Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
275.98 17.8

Annotations:

^{1,3}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_3--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd ^{3,5}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_3_5--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
290.0 106.4

Annotations:

^{1,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_4--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd B a2D-NeuGc,p/#bcleavage--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd B b1D-Gal,p/#bcleavage--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
290.99 22.4

Annotations:

^{1,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_4--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd B a2D-NeuGc,p/#bcleavage--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd B b1D-Gal,p/#bcleavage--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd ^{1,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_1_4--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
292.07 14.0

Annotations:

^{1,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_1_4--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd ^{0,3}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_3--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd ^{1,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_1_4--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{1,4}A_{GlcNAc}Y b1D-GlcNAc,p/#acleavage_1_4--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
306.01 9.6

Annotations:

BY b1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-Gal,p/#ccleavage--3a2D-NeuGc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
346.97 7.0

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
380.04 8.8

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd ^{1,4}A_{Gal} b1D-Gal,p/#acleavage_1_4--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
436.01 15.1

Annotations:

^{0,3}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_0_3--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
438.09 5.7

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd ^{3,5}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_3_5--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
468.08 45.9

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ^{0,2}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_2(--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
470.09 13.3

Annotations:

C b1D-GlcNAc,p/#ccleavage--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
478.12 7.7
530.24 8.2
530.69 6.1

Annotations:

^{0,2}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_0_2(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd
537.13 14.9
549.77 6.3
555.62 7.2

Annotations:

^{2,5}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_5--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
567.12 36.9
568.17 11.4

Annotations:

^{1,5}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_1_5(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd
569.14 6.9

Annotations:

^{1,5}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_1_5(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd ^{1,3}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_1_3--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
581.14 350.1

Annotations:

^{1,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_4--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
581.59 14.2

Annotations:

^{1,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_4--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
582.2 45.6

Annotations:

^{1,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_1_4--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd
587.23 9.9

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
597.12 57.0

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
598.15 8.7

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
609.13 5.7
632.24 5.7
635.12 9.0
647.21 9.8
658.16 459.4

Annotations:

^{1,3}A_{Gal} b1D-Gal,p/#acleavage_1_3--3a2D-NeuGc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd ^{2,4}A_{Gal} b1D-Gal,p/#acleavage_2_4--3a2D-NeuGc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
658.69 205.0
659.21 33.3
661.24 6.6
664.14 136.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
664.66 37.7

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
665.17 105.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
665.66 51.1
671.15 16.2
671.84 11.0
672.14 7.7
673.21 381.5

Annotations:

C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
673.67 211.0

Annotations:

C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
674.5 6.1
675.13 83.5
676.22 12.7
708.58 14.5
723.88 7.5
727.12 7.3
729.33 5.7

Annotations:

^{3,5}A_{GalNAc} ?1D-GalNAc,p/#acleavage_3_5--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
739.24 6.2
745.16 6.4

Annotations:

^{0,3}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_3--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
749.28 6.1

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
754.27 12.9
754.66 6.1
757.36 9.2
759.22 13.9

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd ^{2,5}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_5(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
774.34 10.2
775.11 12.6
782.41 31.4
782.76 7.6
783.34 17.3
788.16 13.2
878.28 57.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
879.33 13.9
942.28 7.8
962.23 51.7
962.51 7.6
964.23 13.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
964.42 7.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1002.16 6.4
1026.29 238.4
1026.89 9.9
1027.3 73.3
1038.28 101.4

Annotations:

ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1039.31 27.7

Annotations:

ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1040.3 204.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1040.9 6.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1041.22 33.9

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1041.49 24.6
1041.8 6.7
1054.24 5.8
1056.3 161.4

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1057.28 49.3

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1057.69 8.7
1169.37 41.6
1171.37 7.3
1288.39 8.0
1313.25 6.3
1313.5 11.5
1317.41 12.9
1318.38 31.9
1329.42 14.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1330.52 7.2
1331.23 21.2
1331.5 31.6
1332.3 26.3
1347.36 43.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1348.42 8.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1462.09 6.4

There are not related spectra

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1637.57
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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