Structure

    redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6b1D-GlcNAc,p--??2D-NeuAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd

Effects of size and geographical origin on Atlantic salmon, Salmo salar, mucin O-glycan repertoire

PubMed Entry

GlyTouCan Accession Number: Loading...

Peak Intensity
290.07 10.6

Annotations:

B b1D-Gal,p/#bcleavage--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
290.79 0.5
326.4 0.9

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
473.42 0.8
488.0 0.5
492.98 0.4

Annotations:

B ?1D-Gal,p/#bcleavage--6?1HexNAc,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd
493.28 0.4
592.93 0.7

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p/#ycleavage)--6?1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
630.3 0.8

Annotations:

C^{0,4}X_{Gal} ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1D-Gal,p/#xcleavage_0_4--3?1D-Gal,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
670.95 0.8
674.7 0.5
674.94 0.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
694.07 0.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd
730.55 0.5
749.64 0.4
751.03 0.5
752.69 0.6
767.56 1.3
775.36 0.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p$MONO,Und,-2H,0,redEnd Y^{0,2}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p/#xcleavage_0_2)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
776.06 0.6

Annotations:

^{1,3}X_{GalNAc}Z redEnd--??1D-GalNAc,p/#xcleavage_1_3--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
777.92 1.0
783.35 0.4
791.97 0.8
797.89 3.0
810.36 0.5
815.88 0.5
819.92 0.6
829.22 0.4
829.77 0.5
835.2 0.7

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd Y^{0,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p/#xcleavage_0_4--3?1D-Gal,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ^{2,4}X_{GalNAc}Y redEnd--??1D-GalNAc,p/#xcleavage_2_4--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
835.46 0.9

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd Y^{0,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p/#xcleavage_0_4--3?1D-Gal,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ^{2,4}X_{GalNAc}Y redEnd--??1D-GalNAc,p/#xcleavage_2_4--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
835.78 0.4

Annotations:

C b1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p$MONO,Und,-H,0,redEnd Y^{0,4}X_{Gal} redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p/#xcleavage_0_4--3?1D-Gal,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ^{2,4}X_{GalNAc}Y redEnd--??1D-GalNAc,p/#xcleavage_2_4--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
836.22 0.6
836.6 0.6
837.32 0.7
837.93 1.0
842.28 2.1

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
844.72 0.5
848.19 0.8

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-2H,0,redEnd
849.29 0.4
850.78 0.4
853.27 0.8
854.01 0.4
857.94 0.5
861.13 0.8
861.49 1.0
862.33 1.2
869.73 1.3
874.76 0.4
875.4 0.6

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
876.44 0.4
877.13 0.5
877.83 1.5

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
878.37 1.3
880.01 1.1
884.35 0.7
889.72 0.7
890.04 0.8
890.86 1.4
937.48 0.5
1006.1 0.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1020.72 0.4

Annotations:

BY ?1D-GalNAc,p/#bcleavage--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ^{2,4}X_{GalNAc}Z redEnd--??1D-GalNAc,p/#xcleavage_2_4--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1024.13 0.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1080.39 0.9

Annotations:

^{0,4}A_{GalNAc}Y ?1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1082.06 0.8
1098.1 0.5

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1098.35 0.4
1098.63 0.4
1260.36 7.9

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1260.97 1.7
1261.5 2.4
1262.47 1.8
1263.5 0.8
1292.47 0.4
1301.7 0.7
1313.63 0.4
1331.7 0.5
1348.47 0.6

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1348.66 0.4
1351.47 1.3
1355.53 0.4
1363.6 0.5
1369.44 0.7

Annotations:

ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p/#zcleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
1389.31 1.2

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1516.63 0.4

Annotations:

YZ redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p/#ycleavage)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p/#zcleavage)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
1532.29 0.6
1533.26 1.4

Annotations:

Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p/#zcleavage)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1534.5 0.8

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p/#ycleavage)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
1534.74 0.4

Annotations:

YY redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p/#ycleavage)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
1548.65 0.7
1550.81 2.1
1551.57 77.5

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p/#ycleavage)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
1552.42 23.2
1552.73 17.3
1553.81 11.4
1554.72 1.2
1595.79 0.4
1610.04 0.8
1696.63 0.4

Annotations:

Y redEnd--??1D-GalNAc,p(--3b1D-Gal,p--??2D-NeuAc,p)--6b1D-GlcNAc,p(--??1D-Gal,p(--3?1D-Gal,p)--6?1HexNAc,p--??2D-NeuAc,p)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
1752.71 0.5

There are 2 similar spectra:

Id Structure Score

4946

0.98

5879

0.85

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1841.67
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Salmo Salar
Tissue - Mucus

HPLC

Column

Method

  • 40 min gradient with 10 ul/min run rate
  • 10 mM (NH4)HCO3 in water
  • 10 mM (NH4)HCO3 in 80% acetontirile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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