Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
287.96 16.7
289.96 10.7
292.0 12.3
306.02 974.4

Annotations:

B ?1D-Gal,p/#bcleavage--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
306.6 25.5
307.03 102.5
308.06 14.5
322.97 17.0
424.13 19.6

Annotations:

^{0,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
484.13 10.0
486.09 12.5

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
526.13 47.9

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
527.18 16.6
539.08 38.1

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage$MONO,Und,-2H,0,redEnd
540.12 24.2
552.12 22.0
629.15 11.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
669.17 20.9
671.12 26.1

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd Z^{2,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
673.13 11.0
689.15 99.2

Annotations:

C ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
690.12 21.3
710.23 102.9

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
710.72 77.4
711.19 30.1
713.86 11.9
745.2 63.7
745.72 37.7
746.19 11.2
749.24 30.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
761.19 34.4
761.72 25.2
762.19 13.8
773.85 10.5
774.24 13.0
782.72 17.8
783.26 18.5
802.13 11.7
815.21 20.6
816.75 38.4
817.25 34.7
817.69 11.2
818.24 13.6
820.29 18.6
826.82 9.8
832.76 13.7
833.23 66.8

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
833.68 11.1
834.23 19.1
934.29 30.9

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
935.28 9.6
952.3 72.2

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
953.31 26.2
1036.29 9.6
1038.34 15.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
1054.29 10.8
1056.3 51.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
1057.29 25.7
1114.35 370.0

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
1115.34 193.0
1116.32 65.1
1117.38 13.0
1184.37 14.4
1185.33 10.4
1200.35 21.3
1201.31 9.7
1216.35 24.4
1217.36 18.9
1239.33 15.8
1241.36 34.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
1242.31 22.7
1243.38 21.8
1259.37 136.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
1260.36 74.5
1261.36 26.5
1327.41 105.6
1328.42 54.3
1329.4 20.6
1345.48 10.2
1377.44 44.2
1378.45 27.3
1379.44 10.1
1401.42 14.0
1402.36 10.7
1403.42 220.2

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
1404.42 133.4
1405.4 64.1
1406.45 11.1
1419.43 44.3
1420.42 43.5
1421.45 3585.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuGc,p$MONO,Und,-H,0,redEnd
1422.43 2235.1
1423.42 938.9
1424.43 249.3
1437.47 18.4
1438.46 10.0
1479.46 39.8
1480.45 26.6
1481.45 12.4
1634.52 15.1

There are 3 similar spectra:

Id Structure Score

3528

0.99

3185

0.98

0.83

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1727.60
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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