Structure

    redEnd--??1D-GalNAc,p--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
304.95 1.2
306.01 112.4

Annotations:

B a2D-NeuGc,p/#bcleavage--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd BY b1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-Gal,p/#ccleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
306.49 3.6

Annotations:

B a2D-NeuGc,p/#bcleavage--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd BY b1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-Gal,p/#ccleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
306.94 2.7

Annotations:

B a2D-NeuGc,p/#bcleavage--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd BY b1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-Gal,p/#ccleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
310.02 1.1
323.97 1.7

Annotations:

C a2D-NeuGc,p/#ccleavage--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd CY b1D-Gal,p/#ccleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
366.07 1.2

Annotations:

^{1,3}A_{Gal}Y b1D-Gal,p/#acleavage_1_3--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{2,4}A_{Gal}Y b1D-Gal,p/#acleavage_2_4--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p--3b1D-Gal,p--3a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
378.08 1.1

Annotations:

^{1,4}A_{Gal}Z b1D-Gal,p/#acleavage_1_4--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
380.08 2.0
384.07 18.2

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
398.05 3.4
406.01 2.0
417.12 1.9
420.02 1.5
436.13 1.3
440.1 1.1

Annotations:

^{1,5}A_{Gal}Y b1D-Gal,p/#acleavage_1_5--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
454.13 21.4
467.22 2.1

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
468.12 1.4

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
477.18 4.7
478.15 1.9
493.08 4.8
495.09 3.0
507.15 1.1
509.16 1.5

Annotations:

^{2,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
511.12 3.4

Annotations:

^{2,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
512.1 2.7
513.23 3.3

Annotations:

^{0,3}A_{NeuGc} a2D-NeuGc,p/#acleavage_0_3--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
529.13 4.5

Annotations:

^{2,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
530.07 3.0
534.08 1.6
537.23 2.6
551.16 3.1

Annotations:

^{1,3}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_3--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
553.06 1.9
556.5 1.8
569.19 11.5

Annotations:

^{1,3}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_1_3--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{0,2}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_0_2--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
571.49 1.2

Annotations:

^{2,5}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_2_5--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
582.61 1.2
583.11 7.7
583.35 2.5
588.27 1.9

Annotations:

^{0,2}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_2--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
591.3 1.4
597.16 92.9
597.76 6.3
598.2 9.0

Annotations:

^{1,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_1_4--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
599.04 1.7

Annotations:

^{1,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_1_4--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
611.18 2.5
613.14 59.6

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
613.76 3.5

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
614.15 4.6

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
615.03 2.6
632.17 1.2

Annotations:

C b1D-Gal,p/#ccleavage--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
647.13 9.3
647.44 1.5
648.42 1.4
655.1 3.8
657.18 1.4
661.19 117.8
662.16 7.4
672.15 2.5
673.18 289.5

Annotations:

^{1,3}A_{Gal} b1D-Gal,p/#acleavage_1_3--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd ^{2,4}A_{Gal} b1D-Gal,p/#acleavage_2_4--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
674.14 11.2

Annotations:

^{1,3}A_{Gal} b1D-Gal,p/#acleavage_1_3--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd ^{2,4}A_{Gal} b1D-Gal,p/#acleavage_2_4--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
674.74 2.9
675.13 5.2
676.32 2.2
677.0 1.6
689.19 40.0
690.22 49.7
691.2 11022.0

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
692.16 581.9

Annotations:

Y redEnd--??1D-GalNAc,p--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
693.16 31.2
693.67 2.6
707.17 2.7
717.19 3.1

Annotations:

^{2,5}A_{Gal} b1D-Gal,p/#acleavage_2_5--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
726.03 1.1
727.2 1.6
743.19 1.2
748.11 1.8

Annotations:

^{1,5}A_{Gal} b1D-Gal,p/#acleavage_1_5--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
761.2 1.4
767.19 1.3
817.16 1.2
860.25 6.8
886.16 4.4
887.37 1.3
918.33 1.3
922.27 7.7
922.49 2.4
923.33 1.2
924.27 11.0
936.26 11.8
950.23 17.5

Annotations:

^{1,5}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_5--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
953.17 1.2
954.29 287.5
955.29 18.7
956.15 1.5
962.22 19.5
962.75 1.4
963.2 1.3
964.31 5.2
968.25 3.4

There are 4 similar spectra:

Id Structure Score

8023

1.00

4210

1.00

3509

1.00

7631

1.00

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 997.34
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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