Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
288.02 17.4
290.0 648.7

Annotations:

B ?1D-Gal,p/#bcleavage--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
290.45 23.0
290.99 80.4
291.99 16.6
306.01 720.3

Annotations:

B ?1D-Gal,p/#bcleavage--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
306.54 26.6
307.0 80.6
308.01 21.8

Annotations:

C ?1D-Gal,p/#ccleavage--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
408.1 17.4
424.1 19.0

Annotations:

^{0,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
468.1 17.2

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
526.11 30.6

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
531.09 20.4
532.07 21.4
552.13 25.2
629.19 33.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
653.17 20.0
655.16 17.5

Annotations:

B b1D-Gal,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
671.14 35.7

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
673.16 55.9

Annotations:

C b1D-Gal,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
674.25 23.0
689.15 93.0

Annotations:

C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
690.13 27.2
702.17 72.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-2H,0,redEnd
702.71 54.6
703.16 30.4
710.19 92.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
710.69 41.4
711.24 23.8
737.18 38.3
737.73 28.4
745.21 41.1
745.66 26.1
746.21 18.5
749.19 34.2

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
753.22 27.0
753.69 33.3
768.95 16.6
811.23 22.1
812.21 26.1
813.26 16.5
815.21 27.1
816.72 45.9
817.19 77.9

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
818.2 19.8
819.13 25.1
824.75 32.7
825.26 31.0
825.67 22.1
826.25 20.9
934.3 41.9

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
952.27 91.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
953.26 34.6
1040.31 59.9

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1041.28 30.4
1056.32 37.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
1057.23 17.6
1114.34 498.9

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
1115.35 245.4
1116.33 90.8
1184.33 17.2
1200.31 31.8
1216.36 17.6
1223.37 21.0
1225.37 27.6

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
1226.32 21.9
1241.35 51.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
1242.38 22.5
1243.38 113.9

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
1244.35 62.1
1259.37 137.9

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
1260.35 83.8
1261.34 25.7
1327.41 74.7
1328.42 48.8
1329.39 22.5
1345.37 23.7

Annotations:

^{2,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
1361.43 21.8

Annotations:

^{2,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#xcleavage_2_4)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
1377.32 20.9
1377.63 17.2
1378.4 27.5
1385.44 17.5
1387.42 187.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
1388.39 126.6
1389.44 44.5
1403.43 204.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
1404.44 140.2
1405.43 2813.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
1406.43 1684.9
1407.43 694.2
1408.45 162.1
1419.37 35.3
1420.46 26.1
1421.44 2214.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
1422.42 1320.1
1423.43 597.5
1424.45 146.2
1463.47 59.2
1464.44 39.1

There are 2 similar spectra:

Id Structure Score

3184

0.86

0.71

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1711.61
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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