Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
470.13 10.8

Annotations:

C ?1HexNAc,p/#ccleavage--??1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd
537.13 7.5
581.12 34.9

Annotations:

B ?1D-Gal,p/#bcleavage--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
653.22 7.5
745.61 7.9
803.67 13.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd
804.29 13.9
858.27 7.4
860.27 10.7
884.77 70.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd
885.28 58.0
885.75 26.2
919.77 20.8
920.26 19.6
920.73 7.1
931.73 8.6
939.83 17.9
940.29 11.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
949.28 9.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
949.81 25.5
950.31 12.8
961.82 7.9
962.23 8.6
976.77 16.2
977.41 7.0
991.3 25.8
991.79 32.2
999.26 7.6
999.76 8.8
1000.35 39.5
1000.82 32.2
1001.33 8.6
1008.33 64.9
1008.8 53.5
1009.32 21.8
1012.78 9.2
1020.3 11.1

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1020.73 21.6
1021.29 649.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
1021.79 605.9
1022.32 184.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1022.89 9.2
1029.37 130.1
1030.32 26423.3

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-2H,0,redEnd
1030.75 24203.4
1031.3 7047.9
1032.79 29.2
1033.17 35.9
1033.75 11.9
1065.86 9.5
1068.26 7.0
1076.86 10.3
1100.82 9.0
1101.29 16.0
1102.59 7.5
1106.8 9.3
1107.88 7.4

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd
1109.98 7.4
1113.37 13.9
1114.79 14.5

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1115.24 7.2
1127.46 10.0
1127.84 12.6
1128.41 11.6
1128.75 7.0
1131.3 12.6
1132.41 16.0
1135.88 11.5
1136.34 13.2
1136.74 13.6
1137.21 14.4

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
1137.48 10.1
1139.38 12.6
1139.85 10.6
1140.37 7.3
1141.28 10.8
1144.87 12.5
1200.33 13.7
1317.42 7.4

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1405.52 14.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1406.5 15.3
1479.48 16.4

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1480.42 31.6
1481.41 11.8
1589.61 13.4
1590.59 14.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
1591.44 11.8
1608.53 55.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
1609.56 41.4
1752.6 70.8

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1753.64 57.2
1754.63 18.2
1770.59 1293.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p/#ycleavage$MONO,Und,-H,0,redEnd
1771.6 1125.3
1772.58 356.7
1773.48 13.4
1774.17 9.1
1812.63 8.5
1855.52 7.2
1881.7 7.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p--??1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p--??1HexNAc,p--??1D-Gal,p--3a2D-NeuAc,p--8a2D-NeuAc,p$MONO,Und,-H,0,redEnd

There are not related spectra

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 2351.84
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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