Structure

    redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1L-Fuc,p$MONO,Und,-H,0,redEnd

Sulfation of O-glycans on mucin-type proteins from serous ovarian epithelial tumors

GlyTouCan Accession Number: Loading...

Peak Intensity
366.05 0.9

Annotations:

CY ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p/#zcleavage$MONO,Und,-H,0,redEnd
388.99 0.8
407.09 0.6
408.31 0.5
425.96 1.4

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
427.79 0.4
428.28 0.5
429.04 0.5
443.0 0.6
444.04 29.4

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
445.13 3.2
464.13 2.2
504.13 0.4
505.29 0.3
509.14 0.3
528.02 0.6

Annotations:

C ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
528.27 0.6

Annotations:

C ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
533.9 0.4
534.93 0.4

Annotations:

ZZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
562.11 0.5
569.13 1.7

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
569.42 0.5

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
587.16 1.0

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
589.07 0.6
590.17 21.7

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
591.1 3.8
592.01 0.5
600.79 0.8
607.06 0.4
608.13 1.0

Annotations:

C ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
609.37 0.7
623.95 0.7
631.22 0.6

Annotations:

ZZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
647.96 0.3
649.11 3.4

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
650.22 2.7
651.04 1.5
651.23 0.8
667.2 73.0

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
668.16 17.9
669.35 0.3
679.75 0.4
680.16 0.7
693.22 0.5
695.23 0.4
709.96 1.6
710.71 0.9
715.5 0.7

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
716.99 0.4
734.27 0.6
735.25 3.3
735.59 0.5
749.14 1.9

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1S/#lcleavage)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
753.16 1.1
754.04 0.7
754.27 0.8
768.21 0.4
769.0 0.3
769.48 0.6
774.93 0.4
775.35 0.3
776.9 0.4
777.33 0.5
778.48 0.5
787.15 0.3
793.03 0.4
793.34 0.3
794.36 1.2
794.6 0.5
795.28 9.8

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
796.33 1.7
810.22 0.9
811.26 4.0

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1L-Fuc,p/#zcleavage$MONO,Und,-H,0,redEnd
812.19 1.7
813.2 181.6

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1L-Fuc,p$MONO,Und,-H,0,redEnd
814.21 62.2
815.21 2.0
819.08 0.3
828.24 2.0
829.22 328.6

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1S)--??1L-Fuc,p/#ycleavage$MONO,Und,-H,0,redEnd
830.21 103.2
854.73 0.5
855.36 0.7
856.26 1.7
857.16 1.7
857.4 0.4
885.22 0.4
899.05 0.7
901.19 0.6
903.33 0.5
915.05 2.5
915.36 0.9
916.12 2.2
933.4 2.3
934.29 1.4
938.17 0.8
944.51 0.8
945.35 0.6
975.91 0.6
977.14 0.8

There are 16 similar spectra:

Id Structure Score

6745

1.00

6747

0.96

7655

0.95

7671

0.95

6655

0.95

6746

0.92

6657

0.90

3134

0.89

5798

0.88

5799

0.86

6744

0.81

6653

0.79

6656

0.77

5797

0.74

7901

0.73

7939

0.72

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 974.31
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Homo Sapiens
Tissue - Cyst Fluid

HPLC

Column

Method

  • 100 min gradient with approx 3-5 ul/min (static split from 250 ul/min) run rate
  • 10 mM (NH4)HCO3
  • 10 mM (NH4)HCO3 in 80% acetonitrile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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