Structure

    redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1HexNAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
261.97 8.0

Annotations:

^{0,4}A_{Gal} b1D-Gal,p/#acleavage_0_4--6b1HexNAc,p$MONO,Und,-H,0,redEnd
289.99 284.3

Annotations:

B a2D-NeuAc,p/#bcleavage--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
290.41 10.3
290.94 42.1
307.99 12.2

Annotations:

C a2D-NeuAc,p/#ccleavage--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
346.03 19.0

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p(--3b1HexNAc,p/#zcleavage)--6b1HexNAc,p$MONO,Und,-H,0,redEnd
364.07 22.2

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p(--3b1HexNAc,p/#ycleavage)--6b1HexNAc,p$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p(--3b1HexNAc,p/#zcleavage)--6b1HexNAc,p$MONO,Und,-H,0,redEnd BY b1D-Gal,p/#bcleavage--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-Gal,p/#ccleavage--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
397.29 4.0
404.86 4.7
493.13 41.4
537.15 6.3
557.98 5.6
563.16 12.2

Annotations:

CY ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd
564.17 4.4
569.14 7.6

Annotations:

Z redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p/#zcleavage)--6b1HexNAc,p$MONO,Und,-H,0,redEnd
580.06 5.3
581.14 550.6

Annotations:

B ?1D-Gal,p/#bcleavage--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
582.12 140.0
583.16 26.2
587.16 28.5

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p/#ycleavage)--6b1HexNAc,p$MONO,Und,-H,0,redEnd
602.19 7.8
612.11 4.3

Annotations:

Z redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage)--6b1HexNAc,p$MONO,Und,-2H,0,redEnd
621.15 3.8

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage)--6b1HexNAc,p$MONO,Und,-2H,0,redEnd
622.17 4.0
624.21 3.8
635.72 5.9
636.58 4.9
637.67 6.5

Annotations:

BZ b1D-Gal,p/#bcleavage--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
645.57 6.0
656.18 15.4

Annotations:

Z redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1HexNAc,p/#zcleavage$MONO,Und,-2H,0,redEnd
656.68 13.4
657.22 4.0
663.17 6.0
665.15 20.1

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd
666.21 7.9
668.93 3.9
672.99 5.3

Annotations:

CY b1D-Gal,p/#ccleavage--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
674.73 6.4
678.12 4.0
679.06 3.9
682.59 7.5
694.5 5.9
695.57 5.7
700.08 4.5
703.17 4.4
704.11 7.9
704.69 11.0
705.17 5.5
706.04 5.8
712.17 6.2
713.16 6.9

Annotations:

ZZ redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
713.79 4.2
714.23 3.8
718.63 5.6
719.1 15.2
722.17 15.0
723.16 10.9
723.64 6.8
724.13 11.0
725.32 5.2
727.7 3.8
728.2 9.2
728.97 4.7

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1HexNAc,p$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1HexNAc,p$MONO,Und,-H,0,redEnd
731.07 6.8

Annotations:

YZ redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
734.19 35.1
736.13 11.6
736.67 21.5
737.14 9.0
790.23 5.1

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p/#ycleavage)--6b1HexNAc,p$MONO,Und,-H,0,redEnd
791.16 5.3
804.03 4.0
845.23 6.1
892.21 10.9

Annotations:

^{2,4}X_{Gal} redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p/#xcleavage_2_4)--6b1HexNAc,p$MONO,Und,-H,0,redEnd
911.28 11.1
920.01 3.9
934.05 4.0

Annotations:

Z redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1HexNAc,p$MONO,Und,-H,0,redEnd
935.29 4.0
946.23 78.7

Annotations:

B b1D-Gal,p/#bcleavage--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
947.28 27.2
948.23 11.3
949.24 6.8
952.3 699.1

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1HexNAc,p$MONO,Und,-H,0,redEnd
953.27 304.3
954.29 91.7
954.79 4.2
955.33 8.4
964.16 3.8

Annotations:

C b1D-Gal,p/#ccleavage--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1022.38 4.3

Annotations:

YZ redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage)--6b1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage)--6b1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1108.32 4.5

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1218.42 5.0
1225.32 13.2

Annotations:

Z redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage)--6b1HexNAc,p$MONO,Und,-H,0,redEnd
1226.04 8.9
1243.37 199.3

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage)--6b1HexNAc,p$MONO,Und,-H,0,redEnd
1244.34 144.6
1245.37 42.5
1295.39 4.5
1311.35 29.2

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1HexNAc,p$MONO,Und,-H,0,redEnd
1312.34 14.3
1313.39 6.3

Annotations:

Z redEnd--??1D-GalNAc,p--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1329.34 6.7

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p(--3b1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1HexNAc,p$MONO,Und,-H,0,redEnd

There are 1 similar spectra:

Id Structure Score

8072

0.98

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1533.56
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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