Structure

    redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd

Sulfation of O-glycans on mucin-type proteins from serous ovarian epithelial tumors

GlyTouCan Accession Number: Loading...

Peak Intensity
343.35 0.1
397.28 0.1
444.04 2.4

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
445.07 0.5
462.21 0.2

Annotations:

CY ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
463.04 0.2
487.11 0.5

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
504.17 0.3
505.1 9.6

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
506.11 1.5
534.25 0.2
559.07 0.2
606.09 0.7
607.06 0.5
625.36 0.1
631.19 0.2

Annotations:

ZZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
647.02 0.7

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
647.25 0.4

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
648.12 0.2
648.64 0.1
649.21 1.8

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
650.02 0.4
667.14 35.4

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
668.18 6.4
673.34 0.2
680.12 0.1
708.31 0.4
708.91 0.1
750.86 0.1
752.02 0.1
754.34 0.2

Annotations:

ZZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
787.07 0.3
791.0 0.2
809.14 10.2

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
809.58 0.8

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
810.31 1.6
811.15 0.3

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
811.37 0.3

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
812.22 0.2
828.17 0.3
829.2 37.1

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
830.25 7.7
851.78 0.3

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
852.27 0.3

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
852.51 0.2

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
853.01 0.3
869.05 0.2
869.24 0.1
870.21 8.9

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
871.25 3.6
885.46 0.3
899.21 0.2
901.32 0.1
912.16 0.2
942.24 0.2
954.23 0.8
955.05 0.5
955.38 0.4
956.38 0.1
966.37 0.1
972.18 0.5
973.3 0.3
995.97 0.2
996.25 0.4
1013.13 0.1
1013.54 0.1
1014.4 3.0

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
1015.24 2.1
1031.41 0.4
1032.27 96.5

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
1033.28 34.6
1034.29 0.2
1034.88 0.1
1044.4 0.3
1047.34 0.5
1074.03 0.2
1074.88 0.2
1075.37 0.5
1075.74 0.2
1077.18 0.1
1103.91 0.4
1104.2 0.3
1104.47 0.4
1105.44 0.3
1111.64 0.2
1114.54 0.2

Annotations:

redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p(--??1D-Gal,p--??1D-GlcNAc,p--??1D-Gal,p)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
1121.42 0.5
1121.69 0.1
1122.39 0.4
1134.18 1.4
1135.1 0.6
1135.45 0.2
1151.01 0.2
1152.44 0.8
1153.49 0.1
1163.22 1.0
1164.13 0.5
1164.42 0.2
1195.36 1.3
1196.27 5.2

There are 3 similar spectra:

Id Structure Score

1.00

6662

0.81

0.81

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1193.38
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Homo Sapiens
Tissue - Cyst Fluid

HPLC

Column

Method

  • 100 min gradient with approx 3-5 ul/min (static split from 250 ul/min) run rate
  • 10 mM (NH4)HCO3
  • 10 mM (NH4)HCO3 in 80% acetonitrile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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