Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd

Effects of size and geographical origin on Atlantic salmon, Salmo salar, mucin O-glycan repertoire

PubMed Entry

GlyTouCan Accession Number: Loading...

Peak Intensity
347.28 0.7
359.1 1.1
364.2 0.6

Annotations:

BY b1D-GlcNAc,p/#bcleavage--??1HexNAc,p(--??1D-Gal,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ b1D-GlcNAc,p/#ccleavage--??1HexNAc,p(--??1D-Gal,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
364.96 0.5
365.54 0.6
388.82 0.8
389.2 1.6

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
407.09 31.4

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
407.98 1.4
408.19 2.0
424.13 1.0
425.05 1.3

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
425.36 0.7
426.12 0.5
434.18 0.9
435.16 0.6
448.21 0.5
463.38 0.5
466.96 0.5
485.28 1.4
491.06 0.5
503.07 2.5
503.91 0.6
509.23 3.5
509.69 1.6
510.12 8.0

Annotations:

B b1D-GlcNAc,p/#bcleavage--??1HexNAc,p(--??1D-Gal,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
511.05 0.5
522.54 0.8
527.18 16.2
545.12 1.8
546.15 0.8
546.45 0.8
549.1 0.5
550.9 1.8
551.25 1.9

Annotations:

CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
569.16 23.3

Annotations:

CY ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--??1HexNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
570.19 14.4
571.02 1.1
571.27 0.7
587.2 45.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--??1HexNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
588.0 3.4
588.31 3.1
612.18 0.9
629.89 0.7
664.33 0.6
665.3 0.9
671.24 0.8
688.66 0.7
689.2 4.8
707.12 0.9
707.34 0.7
707.81 0.5
708.17 1.2
713.18 4.0

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
714.25 1.9
749.22 5.7
750.08 1.1
751.25 0.6
754.35 2.7

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p/#zcleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
754.87 0.9
755.28 1.4
772.34 1.8

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p/#ycleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p/#zcleavage)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
772.68 0.7
773.23 12.1

Annotations:

^{0,4}A_{GalNAc} ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
774.41 1.4

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
814.21 0.5
815.19 1.7
815.43 1.0
834.4 0.8
844.28 1.7
846.2 0.5
852.27 0.9
858.22 1.2
858.61 0.7
859.18 1.4
874.05 1.0
876.29 31.1

Annotations:

^{2,4}X_{Gal}Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#xcleavage_2_4)--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Y^{2,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p/#xcleavage_2_4)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
877.12 5.5
877.4 5.3
888.28 0.7
891.17 0.7
894.25 3.2
894.56 2.6
894.86 1.1
895.11 0.8
895.45 1.4
900.05 1.3
916.19 1.9
916.41 0.9
918.27 130.5

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
919.23 37.0
935.52 1.1
936.35 44.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p)--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p--??1HexNAc,p(--??1D-Gal,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
937.32 16.2
953.25 0.6
995.96 1.1
996.29 2.8
997.05 0.6
1038.34 71.0
1039.26 26.0

There are 4 similar spectra:

Id Structure Score

1.00

5450

0.90

5745

0.86

3983

0.78

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1097.43
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Salmo Salar
Tissue - Mucus

HPLC

Column

Method

  • 40 min gradient with 10 ul/min run rate
  • 10 mM (NH4)HCO3 in water
  • 10 mM (NH4)HCO3 in 80% acetontirile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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