Structure

    redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p)--??1S$MONO,Und,-H,0,redEnd

Sulfation of O-glycans on mucin-type proteins from serous ovarian epithelial tumors

GlyTouCan Accession Number: Loading...

Peak Intensity
282.16 0.2
314.87 0.8
315.21 0.5
316.0 0.2
360.8 0.2
425.67 0.2

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
426.13 1.4

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
428.14 2.8

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p((--??1D-Gal,p/#ycleavage)--??1L-Fuc,p)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p((--??1D-Gal,p/#zcleavage)--??1L-Fuc,p)--??1S$MONO,Und,-H,0,redEnd
429.2 0.3
438.93 0.1
444.08 3.1

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
445.23 0.2
446.3 0.1

Annotations:

CY ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p((--??1D-Gal,p/#ycleavage)--??1L-Fuc,p)--??1S$MONO,Und,-H,0,redEnd
451.0 0.2
462.2 0.2

Annotations:

CY ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
472.18 0.1
488.1 0.5
505.15 6.8
506.18 1.5
510.02 0.4

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
518.01 0.5
519.38 0.2
547.04 0.2
547.44 0.2
569.15 0.2

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p((--??1D-Gal,p/#ycleavage)--??1L-Fuc,p/#zcleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p((--??1D-Gal,p/#zcleavage)--??1L-Fuc,p/#ycleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p/#zcleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p/#ycleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
572.99 0.3
573.88 0.3
590.11 12.1

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p)--??1S$MONO,Und,-H,0,redEnd
591.03 1.1
591.3 1.3
598.18 0.3
633.45 0.9

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p((--??1D-Gal,p/#zcleavage)--??1L-Fuc,p)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p((--??1D-Gal,p/#ycleavage)--??1L-Fuc,p)--??1S$MONO,Und,-H,0,redEnd
633.89 0.2
648.74 0.2

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p((--??1D-Gal,p/#ycleavage)--??1L-Fuc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p((--??1D-Gal,p/#zcleavage)--??1L-Fuc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
649.11 1.1

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p((--??1D-Gal,p/#ycleavage)--??1L-Fuc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p((--??1D-Gal,p/#zcleavage)--??1L-Fuc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
650.18 1.3
651.15 21.4

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p((--??1D-Gal,p/#ycleavage)--??1L-Fuc,p)--??1S$MONO,Und,-H,0,redEnd
652.18 4.5
655.14 0.2
667.14 40.1

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p((--??1D-Gal,p/#ycleavage)--??1L-Fuc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
668.23 6.3
676.01 0.2
680.06 0.4
680.27 0.6
687.11 0.1
694.1 0.2
710.13 0.2
733.99 0.4
735.22 1.4
736.38 0.2
737.07 0.4
745.35 0.2
747.31 0.4
753.16 2.0
753.98 0.4
765.22 0.4
768.9 0.2
769.14 0.2
770.14 0.2
771.31 0.2
778.56 0.2
785.69 0.1
787.04 0.1
793.32 0.2
794.3 0.5
795.2 5.5

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p((--??1D-Gal,p/#zcleavage)--??1L-Fuc,p)--??1S$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p)--??1S$MONO,Und,-H,0,redEnd
796.01 0.8
796.4 1.5
800.22 0.4
803.24 0.2
810.16 0.3
810.84 0.2

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
811.38 0.7

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
812.12 0.4
813.2 148.7

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p((--??1D-Gal,p/#ycleavage)--??1L-Fuc,p)--??1S$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p)--??1S$MONO,Und,-H,0,redEnd
814.21 42.0
815.19 1.6
815.54 0.4
824.42 0.2
827.68 0.3
829.21 62.9

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p((--??1D-Gal,p)--??1L-Fuc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
830.24 20.7
837.82 0.2
855.36 0.2
856.7 0.2
857.49 0.2
871.99 0.4
901.22 0.2
915.34 0.3
915.65 0.3
915.98 0.4
932.97 0.2
933.49 0.2
934.07 0.3
934.45 0.4
940.77 0.2
944.34 0.6
944.7 0.3
976.08 0.4
977.42 0.2

There are 11 similar spectra:

Id Structure Score

6744

1.00

6656

0.96

6745

0.80

7655

0.80

7671

0.80

6654

0.79

6655

0.79

6747

0.78

3134

0.54

6746

0.53

6657

0.52

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 974.31
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Homo Sapiens
Tissue - Cyst Fluid

HPLC

Column

Method

  • 100 min gradient with approx 3-5 ul/min (static split from 250 ul/min) run rate
  • 10 mM (NH4)HCO3
  • 10 mM (NH4)HCO3 in 80% acetonitrile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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