Structure

    redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p)--??1L-Fuc,p)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-2H,0,redEnd

Stress impairs skin barrier function and induces α2-3 linked N-acetylneuraminic acid and core 1 O-glycans on skin mucins in Atlantic salmon, Salmo salar

GlyTouCan Accession Number: Loading...

Peak Intensity
278.95 0.2
279.23 0.8
279.79 0.0
330.13 0.3

Annotations:

BZ b1D-Gal,p/#bcleavage--??1HexNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
339.28 0.2
348.21 1.9

Annotations:

BY b1D-Gal,p/#bcleavage--??1HexNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd CZ b1D-Gal,p/#ccleavage--??1HexNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
348.97 0.7
349.53 0.0
365.76 0.2

Annotations:

CY b1D-Gal,p/#ccleavage--??1HexNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
424.12 17.1

Annotations:

^{0,4}A_{GalNAc} a1D-GalNAc,p/#acleavage_0_4--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
425.15 2.2

Annotations:

YY redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p/#ycleavage)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd
425.77 0.0
475.59 1.4

Annotations:

Y redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-2H,0,redEnd
475.81 0.3
479.56 0.7
480.12 0.0
519.09 0.5
519.62 0.0
522.77 0.4
548.1 0.4
549.2 0.3

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--3a1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd BZ a1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
551.25 4.8

Annotations:

B b1D-Gal,p/#bcleavage--??1HexNAc,p(--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
551.91 0.0
552.4 0.4
557.23 0.3
566.45 1.0
567.02 0.0
567.82 1.1

Annotations:

CY ?1D-GalNAc,p/#ccleavage--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p)--??1L-Fuc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd YZ redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-2H,0,redEnd ZY redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-2H,0,redEnd
568.37 0.0
571.11 0.4
577.36 4.2

Annotations:

YY redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-2H,0,redEnd
577.78 1.5
578.35 0.0
579.58 0.4

Annotations:

ZZ redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p)--??1L-Fuc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-2H,0,redEnd
594.16 0.4
594.55 0.0
654.53 0.5
671.22 0.6

Annotations:

Y redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p)--??1L-Fuc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-2H,0,redEnd
671.78 0.0
672.23 0.5
676.72 0.3
677.95 0.8
678.51 0.0
690.84 0.5
691.38 0.0
698.36 0.5
712.69 1.0
713.14 0.5

Annotations:

B a1D-GalNAc,p/#bcleavage--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
714.67 0.6
715.22 0.0
721.72 8.4
722.25 5.6
722.63 1.2
722.85 0.8
723.41 0.0
772.16 0.7

Annotations:

YZ redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
772.71 0.0
773.18 0.8

Annotations:

^{2,4}A_{GalNAc} a1D-GalNAc,p/#acleavage_2_4--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
773.74 0.0
791.21 0.3
869.27 0.4
874.17 0.3
875.26 0.9
875.8 0.0
892.34 3.2
892.72 0.7
893.4 1.0
893.95 0.0
894.45 0.4
911.17 1.2
911.73 0.0
915.35 0.5

Annotations:

^{0,4}X_{GalNAc}Z redEnd--??1D-GalNAc,p--3a1D-GalNAc,p/#xcleavage_0_4--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
934.27 0.5

Annotations:

CY ?1D-GalNAc,p/#ccleavage--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p)--??1L-Fuc,p)--6b1D-GlcNAc,p/#ycleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
952.26 17.7

Annotations:

Y redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
952.61 6.3
953.43 6.9
954.19 1.6
954.55 0.3
1049.3 1.5
1049.86 0.0
1077.33 1.2
1077.59 0.2
1089.47 0.2
1095.47 0.6
1100.34 0.4
1119.33 0.8

Annotations:

BY ?1D-GalNAc,p/#bcleavage--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p)--??1L-Fuc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p)--??1L-Fuc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZZ redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
1119.88 0.0
1120.97 0.3
1121.38 0.5

Annotations:

Z redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p)--??1L-Fuc,p)--6b1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
1121.6 0.4
1137.18 1.1

Annotations:

CY ?1D-GalNAc,p/#ccleavage--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p)--??1L-Fuc,p)--6b1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p/#zcleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p/#zcleavage)--??1L-Fuc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
1137.71 0.5
1140.17 0.6
1140.71 0.0
1154.95 0.3
1155.25 1.5

Annotations:

YY redEnd--??1D-GalNAc,p--3a1D-GalNAc,p(--3b1D-Gal,p--??1HexNAc,p(--??1HexNAc,p/#ycleavage)--??1L-Fuc,p/#ycleavage)--6b1D-GlcNAc,p--??1D-Gal,p$MONO,Und,-H,0,redEnd
1155.59 1.1
1156.38 0.5
1282.29 0.2
1445.64 0.2

There are 5 similar spectra:

Id Structure Score

4826

0.94

5484

0.71

5764

0.65

5486

0.62

4827

0.51

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1503.59
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Salmo Salar
Tissue - Mucus

HPLC

Column Hypercarb

Method

  • 40 min gradient with 10 ul/min run rate
  • 10 mM (NH4)HCO3 in water
  • 10 mM (NH4)HCO3 in 80% acetontirile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

Report errors in this entry

UniCarb-DR Creative Commons License

Supported by SIB ExPASy  |  JST / NBDCDICP