Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
290.0 127.9

Annotations:

B a2D-NeuAc,p/#bcleavage--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
290.46 6.4
291.01 15.8
299.02 2.8

Annotations:

C ?1D-Gal,p/#ccleavage--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
308.05 6.8

Annotations:

C a2D-NeuAc,p/#ccleavage--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
364.13 3.1

Annotations:

B b1D-Gal,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
380.07 2.7

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
382.01 8.4

Annotations:

C b1D-Gal,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
392.03 6.0
478.13 2.6
493.17 23.6
507.98 8.4
508.23 10.2
517.04 4.4
525.12 2.7
526.12 5.4

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
528.16 5.3
563.15 10.2
564.07 4.0
580.13 3.0
581.15 316.9

Annotations:

B ?1D-Gal,p/#bcleavage--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
582.14 78.8
583.11 12.8
615.2 6.3
654.29 2.9
657.09 4.8
702.19 14.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd
715.08 3.2

Annotations:

^{0,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
716.22 4.8
725.34 3.4
731.21 3.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
732.15 5.0
737.16 7.1
737.69 4.2
743.05 3.1

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
745.29 5.3
745.72 5.1
749.22 25.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
750.29 8.6
758.13 3.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
758.72 6.5
759.16 6.5
759.97 2.8
761.11 5.8

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
765.27 3.3
766.76 4.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
767.18 13.5
767.69 2.9
772.67 4.6

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
773.43 3.8
785.14 6.3
786.24 5.0
787.08 3.8
787.62 3.3
794.29 3.1
796.27 3.6
801.53 5.0
803.28 9.2
804.24 8.4
805.2 5.7
808.72 12.7
809.21 15.4
811.23 9.0
812.31 6.9
813.26 7.1
817.7 13.7
818.19 15.1
818.71 5.2
849.98 2.8
934.26 27.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
935.25 5.9
952.26 14.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
953.32 4.4
954.4 6.1
989.0 4.7
1049.26 2.7
1054.33 10.3

Annotations:

^{2,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
1055.37 5.0
1072.27 8.7
1090.26 20.9
1091.94 2.8
1096.32 3.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1097.3 2.8
1108.43 3.9
1113.19 4.0
1114.35 430.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1115.32 211.1
1116.36 71.4
1117.32 9.4
1387.62 3.2

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1388.51 7.1
1389.36 3.7
1405.42 138.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1406.44 92.5
1406.89 4.0
1407.54 13.6
1408.42 9.9
1455.24 5.2
1455.46 2.7
1491.57 3.2

There are 1 similar spectra:

Id Structure Score

8091

0.96

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1695.61
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

Report errors in this entry

UniCarb-DR Creative Commons License

Supported by SIB ExPASy  |  JST / NBDCDICP