Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-2H,0,redEnd

Gilthead seabream mucus glycosylation is complex, differs between epithelial sites and carries unusual poly N-acetylhexosamine motifs

GlyTouCan Accession Number: Loading...

Peak Intensity
217.95 51.0

Annotations:

^{3,5}A_{GalNAc} ?1D-GalNAc,p/#acleavage_3_5--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-2H,0,redEnd
276.0 49.2

Annotations:

^{1,3}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_3--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-2H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd ^{3,5}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_3_5--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
288.0 30.1

Annotations:

BZ b1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
306.04 2501.4

Annotations:

^{2,5}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_2_5(--3b1D-Gal,p--3a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-2H,0,redEnd B a2D-NeuGc,p/#bcleavage--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd BY b1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-Gal,p/#ccleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd B b1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
307.02 295.6

Annotations:

B a2D-NeuGc,p/#bcleavage--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd BY b1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-Gal,p/#ccleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd B b1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd
308.03 50.3
324.03 53.4

Annotations:

C a2D-NeuGc,p/#ccleavage--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd CY b1D-Gal,p/#ccleavage--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
357.0 36.6
364.04 27.3

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
366.08 46.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-2H,0,redEnd ^{0,2}A_{Gal} b1D-Gal,p/#acleavage_0_2--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd ^{1,3}A_{Gal}Y b1D-Gal,p/#acleavage_1_3--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd ^{2,4}A_{Gal}Y b1D-Gal,p/#acleavage_2_4--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
384.08 47.0

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
389.1 156.4

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
390.1 33.5

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
396.05 55.7

Annotations:

C ?1D-GalNAc,p/#ccleavage--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd ^{1,4}A_{Gal}Y b1D-Gal,p/#acleavage_1_4--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
407.08 63.2

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
408.08 117.2

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd ^{0,2}A_{Gal}Z b1D-Gal,p/#acleavage_0_2--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
408.53 35.0

Annotations:

^{0,2}A_{Gal}Z b1D-Gal,p/#acleavage_0_2--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
424.09 27.0

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
429.09 28.8

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd
438.05 28.4

Annotations:

^{1,3}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_3--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-2H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd ^{3,5}A_{GalNAc} ?1D-GalNAc,p/#acleavage_3_5--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
447.09 28.1

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd
494.12 71.5

Annotations:

^{1,5}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_5(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-2H,0,redEnd
495.09 37.9

Annotations:

^{1,5}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_5(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-2H,0,redEnd
507.11 30.2
509.11 36.3
521.14 36.1
525.12 289.1
526.11 60.3
527.13 73.4

Annotations:

^{2,5}A_{NeuGc} a2D-NeuGc,p/#acleavage_2_5--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-2H,0,redEnd
528.15 29.4

Annotations:

^{2,5}A_{NeuGc} a2D-NeuGc,p/#acleavage_2_5--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-2H,0,redEnd ^{2,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd
533.14 28.1
543.11 23.2

Annotations:

^{0,2}A_{NeuGc} a2D-NeuGc,p/#acleavage_0_2--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
551.16 77.7

Annotations:

^{1,3}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_3--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
552.09 30.3

Annotations:

^{1,3}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_3--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
562.63 93.0
563.12 46.2
564.13 23.1
567.18 26.0

Annotations:

^{1,5}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_5(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd
569.18 1717.0

Annotations:

^{1,3}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_1_3--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
570.15 518.7

Annotations:

^{1,3}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_1_3--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
571.2 105.1
573.13 27.6
582.16 140.2

Annotations:

^{1,4}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_1_4--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage$MONO,Und,-H,0,redEnd
582.64 79.4
583.12 286.1
584.09 60.4
587.19 304.9

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
588.19 84.9

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
589.17 24.6
590.15 70.7
590.64 56.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd
591.14 135.3

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd
591.67 74.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd
592.17 47.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd
595.12 176.5
596.09 59.1
600.17 109.8

Annotations:

^{1,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_1_4--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd
600.66 99.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd
601.15 45.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd
611.12 66.3
613.14 4208.7

Annotations:

^{2,5}A_{GalNAc}Z ?1D-GalNAc,p/#acleavage_2_5(--3b1D-Gal,p--3a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd B b1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
614.13 1041.2

Annotations:

B b1D-Gal,p/#bcleavage--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
615.12 231.6
636.17 34.3
637.19 41.4
638.1 36.3
643.22 33.1
644.17 22.3
650.17 63.5
651.17 54.7
652.16 31.1
689.22 70.2
690.2 26.2
707.22 33.8
749.24 4281.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
750.23 1332.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
751.22 354.9
752.24 36.6
775.2 33.6

Annotations:

B ?1D-GalNAc,p/#bcleavage--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd
819.23 24.3
876.24 44.0

Annotations:

^{1,3}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_3--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
877.22 86.7

Annotations:

^{1,3}A_{GalNAc} ?1D-GalNAc,p/#acleavage_1_3--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
962.28 187.0
963.29 68.5
978.24 101.9
979.24 40.3
1026.27 24.5
1038.27 106.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
1039.31 50.1

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
1050.24 36.8
1056.3 4171.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
1057.29 1832.1

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--3a2D-NeuGc,p--8a2D-NeuGc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
1058.31 576.3
1059.22 62.9
1139.35 45.1
1165.32 370.1
1166.31 177.8
1167.3 65.9
1269.37 107.0
1270.34 45.0

There are 3 similar spectra:

Id Structure Score

3524

0.67

8057

0.60

4221

0.60

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1362.47
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Sparus Aurata
Tissue - Mucus

Mass Spec

N/A

MIRAGE Structural data

Report errors in this entry

UniCarb-DR Creative Commons License

Supported by SIB ExPASy  |  JST / NBDCDICP