Structure

    freeEnd--?b1D-GlcN,p(--4a14uHexA,p--2?1S)--N?1S$MONO,Und,-2H,0,freeEnd

Shotgun Ion-Mobility Mass Spectrometry Sequencing (SIMMS2) for glycosaminoglycan oligosaccharides

GlyTouCan Accession Number: Loading...

Peak Intensity
57.0415 6340.0
79.9707 843000.0
80.9775 331000.0
81.9644 12200.0

Annotations:

^{0,3}A_{GlcN} b1D-GlcN,p/#acleavage_0_3--4a14uHexA,p--2?1S/#lcleavage$MONO,Und,-3H,0,freeEnd
82.0393 366.0
82.9718 5360.0
83.0238 4400.0
85.0437 472000.0

Annotations:

Y freeEnd--?b1D-GlcN,p(--4a14uHexA,p/#ycleavage)--N?1S$MONO,Und,-3H,0,freeEnd
95.026 56500.0
96.0294 1870.0

Annotations:

^{1,5}A_{GlcN} b1D-GlcN,p/#acleavage_1_5(--4a14uHexA,p--2?1S/#lcleavage)--N?1S/#lcleavage$MONO,Und,-3H,0,freeEnd
96.9766 1310000.0
97.9722 2270.0
98.0376 1920.0

Annotations:

^{2,4}A_{GlcN} b1D-GlcN,p/#acleavage_2_4--4a14uHexA,p--2?1S$MONO,Und,-3H,0,freeEnd
98.9691 18000.0
111.0238 138000.0
115.0184 38600.0

Annotations:

^{3,5}A_{GlcN} b1D-GlcN,p/#acleavage_3_5--4a14uHexA,p--2?1S/#lcleavage$MONO,Und,-2H,0,freeEnd
129.0355 28600.0
136.0577 8800.0
137.0168 1500.0
138.0104 3550000.0

Annotations:

^{1,3}A_{GlcN} b1D-GlcN,p/#acleavage_1_3--N?1S$MONO,Und,-H,0,freeEnd freeEnd--?b1D-GlcN,p(--4a14uHexA,p--2?1S/#lcleavage)--N?1S/#lcleavage}--??1S$MONO,Und,-3H,0,freeEnd ^{0,2}A_{GlcN} b1D-GlcN,p/#acleavage_0_2--4a14uHexA,p--2?1S/#lcleavage$MONO,Und,-2H,0,freeEnd
138.993 120000.0

Annotations:

^{1,3}A_{4uHexA} a14uHexA,p/#acleavage_1_3--2?1S$MONO,Und,-H,0,freeEnd
139.0569 2660.0

Annotations:

^{1,3}A_{4uHexA} a14uHexA,p/#acleavage_1_3--2?1S$MONO,Und,-H,0,freeEnd
140.0016 66100.0
142.0691 19500.0
150.0062 55400.0
155.0475 746.0

Annotations:

^{3,5}A_{GlcN} b1D-GlcN,p/#acleavage_3_5--4a14uHexA,p--2?1S$MONO,Und,-2H,0,freeEnd
155.1268 23.9

Annotations:

^{3,5}A_{GlcN} b1D-GlcN,p/#acleavage_3_5--4a14uHexA,p--2?1S$MONO,Und,-2H,0,freeEnd
157.041 616000.0

Annotations:

B b1D-GlcN,p/#bcleavage--4a14uHexA,p--2?1S/#lcleavage$MONO,Und,-H,0,freeEnd
166.9883 4570.0
167.0562 1370.0
168.5103 2050.0
168.8575 30.7
169.0164 1040.0
169.0722 1850.0
174.9931 2550.0

Annotations:

C b1D-GlcN,p/#ccleavage--4a14uHexA,p--2?1S/#lcleavage$MONO,Und,-H,0,freeEnd
175.047 1830.0

Annotations:

C b1D-GlcN,p/#ccleavage--4a14uHexA,p--2?1S/#lcleavage$MONO,Und,-H,0,freeEnd
177.0154 1460.0
180.0292 3140.0
184.0256 18900.0
184.9496 32.9
185.025 1620.0
189.5279 1080000.0
190.021 53200.0
190.519 67500.0
190.5707 70.2
191.0212 4390.0
192.0219 17700.0
193.5216 494.0
194.0303 1570.0
197.0716 3240.0
198.545 184000.0
199.5419 8360.0
202.5286 17900.0

Annotations:

^{1,4}A_{GlcN} b1D-GlcN,p/#acleavage_1_4(--4a14uHexA,p--2?1S)--N?1S$MONO,Und,-2H,0,freeEnd
206.9994 26.3
207.549 48400.0

Annotations:

freeEnd--?b1D-GlcN,p(--4a14uHexA,p--2?1S/#lcleavage)--N?1S/#lcleavage}--??1S$MONO,Und,-2H,0,freeEnd
211.0215 1740.0
211.5353 2660.0
216.5281 11500.0
222.0389 150000.0
224.0496 11300.0
229.5193 2370.0
237.0039 123000.0

Annotations:

B b1D-GlcN,p/#bcleavage--4a14uHexA,p--2?1S$MONO,Und,-H,0,freeEnd
241.0454 1670000.0
242.0408 53700.0
243.0333 28000.0
243.0925 107.0
247.1778 1340.0

Annotations:

^{0,3}A_{GlcN} b1D-GlcN,p/#acleavage_0_3--4a14uHexA,p--2?1S/#lcleavage$MONO,Und,-H,0,freeEnd
247.5451 2540000.0

Annotations:

freeEnd--?b1D-GlcN,p(--4a14uHexA,p--2?1S)--N?1S$MONO,Und,-2H,0,freeEnd
248.0869 712.0
248.5374 208000.0
248.6157 64900.0
249.1683 7870.0
253.0292 4070.0
253.2505 2600.0
255.0156 21300.0

Annotations:

C b1D-GlcN,p/#ccleavage--4a14uHexA,p--2?1S$MONO,Und,-H,0,freeEnd
255.267 2710.0

Annotations:

C b1D-GlcN,p/#ccleavage--4a14uHexA,p--2?1S$MONO,Und,-H,0,freeEnd
257.0566 321.0
257.8923 56.6

Annotations:

Y freeEnd--?b1D-GlcN,p(--4a14uHexA,p/#ycleavage)--N?1S$MONO,Und,-H,0,freeEnd
258.0746 3040000.0

Annotations:

Y freeEnd--?b1D-GlcN,p(--4a14uHexA,p/#ycleavage)--N?1S$MONO,Und,-H,0,freeEnd
260.0637 69900.0
261.0683 1670.0

Annotations:

^{2,5}A_{GlcN} b1D-GlcN,p/#acleavage_2_5--4a14uHexA,p--2?1S/#lcleavage$MONO,Und,-H,0,freeEnd
267.0533 10300.0
267.3828 78.0
268.049 8430.0
270.0448 417.0
277.0934 24300.0

Annotations:

^{0,2}A_{GlcN} b1D-GlcN,p/#acleavage_0_2--4a14uHexA,p--2?1S/#lcleavage$MONO,Und,-H,0,freeEnd
279.0592 26.1
282.0667 22300.0
283.0562 3140.0
283.3225 22.8
284.0811 8080.0
284.9679 63.0
285.069 4770.0
286.0632 82500.0
286.2941 19.4
287.0648 3000.0
295.0524 18900.0
295.6916 45.0
296.0566 1310.0
297.0379 220000.0

Annotations:

^{2,4}A_{GlcN} b1D-GlcN,p/#acleavage_2_4--4a14uHexA,p--2?1S$MONO,Und,-H,0,freeEnd
299.0573 1870.0
300.0938 4200000.0
300.2248 96700.0
301.0884 183000.0
301.2307 41.9
302.0815 107000.0
306.0737 111.0
310.0661 4630.0
311.0541 982.0

Annotations:

^{3,5}A_{GlcN} b1D-GlcN,p/#acleavage_3_5--4a14uHexA,p--2?1S$MONO,Und,-H,0,freeEnd
311.5893 37.0
313.0672 36500.0
313.1486 27.0
314.073 2220.0
317.1179 4690.0
318.1277 86500.0
319.1284 4930.0
324.0832 765.0
325.0901 2740.0
326.0988 11100.0

Annotations:

^{1,4}A_{GlcN} b1D-GlcN,p/#acleavage_1_4(--4a14uHexA,p--2?1S/#lcleavage)--N?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
327.9839 16.2
328.0929 388000.0
330.0768 6490.0
335.9401 19.0

Annotations:

freeEnd--?b1D-GlcN,p(--4a14uHexA,p--2?1S/#lcleavage)--N?1S/#lcleavage$MONO,Und,-H,0,freeEnd
339.0495 52400.0
340.0517 2750.0
341.0471 1440.0

Annotations:

^{2,5}A_{GlcN} b1D-GlcN,p/#acleavage_2_5--4a14uHexA,p--2?1S$MONO,Und,-H,0,freeEnd
352.0812 1570.0
353.0893 1590.0
357.0793 7150000.0

Annotations:

^{0,2}A_{GlcN} b1D-GlcN,p/#acleavage_0_2--4a14uHexA,p--2?1S$MONO,Und,-H,0,freeEnd
358.0804 698000.0
359.0777 423000.0
360.0653 11200.0
380.0765 1710.0
381.0689 355.0
396.0775 1810.0
397.0848 2440.0
398.0955 43800.0
399.0868 6200.0
414.0916 8560.0
415.1029 103000.0
415.2503 70.4
416.101 6320.0

Annotations:

freeEnd--?b1D-GlcN,p(--4a14uHexA,p--2?1S/#lcleavage)--N?1S/#lcleavage}--??1S$MONO,Und,-H,0,freeEnd
417.0981 2290.0

There are 1 similar spectra:

Id Structure Score

5313

0.91

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 495.01
(Calculated Monoisotopic)

Reducing End: Free reducing end

Persubstitution: Underivatised

Biological Context

N/A

HPLC

Column

Method

  • gradient with 0.1 ml/min run rate
  • water
  • water

Mass Spec

Waters Synapt G2-S HDMS

MIRAGE Structural data

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