Structure

    redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p)--??1HexNAc,p$MONO,Und,-H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
219.97 46.2

Annotations:

C ?1D-GalNAc,p/#ccleavage--??1HexNAc,p$MONO,Und,-H,0,redEnd CY ?1D-GalNAc,p/#ccleavage--??1HexNAc,p--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
221.99 42.1

Annotations:

YY redEnd--??1D-GalNAc,p(--??1HexNAc,p/#ycleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
234.0 14.2
239.02 9.6
245.04 9.1

Annotations:

B^{0,2}X_{Fuc} ?1D-GalNAc,p/#bcleavage--??1HexNAc,p--??1L-Fuc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
257.03 15.0
262.02 137.9

Annotations:

C^{0,2}X_{Fuc} ?1D-GalNAc,p/#ccleavage--??1HexNAc,p--??1L-Fuc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
262.99 23.3

Annotations:

C^{0,2}X_{Fuc} ?1D-GalNAc,p/#ccleavage--??1HexNAc,p--??1L-Fuc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
264.02 19.3
269.09 7.6
276.05 57.6

Annotations:

C^{1,4}X_{Fuc} ?1D-GalNAc,p/#ccleavage--??1HexNAc,p--??1L-Fuc,p/#xcleavage_1_4$MONO,Und,-H,0,redEnd Z^{1,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p/#zcleavage)--??1HexNAc,p/#xcleavage_1_4$MONO,Und,-H,0,redEnd
281.02 11.8
287.04 8.7

Annotations:

Z^{0,2}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p/#zcleavage)--??1HexNAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
288.07 9.7

Annotations:

Z^{0,2}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p/#zcleavage)--??1HexNAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd B^{1,3}X_{Fuc} ?1D-GalNAc,p/#bcleavage--??1HexNAc,p--??1L-Fuc,p/#xcleavage_1_3$MONO,Und,-H,0,redEnd B^{2,4}X_{Fuc} ?1D-GalNAc,p/#bcleavage--??1HexNAc,p--??1L-Fuc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
292.0 12.6

Annotations:

C^{0,3}X_{Fuc} ?1D-GalNAc,p/#ccleavage--??1HexNAc,p--??1L-Fuc,p/#xcleavage_0_3$MONO,Und,-H,0,redEnd
299.06 37.5
300.13 8.8
304.04 12.7

Annotations:

Z^{2,5}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p/#zcleavage)--??1HexNAc,p/#xcleavage_2_5$MONO,Und,-H,0,redEnd B^{0,4}X_{Fuc} ?1D-GalNAc,p/#bcleavage--??1HexNAc,p--??1L-Fuc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd
305.07 8.1

Annotations:

B^{0,4}X_{Fuc} ?1D-GalNAc,p/#bcleavage--??1HexNAc,p--??1L-Fuc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd Y^{0,2}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p/#ycleavage)--??1HexNAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd
311.05 15.2
312.07 23.9
322.05 43.9

Annotations:

Y^{2,5}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p/#ycleavage)--??1HexNAc,p/#xcleavage_2_5$MONO,Und,-H,0,redEnd C^{0,4}X_{Fuc} ?1D-GalNAc,p/#ccleavage--??1HexNAc,p--??1L-Fuc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd
323.1 10.1

Annotations:

C^{0,4}X_{Fuc} ?1D-GalNAc,p/#ccleavage--??1HexNAc,p--??1L-Fuc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd
324.05 7.4

Annotations:

Y^{1,3}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p/#ycleavage)--??1HexNAc,p/#xcleavage_1_3$MONO,Und,-H,0,redEnd
329.09 28.1
330.09 14.2
347.11 288.4

Annotations:

Z^{0,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p/#zcleavage)--??1HexNAc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd Z^{2,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p/#zcleavage)--??1HexNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
348.09 173.7

Annotations:

Z^{0,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p/#zcleavage)--??1HexNAc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd Z^{2,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p/#zcleavage)--??1HexNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd B ?1D-GalNAc,p/#bcleavage--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd
349.07 21.7

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd
359.11 74.0
360.16 12.4
365.12 540.5

Annotations:

Y^{0,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p/#ycleavage)--??1HexNAc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd Y^{2,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p/#ycleavage)--??1HexNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
366.11 91.2

Annotations:

Y^{0,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p/#ycleavage)--??1HexNAc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd Y^{2,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p/#ycleavage)--??1HexNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd C ?1D-GalNAc,p/#ccleavage--??1HexNAc,p--??1L-Fuc,p$MONO,Und,-H,0,redEnd
368.11 23.6
371.09 50.8
377.16 8.6
383.16 47.5
384.13 7.7
389.12 293.4

Annotations:

ZZ redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
390.1 35.8

Annotations:

ZZ redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
401.11 15.2
405.13 50.7
406.19 13.4

Annotations:

Z redEnd--??1D-GalNAc,p(--??1HexNAc,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#ycleavage)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
407.14 24435.5

Annotations:

Z redEnd--??1D-GalNAc,p(--??1HexNAc,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#ycleavage)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
408.13 3378.8

Annotations:

Z redEnd--??1D-GalNAc,p(--??1HexNAc,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#ycleavage)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
425.16 12773.6

Annotations:

Y redEnd--??1D-GalNAc,p(--??1HexNAc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#ycleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
426.15 1800.5

Annotations:

Y redEnd--??1D-GalNAc,p(--??1HexNAc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#ycleavage)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
442.18 10.5
460.13 32.8
461.1 7.5
463.16 206.3

Annotations:

^{1,4}X_{Fuc}Z redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#xcleavage_1_4)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
464.08 45.8

Annotations:

^{1,4}X_{Fuc}Z redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#xcleavage_1_4)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
473.11 7.8
478.15 10.2
484.14 150.0

Annotations:

^{2,5}X_{Fuc}Y redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#xcleavage_2_5)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
485.1 22.3
493.18 8.2

Annotations:

^{1,3}X_{Fuc}Z redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#xcleavage_1_3)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ^{2,4}X_{Fuc}Z redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#xcleavage_2_4)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
502.16 123.3
502.53 9.1
503.13 23.4
505.15 35.7
506.15 9.2

Annotations:

Z^{2,5}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#xcleavage_2_5$MONO,Und,-H,0,redEnd
509.06 7.4

Annotations:

Y^{0,2}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#ycleavage)--??1HexNAc,p/#xcleavage_0_2$MONO,Und,-H,0,redEnd Z^{1,3}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#xcleavage_1_3$MONO,Und,-H,0,redEnd ^{0,4}X_{Fuc}Z redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#xcleavage_0_4)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
514.18 16.2

Annotations:

^{3,5}X_{Fuc}Y redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#xcleavage_3_5)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
520.2 837.7

Annotations:

Z^{0,3}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#xcleavage_0_3$MONO,Und,-H,0,redEnd
521.17 177.6

Annotations:

Z^{0,3}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#xcleavage_0_3$MONO,Und,-H,0,redEnd
521.86 7.8
522.23 18.8
532.18 45.8
533.13 19.3
544.19 12.4
550.2 89.8

Annotations:

Z^{0,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd Z^{2,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
551.18 23.3

Annotations:

Z^{0,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd Z^{2,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
553.18 273.9

Annotations:

Z redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
554.18 40.0

Annotations:

Z redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p)--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd Y^{3,5}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#ycleavage)--??1HexNAc,p/#xcleavage_3_5$MONO,Und,-H,0,redEnd
562.2 208.0
563.2 42.0
568.24 19.7

Annotations:

Y^{0,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#ycleavage)--??1HexNAc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd Y^{2,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#ycleavage)--??1HexNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
571.19 73.2

Annotations:

Y redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
572.2 10.9

Annotations:

Y redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p)--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
580.21 64.8
581.24 12.4
592.21 120.1
593.17 18.9
609.22 9.9
610.22 5400.9

Annotations:

Z redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
611.2 834.9

Annotations:

Z redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#zcleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
611.91 18.3
612.2 7.9
628.22 21.8

Annotations:

Y redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
629.2 29.7

Annotations:

Y redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#ycleavage)--??1HexNAc,p$MONO,Und,-H,0,redEnd
630.26 15.7
708.19 8.1
712.08 7.5
714.26 244.5

Annotations:

^{1,3}X_{Fuc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#xcleavage_1_3)--??1HexNAc,p$MONO,Und,-H,0,redEnd ^{2,4}X_{Fuc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#xcleavage_2_4)--??1HexNAc,p$MONO,Und,-H,0,redEnd ^{0,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p)--??1HexNAc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd ^{2,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p)--??1HexNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
715.25 70.0

Annotations:

^{1,3}X_{Fuc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#xcleavage_1_3)--??1HexNAc,p$MONO,Und,-H,0,redEnd ^{2,4}X_{Fuc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#xcleavage_2_4)--??1HexNAc,p$MONO,Und,-H,0,redEnd ^{0,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p)--??1HexNAc,p/#xcleavage_0_4$MONO,Und,-H,0,redEnd ^{2,4}X_{HexNAc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p)--??1HexNAc,p/#xcleavage_2_4$MONO,Und,-H,0,redEnd
729.23 13.5
730.17 12.6

Annotations:

^{0,4}X_{Fuc} redEnd--??1D-GalNAc,p(--??1HexNAc,p--??1L-Fuc,p/#xcleavage_0_4)--??1HexNAc,p$MONO,Und,-H,0,redEnd
732.26 48.2
733.26 19.2

There are not related spectra

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 773.32
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

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