Structure

    freeEnd--?b1D-GlcN,p((--4a14uHexA,p)--N?1S)--6?1S$MONO,Und,-2H,0,freeEnd

Shotgun Ion-Mobility Mass Spectrometry Sequencing (SIMMS2) for glycosaminoglycan oligosaccharides

GlyTouCan Accession Number: Loading...

Peak Intensity
55.0256 458.0
57.0418 2130.0
71.0229 1300.0
73.0389 1480.0
79.9692 262000.0
80.9763 136000.0
81.9641 4820.0

Annotations:

^{0,3}A_{GlcN} b1D-GlcN,p/#acleavage_0_3(--4a14uHexA,p)--6?1S/#lcleavage$MONO,Und,-3H,0,freeEnd
82.0427 95.3
82.9721 2560.0
83.0241 1950.0
84.0456 5.98
84.8917 18.0
85.0408 98600.0

Annotations:

Y freeEnd--?b1D-GlcN,p((--4a14uHexA,p/#ycleavage)--N?1S/#lcleavage)--6?1S/#lcleavage}--??1S$MONO,Und,-3H,0,freeEnd
86.0427 2880.0
87.0196 22700.0

Annotations:

C b1D-GlcN,p/#ccleavage--4a14uHexA,p$MONO,Und,-2H,0,freeEnd
95.0259 23800.0
95.062 247.0
95.5582 37.0
95.9835 2420.0

Annotations:

^{1,5}A_{GlcN} b1D-GlcN,p/#acleavage_1_5((--4a14uHexA,p)--N?1S/#lcleavage)--6?1S/#lcleavage$MONO,Und,-3H,0,freeEnd
96.0294 1000.0

Annotations:

^{1,5}A_{GlcN} b1D-GlcN,p/#acleavage_1_5((--4a14uHexA,p)--N?1S/#lcleavage)--6?1S/#lcleavage$MONO,Und,-3H,0,freeEnd
96.9767 448000.0
97.0421 2260.0
97.0785 73.4
97.9735 1030.0
98.0378 827.0
98.9691 7080.0
99.0211 1660.0
100.7356 22.6
101.0369 2750.0
107.0623 280.0
107.867 17.0

Annotations:

^{2,4}A_{GlcN} b1D-GlcN,p/#acleavage_2_4--4a14uHexA,p$MONO,Und,-2H,0,freeEnd ^{1,4}A_{GlcN} b1D-GlcN,p/#acleavage_1_4(--4a14uHexA,p)--N?1S$MONO,Und,-3H,0,freeEnd
108.0595 1430.0

Annotations:

^{1,4}A_{GlcN} b1D-GlcN,p/#acleavage_1_4(--4a14uHexA,p)--N?1S$MONO,Und,-3H,0,freeEnd ^{2,4}A_{GlcN} b1D-GlcN,p/#acleavage_2_4--4a14uHexA,p$MONO,Und,-2H,0,freeEnd ^{0,3}A_{GlcN} b1D-GlcN,p/#acleavage_0_3(--4a14uHexA,p)--6?1S$MONO,Und,-3H,0,freeEnd
110.0387 1020.0
111.0226 15600.0
111.0589 869.0
111.0989 50.9

Annotations:

freeEnd--?b1D-GlcN,p((--4a14uHexA,p)--N?1S/#lcleavage)--6?1S/#lcleavage$MONO,Und,-3H,0,freeEnd
112.0403 265.0

Annotations:

Y freeEnd--?b1D-GlcN,p((--4a14uHexA,p/#ycleavage)--N?1S)--6?1S$MONO,Und,-3H,0,freeEnd
113.0385 27800.0

Annotations:

^{2,5}A_{GlcN} b1D-GlcN,p/#acleavage_2_5(--4a14uHexA,p)--6?1S$MONO,Und,-3H,0,freeEnd
115.0186 56000.0

Annotations:

^{3,5}A_{GlcN} b1D-GlcN,p/#acleavage_3_5(--4a14uHexA,p)--6?1S/#lcleavage$MONO,Und,-2H,0,freeEnd
115.4881 35.0
116.0221 1270.0
123.009 29.9

Annotations:

^{0,3}A_{GlcN} b1D-GlcN,p/#acleavage_0_3(--4a14uHexA,p)--6?1S/#lcleavage$MONO,Und,-2H,0,freeEnd
125.0403 2020.0
126.0665 400.0
129.0356 14700.0
131.5219 561.0
136.0506 703.0
137.0416 5260.0
138.0105 1140000.0

Annotations:

^{1,3}A_{GlcN} b1D-GlcN,p/#acleavage_1_3--N?1S$MONO,Und,-H,0,freeEnd freeEnd--?b1D-GlcN,p((--4a14uHexA,p)--N?1S/#lcleavage)--6?1S/#lcleavage}--??1S$MONO,Und,-3H,0,freeEnd ^{0,2}A_{GlcN} b1D-GlcN,p/#acleavage_0_2(--4a14uHexA,p)--6?1S/#lcleavage$MONO,Und,-2H,0,freeEnd
138.9951 446000.0

Annotations:

^{0,4}A_{GlcN} b1D-GlcN,p/#acleavage_0_4--6?1S$MONO,Und,-H,0,freeEnd
139.0562 1250.0

Annotations:

^{0,4}A_{GlcN} b1D-GlcN,p/#acleavage_0_4--6?1S$MONO,Und,-H,0,freeEnd
140.0002 22600.0
140.0537 570.0
140.9861 6250.0
142.0693 2810.0
146.0096 410.0
148.0221 344.0
150.0062 5990.0
150.4983 8230.0
150.6602 15.5
150.9969 840.0
151.0579 473.0
151.5029 2090.0
157.0351 52600.0

Annotations:

B b1D-GlcN,p/#bcleavage--4a14uHexA,p$MONO,Und,-H,0,freeEnd
159.0417 358.0
159.5045 10400.0

Annotations:

Z freeEnd--?b1D-GlcN,p((--4a14uHexA,p/#zcleavage)--N?1S)--6?1S$MONO,Und,-2H,0,freeEnd
160.006 587.0

Annotations:

Z freeEnd--?b1D-GlcN,p((--4a14uHexA,p/#zcleavage)--N?1S/#lcleavage)--6?1S/#lcleavage$MONO,Und,-H,0,freeEnd
160.5054 1040.0
162.9908 702.0

Annotations:

^{0,3}A_{GlcN} b1D-GlcN,p/#acleavage_0_3(--4a14uHexA,p)--6?1S$MONO,Und,-2H,0,freeEnd
163.0942 46.2

Annotations:

^{0,3}A_{GlcN} b1D-GlcN,p/#acleavage_0_3(--4a14uHexA,p)--6?1S$MONO,Und,-2H,0,freeEnd
164.0174 265.0
165.0075 31700.0
166.0163 600.0
167.539 880.0

Annotations:

freeEnd--?b1D-GlcN,p((--4a14uHexA,p)--N?1S/#lcleavage)--6?1S/#lcleavage$MONO,Und,-2H,0,freeEnd
168.5132 140000.0

Annotations:

Y freeEnd--?b1D-GlcN,p((--4a14uHexA,p/#ycleavage)--N?1S)--6?1S$MONO,Und,-2H,0,freeEnd
169.0167 24900.0
169.0704 568.0
169.5115 11700.0
170.0149 1940.0

Annotations:

^{2,5}A_{GlcN} b1D-GlcN,p/#acleavage_2_5(--4a14uHexA,p)--6?1S$MONO,Und,-2H,0,freeEnd
170.0685 112.0

Annotations:

^{2,5}A_{GlcN} b1D-GlcN,p/#acleavage_2_5(--4a14uHexA,p)--6?1S$MONO,Und,-2H,0,freeEnd
171.506 4580.0
173.0681 698.0
175.0472 5170.0

Annotations:

C b1D-GlcN,p/#ccleavage--4a14uHexA,p$MONO,Und,-H,0,freeEnd
176.5441 764.0
178.0239 5320.0

Annotations:

^{0,2}A_{GlcN} b1D-GlcN,p/#acleavage_0_2(--4a14uHexA,p)--6?1S$MONO,Und,-2H,0,freeEnd Y freeEnd--?b1D-GlcN,p((--4a14uHexA,p/#ycleavage)--N?1S/#lcleavage)--6?1S/#lcleavage$MONO,Und,-H,0,freeEnd
178.528 681.0
179.0253 546.0
181.0055 17800.0
181.0599 132.0
181.5163 2290.0
182.0123 943.0
182.5105 6770.0
182.8622 25.0
183.0204 13600.0
183.5097 854.0
184.0251 4120.0
184.5346 1180.0

Annotations:

^{1,5}A_{GlcN} b1D-GlcN,p/#acleavage_1_5((--4a14uHexA,p)--N?1S/#lcleavage)--6?1S/#lcleavage}--??1S$MONO,Und,-2H,0,freeEnd
185.0233 563.0
185.5414 143.0
186.999 441.0
187.0825 53.5
188.9729 1430.0
189.5281 857000.0
190.0209 45600.0
190.0923 48.5
190.5193 61300.0
191.5181 633.0
192.0222 6110.0
193.0114 843.0
194.0376 11300.0
195.0266 1040.0
195.5195 13500.0
196.5196 1660.0
197.0654 706.0
198.0249 138.0
198.544 112000.0
199.0269 661000.0
200.0209 12500.0
200.0834 141.0
201.0157 13900.0
204.0232 2500.0
204.5214 133.0
205.0089 2150.0
207.5493 38400.0

Annotations:

freeEnd--?b1D-GlcN,p((--4a14uHexA,p)--N?1S/#lcleavage)--6?1S/#lcleavage}--??1S$MONO,Und,-2H,0,freeEnd
208.0504 5020.0
211.0216 957.0
211.5347 532.0
212.0407 165.0
216.0338 406.0
216.5282 13400.0
218.0102 3540.0
218.0665 188.0
218.5104 597.0
222.0381 85700.0
223.0229 34100.0
223.1622 34.7
224.0451 4980.0
224.528 179.0

Annotations:

^{1,5}A_{GlcN} b1D-GlcN,p/#acleavage_1_5((--4a14uHexA,p)--N?1S)--6?1S$MONO,Und,-2H,0,freeEnd
225.032 1780.0
225.5354 1400.0
227.0169 21200.0
227.2266 52.4
228.0242 616.0
229.519 871.0
230.0516 38.9
231.102 50.9

Annotations:

^{3,5}A_{GlcN} b1D-GlcN,p/#acleavage_3_5(--4a14uHexA,p)--6?1S/#lcleavage$MONO,Und,-H,0,freeEnd
235.022 1530.0
236.0387 75.4
237.0024 4930.0
237.6347 53.0
238.5266 11200.0
239.5259 1580.0
240.0539 171000.0

Annotations:

Z freeEnd--?b1D-GlcN,p((--4a14uHexA,p/#zcleavage)--N?1S/#lcleavage)--6?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
241.0456 1100000.0
241.1621 3360.0
242.0396 32900.0
242.7163 23.4
243.0333 20600.0
243.1174 17.7
244.0379 710.0
246.5262 212.0
247.545 530000.0

Annotations:

freeEnd--?b1D-GlcN,p((--4a14uHexA,p)--N?1S)--6?1S$MONO,Und,-2H,0,freeEnd
248.0361 51300.0
248.1143 38500.0
248.5365 45400.0
249.1866 134000.0
249.5321 697.0
253.0362 9040.0
254.0392 682.0
255.0186 1640.0
257.0594 1470.0
258.0747 1310000.0

Annotations:

Y freeEnd--?b1D-GlcN,p((--4a14uHexA,p/#ycleavage)--N?1S/#lcleavage)--6?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
259.0704 52300.0
259.1407 39.8
260.0626 31300.0
261.0677 817.0

Annotations:

^{2,5}A_{GlcN} b1D-GlcN,p/#acleavage_2_5(--4a14uHexA,p)--6?1S/#lcleavage$MONO,Und,-H,0,freeEnd
264.0541 549.0
267.0544 7720.0
268.0506 68500.0
268.6627 34.0
269.0391 6530.0
269.1041 26.3
270.0479 2420.0
271.0399 387.0
275.0803 147.0
277.0403 2420.0

Annotations:

^{0,2}A_{GlcN} b1D-GlcN,p/#acleavage_0_2(--4a14uHexA,p)--6?1S/#lcleavage$MONO,Und,-H,0,freeEnd
277.0933 4910.0

Annotations:

^{0,2}A_{GlcN} b1D-GlcN,p/#acleavage_0_2(--4a14uHexA,p)--6?1S/#lcleavage$MONO,Und,-H,0,freeEnd
279.0486 76.9
280.0542 233.0
281.2861 30.3
282.0677 46800.0
283.0627 3120.0
283.9883 106.0
284.0686 1560.0
285.0673 6970.0
285.9737 30.1
286.0646 101000.0
286.1192 58.0
287.0663 4270.0
287.1249 20.0
288.061 2360.0
295.0532 28600.0
297.0343 6840.0
299.076 2630.0
300.0941 2980000.0
300.3024 137.0
301.0878 140000.0
302.0064 96.5
302.0816 86200.0
302.1448 47.9
303.0823 2330.0
310.0654 3150.0
310.5722 17.6
311.0618 403.0

Annotations:

^{3,5}A_{GlcN} b1D-GlcN,p/#acleavage_3_5(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
312.0811 1870.0
313.0662 10200.0
314.0704 606.0
314.9821 4.5
317.119 494.0
318.1263 3900.0
319.1298 488.0
321.0353 241.0
324.0836 326.0
325.0306 28.0
325.0916 2690.0
327.0927 449.0

Annotations:

^{0,3}A_{GlcN} b1D-GlcN,p/#acleavage_0_3(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
328.0869 217000.0
329.082 9310.0
330.0035 28.2
330.0784 4850.0
330.1497 24.0
331.0777 300.0
336.0839 834.0

Annotations:

freeEnd--?b1D-GlcN,p((--4a14uHexA,p)--N?1S/#lcleavage)--6?1S/#lcleavage$MONO,Und,-H,0,freeEnd
336.1431 31.4

Annotations:

freeEnd--?b1D-GlcN,p((--4a14uHexA,p)--N?1S/#lcleavage)--6?1S/#lcleavage$MONO,Und,-H,0,freeEnd
337.0741 258.0
338.0317 728.0

Annotations:

Y freeEnd--?b1D-GlcN,p((--4a14uHexA,p/#ycleavage)--N?1S)--6?1S$MONO,Und,-H,0,freeEnd
339.0533 138000.0
340.0517 6360.0
341.0497 3480.0

Annotations:

^{2,5}A_{GlcN} b1D-GlcN,p/#acleavage_2_5(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
342.0539 280.0
357.0787 2280000.0

Annotations:

^{0,2}A_{GlcN} b1D-GlcN,p/#acleavage_0_2(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
357.2202 40700.0

Annotations:

^{0,2}A_{GlcN} b1D-GlcN,p/#acleavage_0_2(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
357.3112 51.1

Annotations:

^{0,2}A_{GlcN} b1D-GlcN,p/#acleavage_0_2(--4a14uHexA,p)--6?1S$MONO,Und,-H,0,freeEnd
357.9775 50.4
358.0706 142000.0
358.1337 212.0
359.0647 77700.0
359.2836 26.0
360.0658 3030.0
361.0645 166.0
370.0966 432.0

Annotations:

^{1,5}A_{GlcN} b1D-GlcN,p/#acleavage_1_5((--4a14uHexA,p)--N?1S/#lcleavage)--6?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
380.0596 389.0
380.1893 13.8
396.0766 367.0
396.7035 16.0
397.0873 259.0
398.0953 2790.0
399.0849 595.0
400.0887 199.0
414.092 1240.0
415.0997 13900.0
416.2189 4.81

Annotations:

freeEnd--?b1D-GlcN,p((--4a14uHexA,p)--N?1S/#lcleavage)--6?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
417.0988 639.0

There are 3 similar spectra:

Id Structure Score

1.00

5314

0.91

0.91

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 495.01
(Calculated Monoisotopic)

Reducing End: Free reducing end

Persubstitution: Underivatised

Biological Context

N/A

HPLC

Column

Method

  • gradient with 0.1 ml/min run rate
  • water
  • water

Mass Spec

Waters Synapt G2-S HDMS

MIRAGE Structural data

Report errors in this entry

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