Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
248.0 12.1
323.01 12.6
341.04 7.3
345.99 9.5

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd BZ ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
364.05 14.8

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
365.12 8.3
405.11 404.1

Annotations:

B b1D-Gal,p/#bcleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
405.68 13.4
406.12 81.4
407.11 136.4

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p@360--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p@360--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
408.09 16.9
423.07 27.6

Annotations:

C b1D-Gal,p/#ccleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
425.16 16.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p@360--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
485.14 15.0
496.14 7.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p@360--??1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
503.12 7.3
504.09 10.6
515.12 9.7
515.62 13.3
515.99 8.8
530.09 7.4
552.71 12.2
567.11 7.5

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
568.16 11.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
575.12 9.1
577.16 146.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
577.68 67.8
578.17 27.3
585.17 14.7

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
596.1 19.0
596.6 51.4
597.1 31.8
616.74 7.8
617.15 22.1
617.66 17.7
618.16 12.7
624.72 33.2
625.11 13.3
627.19 38.1

Annotations:

^{2,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
627.65 10.0
628.2 13.3
645.7 44.9
646.19 37.0
646.77 10.7
647.2 9.9
648.05 13.5
649.06 7.6
665.14 12.8
668.16 15.6
669.19 135.7
669.65 48.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
670.21 39.1
670.7 9.3
671.19 10.9
677.16 12.5
678.71 63.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd
679.19 70.8
679.69 22.5
687.18 19.3
689.16 7.7
697.65 13.1
698.2 192.4
698.71 103.7
699.18 31.9
699.62 9.5
709.22 7.3
715.2 7.3
718.12 11.7
732.09 8.4
735.25 17.6
736.12 16.6
737.16 23.6
737.76 8.8
739.95 13.5
743.23 17.5
743.81 8.4
744.24 9.8
745.25 7.3
749.19 25.8

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
750.24 34.4
790.25 18.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p/#ycleavage@360$MONO,Und,-H,0,redEnd
809.63 20.0
810.26 7.4
975.24 32.6

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p@360--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
976.3 17.0
993.35 12.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p@360--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
994.34 8.9
1095.38 16.7
1137.36 17.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1138.28 13.8
1155.38 1150.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1156.36 575.9
1157.37 201.9
1158.25 32.6
1194.3 8.7
1292.47 22.2
1323.42 9.6
1340.46 37.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p@360--??1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1341.42 23.2
1342.48 9.2

There are 3 similar spectra:

Id Structure Score

0.96

0.96

8076

0.54

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1560.61
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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