Structure

    redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
290.01 37.1

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
405.12 104.2

Annotations:

B b1D-Gal,p/#bcleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
405.62 5.1
406.07 25.9

Annotations:

^{0,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ^{2,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_2_4--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
423.09 32.2

Annotations:

C b1D-Gal,p/#ccleavage--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
424.11 8.8

Annotations:

^{0,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{2,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_2_4--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
538.84 4.4
540.26 4.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
547.15 6.2
549.14 3.9

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
550.18 3.7

Annotations:

Z^{2,4}X_{GlcNAc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd ^{2,4}X_{GlcNAc}Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_2_4)--6b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
567.15 15.8

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd B b1D-GlcNAc,p/#bcleavage--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
568.14 4.2

Annotations:

^{2,4}X_{GlcNAc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p/#xcleavage_2_4$MONO,Und,-2H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y^{2,4}X_{GlcNAc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd ^{2,4}X_{GlcNAc}Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_2_4)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
569.24 19.1

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
581.17 13.1
585.15 24.9

Annotations:

CY ?1D-GalNAc,p/#ccleavage--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd C b1D-GlcNAc,p/#ccleavage--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
590.25 3.8
621.17 34.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
621.69 19.0
622.16 10.2
627.15 86.2

Annotations:

^{2,4}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_2_4--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
628.19 22.0

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
651.19 7.4
653.21 3.8
655.11 5.2

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
669.18 138.9
669.7 4.6
670.2 32.7

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd Y^{0,2}X_{GlcNAc} redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd ^{0,2}X_{GlcNAc}Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#xcleavage_0_2)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
671.12 7.4
673.21 48.5

Annotations:

C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
674.09 3.8
679.21 24.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd
679.88 12.1
680.2 3.7
687.2 7.5

Annotations:

^{0,2}A_{GlcNAc} b1D-GlcNAc,p/#acleavage_0_2--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
689.69 5.4
690.21 4.9
704.13 3.9
715.24 4.4

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
721.18 4.3
722.67 20.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
723.16 5.4
724.18 4.0
727.37 4.4
742.31 4.9
745.27 21.4
747.22 4.4
748.13 5.4
749.16 4.0
749.65 4.9
759.21 8.7
759.42 4.2
761.26 10.8
761.53 6.8
762.23 8.8
763.24 6.5
766.72 3.7
770.25 6.5

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
771.17 6.5
776.3 4.4
777.26 4.9
779.28 28.9
780.21 29.5
781.22 24.1
785.75 5.4
788.22 15.0

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p$MONO,Und,-H,0,redEnd
789.26 5.3
790.22 6.5

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
794.22 16.4
794.87 4.3
795.29 6.0
842.34 14.5
860.26 656.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
861.25 227.3
862.16 64.7
878.26 34.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
879.24 16.7
880.2 6.5
885.3 3.9
886.33 8.2
952.26 7.8

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
953.3 6.7
975.32 27.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1063.34 39.7

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1064.34 13.7
1068.27 15.6
1081.35 6.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1183.35 5.4
1196.35 4.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
1225.42 9.7

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1226.4 5.5
1243.39 277.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1244.39 142.8
1245.36 43.1
1246.4 5.8
1358.54 10.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1359.43 7.5
1359.7 4.3
1428.41 17.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-GlcNAc,p--4b1D-Gal,p--??1HexNAc,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1429.43 8.1

There are not related spectra

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1648.62
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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