Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
290.01 107.0

Annotations:

B ?1D-Gal,p/#bcleavage--3b2D-NeuAc,p$MONO,Und,-H,0,redEnd
290.98 10.2
312.9 16.0
322.94 30.2
380.04 3.3

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
424.93 167.8

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
425.94 16.0
470.16 3.4

Annotations:

C ?1HexNAc,p/#ccleavage--??1D-Gal,p--3b2D-NeuAc,p$MONO,Und,-H,0,redEnd
494.03 3.2
503.13 5.2

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
519.16 4.4
537.13 32.0
538.13 13.5
563.13 10.1
581.15 551.0

Annotations:

B ?1D-Gal,p/#bcleavage--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
582.12 126.7
582.69 4.8
583.16 12.7
635.16 4.4
647.03 19.2
648.16 4.9
651.05 6.5
653.18 6.9
654.17 3.9
665.24 8.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
669.01 448.1
670.02 85.6
670.93 3.3
672.28 3.2
673.07 3.3

Annotations:

C b1D-Gal,p/#ccleavage--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p$MONO,Und,-H,0,redEnd
681.24 3.4
702.27 4.9

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd
702.68 3.6
737.26 5.2
746.29 3.5
748.98 10.4

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
749.37 4.2
759.73 3.3
761.69 4.8

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
809.35 4.4
809.65 3.2
817.65 3.4

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p$MONO,Und,-H,0,redEnd
818.25 4.8
818.73 4.2
825.78 5.1
826.37 5.0
832.32 3.2
838.76 84.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
839.24 60.7
839.77 36.0
846.76 31.6
847.76 5777.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
848.24 4126.9
848.73 1459.0
849.35 112.6
850.05 11.3
850.44 5.1
863.76 4.2
872.24 3.2
873.59 5.2
924.3 3.6
931.25 5.5
945.36 3.6
946.62 4.4

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
949.18 6.5
949.8 4.3
952.33 3.8

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
954.29 7.0
957.4 5.3
962.28 6.1
962.68 6.3
963.32 6.2
963.81 4.3
1114.37 67.1

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1115.28 37.2
1116.38 15.2
1197.89 3.2
1244.18 5.1
1245.39 3.2
1278.88 3.2
1361.53 5.0
1362.54 3.3
1386.28 6.5
1387.44 23.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1388.55 9.1
1403.43 10.5
1404.39 11.3
1405.45 1111.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1406.44 692.5
1407.43 207.3
1652.49 10.5
1652.76 8.0
1653.5 11.8
1654.65 5.0
1678.5 26.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1679.49 13.7
1680.68 4.7
1696.53 85.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3b2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1697.54 65.6
1698.49 21.8

There are 2 similar spectra:

Id Structure Score

4958

0.94

0.94

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1986.71
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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