Structure

    redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p)--6a1L-Fuc,p$MONO,Und,-2H,0,redEnd

Discrimination of Isomers of Released N- and O-Glycans Using Diagnostic Product Ions in Negative Ion PGC-LC-ESI-MS/MS

PubMed Entry

File Name: Annotated_spectra.gwp

GlycoPOST Entry: GPST000024

GlyTouCan Accession Number: Loading...

500.0100015002000m/z0.0501.0e+21.5e+2Abundance
Peak Intensity
289.9776449 6.1008745509068705

Annotations:

YZ redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p/#ycleavage)--6a1D-Man,p/#zcleavage)--6a1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p/#zcleavage)--6a1D-Man,p/#ycleavage)--6a1L-Fuc,p$MONO,Und,-H,0,redEnd B b1D-Gal,p/#bcleavage--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd Y redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p/#ycleavage)--6a1L-Fuc,p$MONO,Und,-H,0,redEnd BY b1D-GlcNAc,p/#bcleavage--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p/#ycleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-2H,0,redEnd CZ b1D-GlcNAc,p/#ccleavage--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p/#zcleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-2H,0,redEnd Z redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p/#zcleavage)--6a1L-Fuc,p$MONO,Und,-H,0,redEnd B a1D-Man,p/#bcleavage--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd YZ redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p/#ycleavage)--6a1L-Fuc,p/#zcleavage$MONO,Und,-2H,0,redEnd ZY redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p/#zcleavage)--6a1L-Fuc,p/#ycleavage$MONO,Und,-2H,0,redEnd YZ redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a1D-Man,p--2b1D-GlcNAc,p/#zcleavage)--6a1L-Fuc,p$MONO,Und,-2H,0,redEnd ZY redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a1D-Man,p--2b1D-GlcNAc,p/#ycleavage)--6a1L-Fuc,p$MONO,Und,-2H,0,redEnd Z redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p/#zcleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p)--6a1L-Fuc,p$MONO,Und,-2H,0,redEnd YY redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p/#ycleavage)--6a1L-Fuc,p/#ycleavage$MONO,Und,-2H,0,redEnd YZ redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p)--6a1L-Fuc,p/#zcleavage$MONO,Und,-2H,0,redEnd ZY redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p)--6a1L-Fuc,p/#ycleavage$MONO,Und,-2H,0,redEnd YZ redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p/#ycleavage)--6a1L-Fuc,p/#zcleavage$MONO,Und,-2H,0,redEnd ZY redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p/#zcleavage)--6a1L-Fuc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p/#ycleavage)--6a1L-Fuc,p$MONO,Und,-2H,0,redEnd CY b1D-GlcNAc,p/#ccleavage--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd YY redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p/#ycleavage)--6a1L-Fuc,p/#ycleavage$MONO,Und,-2H,0,redEnd YY redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p/#ycleavage)--6a1L-Fuc,p/#ycleavage$MONO,Und,-2H,0,redEnd B b1D-Man,p/#bcleavage--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd C b1D-Man,p/#ccleavage--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p$MONO,Und,-H,0,redEnd Y redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p/#ycleavage)--6a1L-Fuc,p$MONO,Und,-2H,0,redEnd ZZ redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage)--6a1L-Fuc,p/#zcleavage$MONO,Und,-2H,0,redEnd Z redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p)--6a1L-Fuc,p$MONO,Und,-2H,0,redEnd YY redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6a1L-Fuc,p/#ycleavage$MONO,Und,-2H,0,redEnd Y redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6a1L-Fuc,p$MONO,Und,-2H,0,redEnd CY b1D-GlcNAc,p/#ccleavage--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd BY b1D-GlcNAc,p/#bcleavage--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd BY b1D-GlcNAc,p/#bcleavage--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-GlcNAc,p/#ccleavage--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd CZ b1D-GlcNAc,p/#ccleavage--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd CY b1D-GlcNAc,p/#ccleavage--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd CY b1D-GlcNAc,p/#ccleavage--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd ZZ redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a1D-Man,p--2b1D-GlcNAc,p/#zcleavage)--6a1L-Fuc,p$MONO,Und,-H,0,redEnd YY redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a1D-Man,p--2b1D-GlcNAc,p/#ycleavage)--6a1L-Fuc,p$MONO,Und,-H,0,redEnd Y redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p/#ycleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p)--6a1L-Fuc,p$MONO,Und,-H,0,redEnd ZZ redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p)--6a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd B b1D-GlcNAc,p/#bcleavage--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd C b1D-GlcNAc,p/#ccleavage--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd YZ redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage)--6a1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6a1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p)--6a1L-Fuc,p$MONO,Und,-H,0,redEnd YZ redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p)--6a1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#zcleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p)--6a1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6a1L-Fuc,p$MONO,Und,-H,0,redEnd Y redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p/#ycleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p)--6a1L-Fuc,p$MONO,Und,-H,0,redEnd B b1D-GlcNAc,p/#bcleavage--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd Y redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p/#ycleavage)--6a1L-Fuc,p$MONO,Und,-H,0,redEnd C b1D-GlcNAc,p/#ccleavage--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p$MONO,Und,-H,0,redEnd Y redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p/#ycleavage)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p)--6a1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--?b1D-GlcNAc,p(--4b1D-GlcNAc,p--4b1D-Man,p(--3a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p--3a2D-NeuAc,p)--6a1D-Man,p--2b1D-GlcNAc,p--4b1D-Gal,p/#zcleavage)--6a1L-Fuc,p$MONO,Und,-H,0,redEnd
368.1599979 1.7214710249648633
424.2194155 7.170429686524748
455.319996 1.2869049311
553.2399938 1.8269576599988022
587.119993 1.0350933075
596.214797 3.0063626766
652.3401497 2.1864165068
655.4068198 9.304407203945198
693.3583471 11.437749651494347
701.8799905 2.757978556665851
715.4214493 4.586731315175363
730.3817357 6.07981575609047
751.1898552 7.911524415
774.8574016 5.128062017164719
782.8684612 75.80618998923227
783.4129015 0.0
817.403926 10.636738579436411
818.3999879 0.0
835.3821684 125.05027753873165
836.3665375 0.0
851.4143634 3.0458645821
856.359987 3.2809841205941135
866.9852607 36.93650651174675
884.4450619 16.18260537504322
908.4580926 4.987811327
910.4399858 1.2309584618
926.9289165 14.5962029696
935.9852784 9.3005815744
958.1999847 3.2837459696075957
980.780343 2.0428931713
1003.379903 4.0665874481
1008.997287 12.0510551929
1095.540034 3.4827424288
1183.55998 1.0490365028
1216.631252 5.5211997032
1233.501109 6.896878374453719
1261.578722 7.0979328156
1275.520479 14.1441001892
1327.700381 2.1612560749
1344.575531 10.834752534590265
1362.654075 27.857567710297303
1363.644339 0.0
1370.639976 1.0827156305
1386.696892 8.33557879464809
1419.503798 2.5572705269
1422.698663 14.034661649251106
1423.879974 0.0
1443.664378 5.289729346664229
1505.590356 6.1613754034
1506.758322 56.69947758561014
1507.667857 0.0
1524.676065 146.02989512789446
1525.604953 0.0
1548.935632 3.1988395452
1583.839971 1.1702196598
1607.681703 15.811463298211049
1608.776763 15.066079996954688
1609.83997 0.0
1623.770241 13.144826614564177
1624.619983 0.0
1625.779376 32.74601600724786
1627.065003 2.819514802320347
1627.844907 0.0
1638.71997 1.385406971
1665.840134 4.6036103964
1709.790729 23.000124730034003
1713.759968 1.7357585455706068
1727.799103 9.631178219992226
1728.725593 3.0240883784291275
1786.817061 5.8691864014
1787.859492 53.58708910503143
1788.869144 0.0
1898.999964 2.5776842489695087

N/A

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 2077.76
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Mus musculus (Mouse)
Tissue - Cell Line
Glycoprotein - P12763
Cell line - monocyte

Mass Spec

Manufacturer: Thermo Fisher

Model: LTQ

Ion Mode: Negative

MIRAGE Structural data

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