Structure

    redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd

Sulfation of O-glycans on mucin-type proteins from serous ovarian epithelial tumors

GlyTouCan Accession Number: Loading...

Peak Intensity
360.98 0.1
388.98 0.1

Annotations:

ZZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd
407.13 0.1

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
407.37 0.1

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd
407.96 0.1
425.88 0.1

Annotations:

BZ ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd BZ ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
444.07 19.7

Annotations:

BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd BY ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CZ ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd
445.04 2.0
461.69 0.1

Annotations:

CY ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CY ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
462.09 0.2

Annotations:

CY ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd CY ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
505.09 0.1
506.22 0.1
527.01 0.2
548.33 0.1
550.14 0.1
576.89 0.1
587.29 0.2

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage$MONO,Und,-H,0,redEnd YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
606.1 3.9

Annotations:

B ?1D-GlcNAc,p/#bcleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
607.05 0.8
618.95 0.1
623.0 0.1
623.97 0.3

Annotations:

C ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
624.32 0.1

Annotations:

C ?1D-GlcNAc,p/#ccleavage--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
647.11 0.1

Annotations:

CZ ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd BY ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
666.14 0.3
667.2 1.2

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
668.03 0.2
668.61 0.1
680.09 0.7
699.39 0.1
712.23 0.1
726.26 0.1
729.44 0.1

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
732.07 0.1
769.05 0.1
791.25 0.1
807.32 0.1
808.24 0.2
809.15 16.6

Annotations:

B ?1D-GalNAc,p/#bcleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
810.21 3.6
827.16 0.1

Annotations:

C ?1D-GalNAc,p/#ccleavage--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
829.26 2.2

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
830.17 0.2
852.39 0.1

Annotations:

YZ redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd ZY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
869.05 0.2
870.18 0.5

Annotations:

YY redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd
871.62 0.1
877.37 0.1
885.44 0.1
899.23 0.1
934.33 0.1

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
935.2 0.1
952.26 0.2

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
952.5 0.1

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S/#lcleavage$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
954.12 0.4
954.35 0.3
955.34 0.1
972.3 0.3
972.57 0.1
973.25 0.2
990.21 0.2
996.19 0.1
1012.31 0.1
1013.35 0.3
1014.38 1.5

Annotations:

Z redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#zcleavage)--??1S$MONO,Und,-H,0,redEnd Z redEnd--??1D-GalNAc,p(--??1D-Gal,p/#zcleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
1015.17 0.7
1032.25 39.4

Annotations:

Y redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p/#ycleavage)--??1S$MONO,Und,-H,0,redEnd Y redEnd--??1D-GalNAc,p(--??1D-Gal,p/#ycleavage)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p)--??1S$MONO,Und,-H,0,redEnd
1033.25 14.6
1034.11 0.1
1047.12 0.1
1047.59 0.1
1048.27 0.2
1063.35 0.2
1074.21 0.1
1075.11 0.3
1076.13 0.1
1091.59 0.1
1103.41 0.1
1104.12 0.2
1113.26 0.1
1113.64 0.1
1114.24 0.2

Annotations:

redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
1114.57 0.1

Annotations:

redEnd--??1D-GalNAc,p(--??1D-Gal,p)--??1D-GlcNAc,p--??1D-Gal,p(--??1D-GlcNAc,p--??1D-Gal,p)--??1S/#lcleavage$MONO,Und,-H,0,redEnd
1115.53 0.1
1134.29 0.4
1134.58 0.1
1135.29 0.2
1145.36 0.1
1148.17 0.1
1152.13 0.5
1152.45 0.9
1153.41 0.1
1162.44 0.1
1163.23 0.2
1164.51 0.1
1175.96 0.1
1176.6 0.1
1195.28 1.2
1196.34 1.7
1203.07 0.1

There are 3 similar spectra:

Id Structure Score

1.00

6661

0.81

0.81

Structure Format

SNFG Oxford Text

Structure details

Reducing Mass: 1193.38
(Calculated Monoisotopic)

Reducing End: Reduced

Persubstitution: Underivatised

Biological Context

Taxonomy - Homo Sapiens
Tissue - Cyst Fluid

HPLC

Column

Method

  • 100 min gradient with approx 3-5 ul/min (static split from 250 ul/min) run rate
  • 10 mM (NH4)HCO3
  • 10 mM (NH4)HCO3 in 80% acetonitrile

Mass Spec

Thermo Fisher LTQ Linear Ion Trap ESI

MIRAGE Structural data

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