1D-GlcNAc,p--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--??2D-NeuAc,p)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd

There are 1 similar spectra:

Id Structure Score

8068

0.98

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1445.54
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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