Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6b1D-GlcNAc,p--??2D-NeuAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd

Effects of size and geographical origin on Atlantic salmon, Salmo salar, mucin O-glycan repertoire

PubMed Entry

GlyTouCan Accession Number: Loading...

Peak Intensity
290.16 5.6

Annotations:

B b1D-Gal,p/#bcleavage--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
290.74 0.0
291.13 1.1
291.71 0.8
292.27 0.0
481.4 1.6
481.96 0.0
527.29 0.9
527.86 0.0

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
553.37 1.5

Annotations:

^{0,4}A_{Gal} ?1D-Gal,p/#acleavage_0_4--6?1HexNAc,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
553.94 0.0
629.1 1.0
668.07 1.3
668.61 0.0
681.84 1.0
682.38 0.0
716.45 1.2
716.99 0.0
740.32 1.1
740.87 0.0
758.27 1.7
758.82 0.0
816.05 2.1
816.61 0.0
835.29 1.3

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd Y^{0,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p/#xcleavage_0_4--3?1D-Gal,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ^{2,4}X_{GalNAc}Y redEnd--??1D-GalNAc,p/#xcleavage_2_4--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
835.86 0.0
837.72 0.7
838.22 1.9
839.08 0.9

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-2H,0,redEnd
839.62 0.0

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p/#ycleavage)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
842.61 0.9

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
843.19 0.0
847.56 1.3
848.22 1.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-2H,0,redEnd
848.78 0.0
852.93 0.8
854.81 1.2
855.36 0.0
860.13 0.9
860.5 1.0

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
861.05 0.0
861.43 0.9
861.98 0.0
862.37 0.7
865.29 1.5
865.86 0.0
866.4 1.9
866.95 0.0
878.33 1.1

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
878.88 0.0
885.39 0.8
885.94 0.0
894.33 1.8
894.88 0.0

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1024.46 1.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1025.03 0.0
1163.03 1.9
1163.58 0.0
1166.34 0.7

Annotations:

B ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p/#zcleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
1166.89 0.0
1186.53 1.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p/#ycleavage)--6?1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1187.1 0.0
1200.77 1.0
1332.35 1.0
1332.89 0.0
1348.64 2.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1348.83 2.3
1349.71 1.8
1350.3 1.0
1350.86 0.0
1452.59 1.0
1453.14 0.0
1516.37 0.9

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p/#ycleavage)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p/#zcleavage)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
1516.94 0.0
1531.54 1.0
1532.11 0.0
1532.81 1.7
1533.17 0.7
1533.55 5.0

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1533.84 1.2
1534.52 1.9

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p/#ycleavage)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
1534.8 1.6
1535.42 0.0
1549.54 0.6
1549.91 1.2
1550.46 0.0
1551.58 60.7

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1552.51 21.1
1552.78 15.5
1553.65 12.8
1554.4 0.7
1554.94 0.6
1592.7 0.9
1593.25 0.0
1661.19 0.7
1687.53 0.7
1692.83 1.7
1693.37 0.0
1750.43 1.7
1750.97 0.0

There are 4 similar spectra:

Id Structure Score

1.00

4947

0.98

0.98

5879

0.85

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1841.67
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Salmo Salar
Tissue - Mucus

HPLC

Column

Method

  • 40 min gradient with 10 ul/min run rate
  • 10 mM (NH4)HCO3 in water
  • 10 mM (NH4)HCO3 in 80% acetontirile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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