Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
290.01 1131.3

Annotations:

B a2D-NeuAc,p/#bcleavage--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
290.98 133.6
291.93 14.0
308.01 26.3

Annotations:

C a2D-NeuAc,p/#ccleavage--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
362.07 19.3
380.05 80.2

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
478.08 37.9
493.14 26.1
501.11 17.4
519.11 92.5
520.08 19.2

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd
537.13 442.4
538.14 109.0
563.12 96.1
563.96 18.9
569.18 15.2

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
579.07 49.1
580.15 113.5
581.14 6438.7

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
581.72 204.8
582.11 1484.6
582.71 39.6
583.13 171.7
587.16 11.9

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
632.26 21.4
643.17 27.4
656.18 36.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
657.19 11.1

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
664.18 70.0
665.17 6337.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
665.66 3789.6
666.15 1311.1
666.82 92.8
667.59 12.3
678.26 12.3
749.22 81.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
750.22 52.2
758.69 36.2
759.16 17.5
779.65 20.2
780.66 54.5
781.22 31.6
788.71 395.4
789.19 324.4
789.74 145.8
790.14 12.7
792.74 12.4
800.73 21.2
801.25 30.4
801.71 624.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
802.21 483.9
802.67 157.8
803.09 13.9

Annotations:

^{2,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
803.63 15.5
804.12 12.1
809.72 97.0
810.24 705.6
810.71 3419.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
811.2 2204.2
811.7 575.6
812.03 64.4
812.28 38.3
828.18 21.8
844.24 19.1
858.23 15.2
872.18 44.3
874.27 53.0
874.73 30.1
875.46 13.0
925.25 33.6
925.77 22.3
926.26 27.2
1022.25 56.1

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1023.27 43.1
1038.31 45.8
1039.27 29.1
1040.29 5601.9

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1041.3 2621.2
1042.28 561.4
1043.3 11.4
1271.31 19.2

Annotations:

^{2,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_2_4)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd ^{2,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
1272.35 14.3
1287.4 161.6
1288.41 93.4
1289.43 30.8
1311.36 30.7
1313.37 306.2

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1314.34 132.0
1315.37 40.6
1329.37 90.4
1330.42 262.3
1331.39 5135.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1332.38 2743.6
1333.35 711.8
1333.77 39.9
1334.15 15.1
1334.45 12.6
1605.49 14.4
1622.51 39.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1623.48 33.8

There are not related spectra

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1912.67
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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