Structure

    redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
290.01 172.6

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
290.99 28.1
389.09 19.3

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
405.12 503.9

Annotations:

B b1D-Gal,p/#bcleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
405.63 25.5
406.1 83.4

Annotations:

^{0,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ^{2,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_2_4--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
407.1 18.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
423.12 25.5

Annotations:

C b1D-Gal,p/#ccleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
470.1 27.8

Annotations:

C b1D-GlcNAc,p/#ccleavage--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
500.09 12.6
500.99 15.4
551.21 13.4

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
567.2 15.5

Annotations:

B b1D-GlcNAc,p/#bcleavage--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
569.2 483.3

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
570.16 135.9
571.15 26.2
572.12 117.0

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
573.12 26.4
581.18 28.5
585.15 35.9

Annotations:

C b1D-GlcNAc,p/#ccleavage--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
587.2 22.3

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
603.1 16.8
605.17 12.4
621.17 191.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd
621.69 97.2
622.17 26.6
627.17 82.5

Annotations:

^{2,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_4--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
628.13 23.6

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
655.17 148.4

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
656.21 43.4
665.19 13.7
669.2 221.5
670.21 68.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-2H,0,redEnd Y^{0,2}X_{GlcNAc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd ^{0,2}X_{GlcNAc}Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_0_2)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
673.19 2922.3

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
673.72 72.6
674.19 788.1
675.17 168.1
678.13 15.3
687.2 46.0

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
689.71 82.5
690.22 45.3
706.27 19.7
713.76 19.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-2H,0,redEnd
714.24 20.6
722.71 46.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-2H,0,redEnd
723.19 34.1
723.81 16.4
754.22 48.4

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
770.26 98.1

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
771.27 29.5
772.21 25.3

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
781.22 13.0
789.13 14.0
790.23 13.8

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
794.26 34.0
794.78 19.3
830.25 43.5

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
831.16 17.1
860.27 79.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
861.28 36.2
878.25 27.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
897.29 13.7
915.28 37.7

Annotations:

^{2,4}X_{GlcNAc}Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_2_4)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
916.24 19.9

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
939.27 19.0
952.3 41.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
953.32 20.9
957.3 60.8

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
958.31 20.5
975.32 1334.9

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
976.32 492.3
977.33 119.0
993.32 68.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
994.32 34.6
1040.31 15.3
1042.32 14.6
1043.31 17.1
1063.32 75.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
1064.29 42.9
1065.3 19.7
1081.38 30.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
1082.33 13.4
1178.38 32.2

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1179.33 16.6
1183.35 15.4
1197.39 13.7
1225.37 49.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1226.38 27.7
1227.34 14.3
1243.41 1189.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1244.37 648.9
1245.41 263.7
1246.43 18.3
1356.4 26.5
1358.45 88.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
1359.47 53.8
1360.37 16.3
1428.45 93.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1429.43 49.9
1430.55 18.6

There are not related spectra

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1648.62
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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